Formation of Water-Soluble Fullerenes [C60,C70] under Ultrasonication and Antioxidant Effect

Authors

  • Weon-Bae Ko Department of Chemistry, Sahmyook University, 26-21 Kong Neung 2-Dong, No Won Gu, Seoul 139-742, Korea.
  • Hong-Seok Jeong Department of Chemistry, Sahmyook University, 26-21 Kong Neung 2-Dong, No Won Gu, Seoul 139-742, Korea.
  • Sung-Ho Hwang Department of Chemistry, Sahmyook University, 26-21 Kong Neung 2-Dong, No Won Gu, Seoul 139-742, Korea.

DOI:

https://doi.org/10.18321/ectj591

Abstract

The water-soluble fullerenes [C60, C70] are prepared with fullerenes [C60, C70] and a mixture of oxidants (v/v) at the ratio of 3:1 under ultrasonic condition at room temperature. The MALDI-TOF MS confirmed that the water-soluble compounds were C60 and C70. The antioxidant effect of water-soluble fullerenes [C60, C70] in the PC 12 cells (Rat pheochromocytoma) line following exposure to hydrogen peroxide (H2O2) was investigated.

References

(1). Kroto, H.W., Heath, J.R., O’Brien, S.C., Curl, R.F., and Smalley, R.E., Nature 318:162 (1985).

(2). Curl, R.F., Angew. Chem. Int. Ed. Eng 36:1566 (1997). (b) Kroto, H., Angew. Chem. Int. Ed. Eng 36:1578 (1997). (c) Smalley, R.E., Angew. Chem Int. Ed. Eng 36:1594 (1997).

(3). Jensen, A.W., Wilson, S.R., and Schuster, D.I., Bioorg. Med. Chem 4:767 (1996).

(4). Foote, C.E., in Light-activated pest control, ACS Symp. Ser. 616, ed. Heitz., J.R., and Downum, K.R., American Chemical Society, Washington, D.C, 1995, p. 17 and references therein.

(5). Scrivens, W.A., Tour, J.M., Creek, K.E., and Pirisi, L., J. Am. Chem.Soc 116:4517 (1994).

(6). Andersson, T., Nilsson, K., Sundahl, M., Westman, G., and Wennerstrom, O., J. Chem. Commun 604 (1992).

(7). Andersson, T., Westman, G., Wennerstrom, O., and Sundahl, M., J. Chem. Soc., Perkin. Trans. 2: 1097 (1994).

(8). Atwood, J.L., Koutsantonis, G.A., and Raston, C.L., Nature 368:229 (1994).

(9). Hwang K.C., and Mauzerall D., Nature 361:138 (1993).

(10). Tokuyama, H., Yamago, S., and Nakamura, E., J. Am. Chem. Soc 115:7918 (1993).

(11). Sijbesma, R., Srdanov, G., Wudl, F., Castoro, J.A., Wilkins, C., H. Friedman, S., De Camp, D.L., and Kenjon, G.L., J. Am. Chem. Soc 115:6510 (1993).

(12). Toniolo, C., Bianco, A., Maggini, M., Scorrano, G., Prato, M., Marastoni, M., Tomatis, R., Spisani, S., Palu, G., and Blair, E.D., J. Med. Chem 37:4558 (1994).

(13). Katoh, R., Yanase, E, Yokoi, H., Shu, U., Yozo, K., Ultrasonics Sonochemistry 5(1):37 (1998).

(14). Suslick, K.S., Ultrasound. Its Chemical, Physical and Biological Effects. VCH, Publisher Weinheim, 1989.

(15). Cataldo, F., and Heymann, D., Fullerene Sci. Technol 7:725 (1999).

(16). Andrievsky, G.V., Kosevich, M.V., M.Vovk, O., Shelkovsky, V.S., and Vashchenko, L.A., J. Chem. Soc., Chem. Commun 1281 (1995).

(17). Ko, W.B., and Baek, K.N., Phys. Solid State 44(3):424 (2002).

(18). Ko, W.B., and Baek, K.N., Ultrasonics 39(10): 729 (2002).

(19). Hansen, M.B., Nielsen, S.E., Berg, K.J. Immunol. Methods 20:203 (1989).

(20). Liu, Y., Schubert, D., J. Neurochem 69:2285 (1997).

(21). Liu, Y., Peterson, D.A., Kimura, H., Schubert, D., J. Neurochem 69:581 (1997).

(22). Mosmann, T., J. Immunol. Methods 65:55 (1983).

(23). Bereznyak E.G., Andrievesky G.V., Klochkov V.K., Bol’bukh T.V., Semenov M.A., 4th Biennial international workshop Fullerenes and Atomic Clusters, Center for research and Technology “FIZINTEL”, Saint Petersburg, 1999, Abstracts, P.140.

(24). Mason, T.J., Chemistry with ultrasound, Elsevier, London, 1990.

(25). Reichardt, C. Solvents and solvent effects in organic chemistry. VCH, Publisher Weinheim, 1998.

(26). Jeffrey, G.A., and Saenger, W., Hydrogen bonding in biological structures, Springer –Verlag, Berlin, 1991.

(27). Kosevich, M.V., and Shelkovskii, V.S., Low Temp. Phys 19:808 (1993).

(28). Holland, P.M. and Castleman, A.W., J. Chem. Phys 72:5984 (1980).

(29). Taylor, P., and Walton, D.R.M., Nature 363:685 (1993).

(30). Wei, S., and Castleman, A.W., Int. J. Mass Spectrum. Ion Processes 131:233 (1994).

(31). Ruoff, R. S., Tsc, D. S., Malhotra, R., and Lorents, D. C., J. Phys. Chem 97:3379 (1993).

(32). Ruoff, R.S., Malhotra, R., Huestis, D.L., Tsc, D.S., and Lorents, D.C., Nature 362:140 (1993).

(33). Mak, I.T., Komarov. A. M., Kramer, J.H., Weglicki, W.B., Cell. Mol. Biol. 8:1337 (2000).

(34). Kamat, J.P., Devasagayam, T.P., Priyadarsini, K.I., Mohan, H., Toxicology 155(1-3):55 (2000).

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Published

2003-01-15

How to Cite

Ko, W.-B., Jeong, H.-S., & Hwang, S.-H. (2003). Formation of Water-Soluble Fullerenes [C60,C70] under Ultrasonication and Antioxidant Effect. Eurasian Chemico-Technological Journal, 5(1), 61–67. https://doi.org/10.18321/ectj591

Issue

Vol. 5 No. 1 (2003)

Section

Articles

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