Design of Highly Efficient Catalyst for Rational Way of Direct Conversion of Methane

  • I. Z. Ismagilov Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva 5, 630090 Novosibirsk, Russia
  • E. V. Matus Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva 5, 630090 Novosibirsk, Russia
  • M. A. Kerzhentsev Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva 5, 630090 Novosibirsk, Russia
  • I. P. Prosvirin Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva 5, 630090 Novosibirsk, Russia
  • R. M. Navarro Instituto de Catálisis y Petroleoquímica, CSIC, Marie Curie 2, 28049 Madrid, Spain
  • J. J.G. Fierro Instituto de Catálisis y Petroleoquímica, CSIC, Marie Curie 2, 28049 Madrid, Spain
  • G. Gerritsen Hybrid Catalysis B.V., Den Dolech 2, Eindhoven 5612, AZ, the Netherlands
  • E. Abbenhuis Hybrid Catalysis B.V., Den Dolech 2, Eindhoven 5612, AZ, the Netherlands
  • Z. R. Ismagilov Institute of Coal Chemistry and Material Science SB RAS, pr. Sovetskiy 18, 650000 Kemerovo, Russia

Abstract

Effects of composition and preparation method of MnNaW/SiO2 and LaSr/CaO catalysts on their physical-chemical properties and performance in oxidative coupling of methane (OCM) have been studied. For MnNaW/SiO2 catalysts the synthesis method and type of SiO2 have a significant effect on the texture, while the Na/W ratio determines the phase composition. The variation of preparation method and temperature of catalyst calcination allows regulation of the metal surface concentration and mode of metal distribution across the SiO2 support. For LaSr/CaO catalysts the synthesis method determines the specific surface area, surface and phase composition. Correlations between catalyst performance, preparation method and state of the catalyst were established. The rational preparation procedure and perspective composition of OCM catalyst have been developed. The 20La/CaO catalysts prepared by citrate sol-gel method were shown to provide ~20% C2 yield and ~40% methane conversion at 800 ºC.

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Published
2015-04-10
How to Cite
[1]
I. Ismagilov, “Design of Highly Efficient Catalyst for Rational Way of Direct Conversion of Methane”, Euras. Chem. Tech. J., vol. 17, no. 2, pp. 105-118, Apr. 2015.
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Articles