Simulation of Steam Reforming Tube with Shaped Particles
DOI:
https://doi.org/10.18321/ectj413Abstract
Shaped catalysts are widely used in steam reforming. A comprehensive mathematical model able to predict and compare performance of different shaped catalysts is developed. The two-dimensional pseudo homogeneous model accounts for heat transfer between the tube wall and catalyst bed, conductivity and diffusivity in the radial direction in the packed bed and intraparticle diffusion. Gas volume changing caused by reaction stoichiometry results in a radial convective mass flux. A verification of the model and simulated performance of different shaped catalysts in steam reforming of natural gas are presented
References
(1). Xu, J., Froment, G.F., AIChE J. 35:88 (1989).
(2). Grevskott, S., Rusten, T., Hillestad, M., Edwin, E. and Olsvik, O., Chem.Eng.Sci. 56:597 (2001).
(3). Soliman, M.A., Elnashaie, S.S., Al-Ubaid, A. and Adris, A., Chem.Eng.Sci. 8:1801 (1988).
(4). Abashar, M.E., Elnashaie, S.S., Math. Comput. Modelling, 7:85 (1993).
(5). Smirnov, E.I., Muzykantov,A.V., Kuzmin, V.A., Kronberg, A.E., Zolotarskii, I.A., Chem. Eng.J.,11:243 (2003).
(6). Smirnov, E.I., Muzykantov, A.V., Kuzmin V.A., Zolotarsky I.A., Koning, G.W., Kronberg, A.E.,Chemistry for Sustainable Development, 11:293 (2003).
(7). Hou, K., Hughes, R., Chem. Eng. J., 82:311 (2001).
(8). Akers, W.W., Camp, D.P., AICh.J., 4:471 (1955).
(9). Khomenko, A.A., Apel'baum, L.O., Shub, F.S., Kinetica i Kataliz (in Russian), 12:423 (1971).
(10). Atroshchenko, V.I., Raman, Sh.K., Zvyagintsev, G.L. Him. Promyshlennost' (in Russian), 1:36 (1970).
(11). Mason, E.A., Malinauskas, A., Gas Transport in Porous Media: The Dusty Gas Model, Elsevier, Amsterdam, 1983.
(12). Rester, S., Jouven, J., Aris, A. Chem. Eng. Science, 24:1019 (1969).
(13). Ergun, S. Chem. Eng. Prog.,48:89 (1952).
(14). Vortuba, J., Mikus, O., Hlavacek, V., Skrivanek, J. Chem. Eng. Sci., 29:2128 (1974).
(15). Samarskii, A.A., Mikhailov, A.P. Mathematical modeling Ideas. Methods. Examples, Moscow, 2001 (in Russian).
(16). Rapatski, L.A., Yausheva, L.V, Preprint No1019, Novosibirsk, 1994 (in Russian).
(17). Novikov, E.A. Numerical methods for solution of differential equations in chemical kinetics. In:Mathematical methods in chemical kinetics, Nauka, Novosibirsk, 1990 (in Russian).
(18). Ivanova, A.S., Bobrova, I.I., Zolotarsky, I.A., Smirnov, E.I., Kuz'min, V.A., Noskov, A.S., Parmon,V.N. Russian patent application: from 26. 04.01 #2001111600.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2005 Eurasian Chemico-Technological Journal
This work is licensed under a Creative Commons Attribution 4.0 International License.
You are free to: Share — copy and redistribute the material in any medium or format. Adapt — remix, transform, and build upon the material for any purpose, even commercially.
Eurasian Chemico-Technological Journal applies a Creative Commons Attribution 4.0 International License to articles and other works we publish.
Subject to the acceptance of the Article for publication in the Eurasian Chemico-Technological Journal, the Author(s) agrees to grant Eurasian Chemico-Technological Journal permission to publish the unpublished and original Article and all associated supplemental material under the Creative Commons Attribution 4.0 International license (CC BY 4.0).
Further distribution of this work must maintain attribution to the author(s) and the published article’s title, journal citation, and DOI.