Ni/Cr-[α-SiW12O40] Layered Double Hydroxide as Effective Adsorbent of Iron(II) From Aqueous Solution

  • A. Lesbani Graduate School of Mathematics and Natural Sciences, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia; Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia
  • M.F. Azmi Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia
  • N.R. Palapa Graduate School of Mathematics and Natural Sciences, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia
  • T. Taher Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia
  • R. Andreas Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Jenderal Soedirman, Jl. Dr. Soeparno, Karangwangkal, Purwokerto Utara, Banyumas, 53123, Indonesia
  • R. Mohadi Graduate School of Mathematics and Natural Sciences, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia; Research Center of Inorganic Materials and Coordination Complexes, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Jl. Palembang Prabumulih Km. 32 Ogan Ilir 30662, Indonesia

Abstract

Layered double hydroxide (LDH) Ni/Cr intercalated [α-SiW12O40]4- has been prepared using the coprecipitation method. Materials were characterized by X-ray, FTIR, BET, and pHpzc analyses. Material Ni/Cr-[α-SiW12O40] LDHs exhibited a high surface area 98.986 m2 g-1 from 11.030 m2 g-1 for Ni/Cr LDH where the interlayer space was an increase from 7.99 to 10.87 Å with indicated that high crystallinity. Ni/Cr-[α-SiW12O40] LDHs showed higher adsorption capacity for iron(II) is up to 250 mg g-1. Adsorption of iron(II) on LDHs has an endothermic process and classify as physical adsorption.

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Published
2021-08-30
How to Cite
[1]
A. Lesbani, M. Azmi, N. Palapa, T. Taher, R. Andreas, and R. Mohadi, “Ni/Cr-[α-SiW12O40] Layered Double Hydroxide as Effective Adsorbent of Iron(II) From Aqueous Solution”, Eurasian Chem.-Technol. J., vol. 23, no. 2, pp. 103-110, Aug. 2021.
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Articles