Synthesis of Carbon Nanofibers on Copper Nanopowders by Low-Temperature CVD

Authors

  • G. Partizan The Institute of Combustion Problems, 050012, Bogenbay batyr str., 172, Almaty, Kazakhstan; Al-Farabi Kazakh National University, 050040, al-Farabi ave., 71, Аlmaty, Kazakhstan
  • B. Z. Mansurov The Institute of Combustion Problems, 050012, Bogenbay batyr str., 172, Almaty, Kazakhstan
  • B. S. Medyanova The Institute of Combustion Problems, 050012, Bogenbay batyr str., 172, Almaty, Kazakhstan; Al-Farabi Kazakh National University, 050040, al-Farabi ave., 71, Аlmaty, Kazakhstan
  • A. B. Koshanova The Institute of Combustion Problems, 050012, Bogenbay batyr str., 172, Almaty, Kazakhstan; Al-Farabi Kazakh National University, 050040, al-Farabi ave., 71, Аlmaty, Kazakhstan
  • M. E. Mansurova Al-Farabi Kazakh National University, 050040, al-Farabi ave., 71, Аlmaty, Kazakhstan
  • B. A. Aliyev Al-Farabi Kazakh National University, 050040, al-Farabi ave., 71, Аlmaty, Kazakhstan
  • X. Jiang Institute of Materials Engineering, University of Siegen, Paul-Bonatz-Straße 9-11, 57076, Siegen, Germany

DOI:

https://doi.org/10.18321/ectj470

Keywords:

thermal chemical vapor deposition, carbon nanostructures, copper nanopowders, low-temperature synthesis of carbon nanofibers

Abstract

The article presents the results of experiments on the synthesis of carbon nanofibers by thermal chemical vapor deposition using copper nanopowders obtained by electric explosion of wire as catalysts. Stable growth of carbon nanofibers was carried out at temperatures significantly lower than normally used. The process parameters that are optimal for low-temperature growth of carbon nanofibers have been identified during the performed experiments. The synthesized samples have different diameters and morphology (from spiral to direct). Copper clusters are both at the ends and inside the fibers. The results of IR spectroscopy indicate that the structure of the obtained carbon nanofibers is polymeric. X-ray analysis revealed the presence of a halo on the diffraction patterns at small values of the angle 2θ, which proves that the grown structures have an amorphous nature. There are no groups that are responsible for long-range order in all Raman spectra. Studies by transmission electron microscopy showed that nanostructures do not have an internal channel and nanofibers are solid.

References

[1]. A. Krueger. Carbon Materials and Nanotechnology. Weinheim: WILEY-VCH Verlag GmbH & Co. KGaA; 2010. <a href="https://doi.org/10.1002/9783527629602">Crossref</a>

[2]. L.V. Radushkevich, V.M. Lukyanovich, Zhurnal fizicheskoj himii [Journal of Physical Chemistry] 26 (1952) 88‒95 (in Russian).

[3]. J.H. Xia, X. Jiang and C.L. Jia, Appl. Phys. Lett. 95 (2009) 223110-1-223110-3. <a href="https://doi.org/10.1063/1.3271031">Crossref</a>

[4]. W. Merchan-Merchan, A.V. Saveliev, L. Kennedy, W.C. Jimenez, Prog. Energy Combust. Sci. 36 (2010) 696‒727. <a href="https://doi.org/10.1016/j.pecs.2010.02.005">Crossref</a>

[5]. S. Sabitov, A. Koshanova, B.S. Medyanova, G. Partizan, B.Z. Mansurov, B.A. Aliyev, Gorenie i plazmohimija [Combustion and plasma chemistry] 13 (1) (2015) 47‒52 (in Russian).

[6]. Yu.S. Buranova, Physics, electronics, nano-technology. Proceedings of MIPT 3 (3) (2011) 30‒41 (in Russian).

[7]. M.I. Lerner, N.V. Svarovskaya, S.G. Psakhie, O.V. Bakin, Rossijskie nanotehnologii [Russian Nanotechnologies] 4 (11-12) (2009) 56‒68 (in Russian).

[8]. U. Pakdee, S. Srabua, A. Phongphala, C. Pawong, Applied Mechanics and Materials 804 (2015) 47‒50. <a href="https://doi.org/10.4028/www.scientific.net/AMM.804.47">Crossref</a>

[9]. Haroon Ur.R., Kaichao Yu., Muhammad Naveed U., Muhammad Naveed A., Khalid Kh., Nasir A. and Muhammad Tariq, J. Rev. Adv. Mater. Sci. 15 (40) (2015) 235‒248.

[10]. Y. Ma, Ch. Weimer, N. Yang, L. Zhang, Th. Staedler, X. Jiang, Materials Today Communications 2 (2015) 55‒61. <a href="https://doi.org/10.1016/j.mtcomm.2014.12.003">Crossref</a>

[11]. Y. Ma, N. Yang and X. Jiang, One-Dimensional Carbon Nanostructures: Low-Temperature Chemical Vapor Synthesis and Applications. N. Yang et al. (eds.), Carbon Nanoparticles and Nanostructures, Springer International Publishing Switzerland 2016, 336 p.

[12]. M.I. Lerner Electroexplosivenanopowders of inorganic materials: production technology, characteristics, application areas: dis. ... Doc. tech. sci: 01.04.07. - Tomsk: 2007, 325 p. (in Russian).

[13]. A.P. Ilyin, Development of electroexplosive technology of nanopowders in the High Voltage Research Institute at Tomsk Polytechnic University. Bulletin of TPU 306 (1) (2003) 133‒39 (in Russian).

[14]. G. Partizan, B.Z. Mansurov, B.S. Medyanova, A.B. Koshanova, B.A. Aliyev, Gorenie i plazmohimija [Combustion and plasma chemistry] 14 (1) (2016). In print (in Russian).

[15]. G. Partizan, B.Z. Mansurov, B.S. Medyanova, A.B. Koshanova, B.A. Aliyev, X. Jiang, Eurasian Chemical-Technological Journal 17 (2015) 200‒207. <a href="https://doi.org/10.18321/ectj245">Crossref</a>

[16]. G. Partizan, B.Z. Mansurov, B.S. Medyanova, B.A. Aliev, X. Jiang, Journal of Engineering Physics and Thermophysics 88 (2015) 1451‒1458. <a href="https://doi.org/10.1007/s10891-015-1329-9>Crossref</a>

[17]. G Partizan, B.Z. Мansurov, B.А. Аliyev, B.S. Мedyanova, X. Jiang, Z.A. Mansurov. Low temperature growth of carbon nanostructures by thermal CVD on the particles of iron nanopawders. Proceedings of the Annual International World Conference on Carbon (Carbon 2015). Dresden, Germany, 2015, p. 232.

[18]. F.A. Abuilaiwi, T. Laoui, M. Al-Harthi and M. Ali Atieh. The Arabian Journal for Science and Engineering 35 (1C) (2010) 37‒48.

[19]. S. Costa, E. Borowiak-Palen, M. Kruszyńska, A. Bachmatiuk, R.J. Kaleńczuk, Materials Science- Poland 26 (2) (2008) 433‒441.

[20]. L Bokobza, J. Zhang, Express Polym. Lett. 6 (7) (2012) 601–608. <a href="https://doi.org/10.3144/expresspolymlett.2012.63">Crossref</a>

Downloads

Published

2016-10-27

How to Cite

Partizan, G., Mansurov, B. Z., Medyanova, B. S., Koshanova, A. B., Mansurova, M. E., Aliyev, B. A., & Jiang, X. (2016). Synthesis of Carbon Nanofibers on Copper Nanopowders by Low-Temperature CVD. Eurasian Chemico-Technological Journal, 18(4), 283–292. https://doi.org/10.18321/ectj470

Issue

Vol. 18 No. 4 (2016)

Section

Articles

License

You are free to: Share — copy and redistribute the material in any medium or format. Adapt — remix, transform, and build upon the material for any purpose, even commercially.

Eurasian Chemico-Technological Journal applies a Creative Commons Attribution 4.0 International License to articles and other works we publish.

Subject to the acceptance of the Article for publication in the Eurasian Chemico-Technological Journal, the Author(s) agrees to grant Eurasian Chemico-Technological Journal permission to publish the unpublished and original Article and all associated supplemental material under the Creative Commons Attribution 4.0 International license (CC BY 4.0).

Further distribution of this work must maintain attribution to the author(s) and the published article’s title, journal citation, and DOI.

Most read articles by the same author(s)