Zeolites for Fine Chemical Production State of Art and Perspectives
DOI:
https://doi.org/10.18321/ectj573Abstract
The paper analyses the role of catalysis and that of renewable resources in the frame of a sustainable development. The possible uses of natural feedstocks for chemical production and the application of catalytic methods to their transformations are reviewed, with emphasis on carbohydrates and vegetable oils and on zeolite catalysts, respectively. The problems arising from the embedment of active sites on the catalyst surface are discussed, with the aid of specific examples taken from oxidation and acid catalysed reactions.
References
1. Workshop on Catalysis for Environmentally Friendly Processes and Products, Istanbul, 24-27 September 2001.
2. van Bekkum, H., Renewable materials and their increasing role as chemical feedstock, in: Workshop on Catalysis for Environmentally Friendly Processes and Products, Istanbul, 24-27 September 2001.
3. Koetsier, W., Oleochemistry; Prospects for the 21st Century, in: Workshop on Catalysis for Environmentally Friendly Processes and Products, Istanbul, 24-27 September 2001.
4. Venuto, P.B., Microporous Mater., 2, 297 (1994).
5. Clerici, M.G., Topics Catal., 13, 33 (2000).
6. Clerici, M.G., Bellussi, G., and Romano, U., J. Catal., 129, 159 (1991).
7. Romano, U., Esposito, A., Maspero, F., Neri, C., and Clerici, M.G., Chim. Ind. (Milan), 72,610 (1990).
8. Clerici, M.G., in: Sheldon, R.A., and van Bekkum, H. (Eds), Fine Chemicals through Heterogeneous Catalysis, p. 538. Wiley-VCH, Weinheim, 2001.
9. Bossaert, W.D., De Vos, D.E., Van Rhjin, W.M., Bullen, J., Grobet, P. J., and P.J. Jacobs, J. Catal.,182, 164 (1999).
10. Lin, X., Khuan, G., and Jaenicke, S., J. Mol. Catal. A, 150, 287 (1999).
11. Machado, M.d.S., Pérez-Pariente, J., Sastre, E., Cardoso, D., de Guereñu, A.M., Appl. Catal. A, 203, 321 (2000).
12. Verhoef, M.J., Koster, R.M., Poels, E., Bliek, A., Peters, J.A., and van Bekkum, H., in:Galarneau, A., Di Renzo, F., Fajula, F., and Vedrine, J., Zeolites and Mesoporous Materials in the Dawn of 21st Century, Stud. Surf. Sc.
Catal., vol. 135. Elsevier, Amsterdam, 2001.
13. Beers, A.E.W., Spruijt, R.A., Nijhuis, T.A., Kapteijn, F., Moulijn, J.A., Catal. Today, 66, 175 (2001).
14. Deshmukh, A.R.A.S., Gumaste, V.K., and Bhaval, B.M., Catal., Letters, 64, 247 (2000).
15. Da, Z., Han, Z., Magnoux, P., and Guisnet, M., Appl. Catal. A, 219, 45 (2001).
16. Corma, A., Iborra, S., Miquel, S., and Primo, J., J. Catal., 180, 218 (1998).
17. Climent, M.J., Corma, A., Iborra, S., Miquel, S., Primo, J., and Rey, F., J. Catal., 183, 76(1999).
18. Chapat, J.F., Finiels, A., Joffre, J., and Moreau, C., J. Catal., 185, 445 (1999).
19. Lecompte, J., Finiels, A., Geneste, P. and Moreau, C., J. Mol. Catal. A, 123, 283 (1998).
20. Allahverdiev, A.I., Irandoust, S., and Murzin, D.Y., J. Catal., 185, 352 (1999).
21. Botella, P., Corma, A., Lopéz-Nieto, J.M., Valencia, S., Lucas, M.E., and Sergio, M., Appl. Catal. A, 203, 251 (2000).
22. Gainsford, G.J., Hosie, C.F., and Weston, R.J., Appl. Catal. A, 167, 331 (1998).
23. Camblor, M.A., Corma, A., Esteve, P., Martínez, A., and Valencia, S., Chem. Commun., 795 (1997).
24. Van der Waal, J.C., Rigutto, M.S., and van Bekkum, H., Appl. Catal. A, 209, 269 (2001).
25. Trong On, D., Kapoor, M.P., Joshi, P.N., Bonneviot, L., and Kaliaguine, S., Catal. Lett., 44, 171 (1997).
26. Suh, Y.W., Kim, N.K., Ahn, W.S., and Rhee, H.K., J. Mol. Catal. A, 174, 249 (2001).
27. Corma, A., Iglesias, M., and Sánchez, F., J. Chem. Soc., Chem. Commun., 1635 (1995).
28. Mombarg, E.J.M., Osnabrug, S.J.M., van Rantwijk, F., and van Bekkum, H., in. H.U. Blaser, A. Baiker, and R. Prins (Eds.), Heterogeneous Catalysis and Fine Chemicals IV, Stud. Surf. Sc. Catal., vol. 108, p. 885. Elsevier, Amsterdam, 1997.
29. Martínez Velarde, A., Bartl, P., Niessen, T.E.W., and Hoelderich, W., J. Mol. Catal. A, 157, 225 (2000).
30. Derouane, E., J. Mol. Catal. A, 134, 29 (1998).
31. Langhendries, G., De Vos, D.E., Baron, G., and Jacobs, P.A., J. Catal., 187, 453 (1999).
32. Clerici, M.G., and Ingallina, P., J. Catal., 140, 71 (1993)
33. van der Waal, J.C., Lin, P., Rigutto, M.S., and van Bekkum, H., Stud. Surf. Sc. Catal., vol. 105, 1093 (1997).
34. Clerici, M.G., Topics Catal., 15, 257 (2001).
35. Clerici, M.G., Appl. Catal. A, 68, 249 (1991).
36. Neurock, M., and Manzer, L.E., J. Chem. Soc., Chem. Commun., 1133 (1966).
37. Gunnewegh, E.A., Downing, R.S., and van. Bekkum, H., in: L. Bonneviot and S. Kaliaguine (Eds.), A Refined Tool for Designing Catalytic Sites, Stud. Surf. Sc. Catal., vol 97, p. 447.Elsevier, Amsterdam, 1995.
38. Hoefnagel, A.J., and van Bekkum, H., Appl. Catal. A, 97, 87 (1993).
39. Richard, F., Careyre, H., and Pérot, G., J. Catal., 159, 427 (1996).
40. Harvey, G., Vogt, A, Kouwenhoven, H.W., and Prins, R., in: R. von Ballmoos, J.B. Higgins, and M.M.J. Treacy (Eds.), Proc. 9th Zeol. Conf, Montreal 1992, p.363. Butterworth-Heinemann, Boston, 1993.
41. Rohan, D., Canaff, C., Fromentin, E., and Guisnet, M., J. Catal., 177, 298 (1998).
42. Gaare, K., and Akporiyae, D., Appl. Catal. A, 109, 177 (1996).
43. Lecompte, J., Finiels, A., Geneste, P., and Moreau, C., Appl. Catal. A, 168, 235 (1998).
44. Lecompte, J., Finiels, A., Geneste, P., and Moreau, C., J. Mol.. Catal. A, 133, 283 (1998).
45. Moreau, C., Fajula, F., Finiels, A., Razigade, S., Gilbert, L., Jacquot, R., and Spagnol, M., Catal. Org. React (Dekker), 51 (1998).
46. Harvey, G., and Mäder, G., Collect. Czech. Chem. Commun., 57, 862 (1992).
47. Andy, P., Garcia-Martinez, J., Lee, G., Gonzalez, H., Jones, C.W., and Davis, M.E., J. Catal.,192, 215 (2000).
48. Casagrande, M., Storaro, L., Lenarda, M., and Ganzerla, R., Appl. Catal. A, 201, 263 (2000).
49. Wu, P., Komatsu, T., and Yashima, T., Stud. Surf. Sc. Catal., Vol. 105, p.663. Elsevier, 1997.
2. van Bekkum, H., Renewable materials and their increasing role as chemical feedstock, in: Workshop on Catalysis for Environmentally Friendly Processes and Products, Istanbul, 24-27 September 2001.
3. Koetsier, W., Oleochemistry; Prospects for the 21st Century, in: Workshop on Catalysis for Environmentally Friendly Processes and Products, Istanbul, 24-27 September 2001.
4. Venuto, P.B., Microporous Mater., 2, 297 (1994).
5. Clerici, M.G., Topics Catal., 13, 33 (2000).
6. Clerici, M.G., Bellussi, G., and Romano, U., J. Catal., 129, 159 (1991).
7. Romano, U., Esposito, A., Maspero, F., Neri, C., and Clerici, M.G., Chim. Ind. (Milan), 72,610 (1990).
8. Clerici, M.G., in: Sheldon, R.A., and van Bekkum, H. (Eds), Fine Chemicals through Heterogeneous Catalysis, p. 538. Wiley-VCH, Weinheim, 2001.
9. Bossaert, W.D., De Vos, D.E., Van Rhjin, W.M., Bullen, J., Grobet, P. J., and P.J. Jacobs, J. Catal.,182, 164 (1999).
10. Lin, X., Khuan, G., and Jaenicke, S., J. Mol. Catal. A, 150, 287 (1999).
11. Machado, M.d.S., Pérez-Pariente, J., Sastre, E., Cardoso, D., de Guereñu, A.M., Appl. Catal. A, 203, 321 (2000).
12. Verhoef, M.J., Koster, R.M., Poels, E., Bliek, A., Peters, J.A., and van Bekkum, H., in:Galarneau, A., Di Renzo, F., Fajula, F., and Vedrine, J., Zeolites and Mesoporous Materials in the Dawn of 21st Century, Stud. Surf. Sc.
Catal., vol. 135. Elsevier, Amsterdam, 2001.
13. Beers, A.E.W., Spruijt, R.A., Nijhuis, T.A., Kapteijn, F., Moulijn, J.A., Catal. Today, 66, 175 (2001).
14. Deshmukh, A.R.A.S., Gumaste, V.K., and Bhaval, B.M., Catal., Letters, 64, 247 (2000).
15. Da, Z., Han, Z., Magnoux, P., and Guisnet, M., Appl. Catal. A, 219, 45 (2001).
16. Corma, A., Iborra, S., Miquel, S., and Primo, J., J. Catal., 180, 218 (1998).
17. Climent, M.J., Corma, A., Iborra, S., Miquel, S., Primo, J., and Rey, F., J. Catal., 183, 76(1999).
18. Chapat, J.F., Finiels, A., Joffre, J., and Moreau, C., J. Catal., 185, 445 (1999).
19. Lecompte, J., Finiels, A., Geneste, P. and Moreau, C., J. Mol. Catal. A, 123, 283 (1998).
20. Allahverdiev, A.I., Irandoust, S., and Murzin, D.Y., J. Catal., 185, 352 (1999).
21. Botella, P., Corma, A., Lopéz-Nieto, J.M., Valencia, S., Lucas, M.E., and Sergio, M., Appl. Catal. A, 203, 251 (2000).
22. Gainsford, G.J., Hosie, C.F., and Weston, R.J., Appl. Catal. A, 167, 331 (1998).
23. Camblor, M.A., Corma, A., Esteve, P., Martínez, A., and Valencia, S., Chem. Commun., 795 (1997).
24. Van der Waal, J.C., Rigutto, M.S., and van Bekkum, H., Appl. Catal. A, 209, 269 (2001).
25. Trong On, D., Kapoor, M.P., Joshi, P.N., Bonneviot, L., and Kaliaguine, S., Catal. Lett., 44, 171 (1997).
26. Suh, Y.W., Kim, N.K., Ahn, W.S., and Rhee, H.K., J. Mol. Catal. A, 174, 249 (2001).
27. Corma, A., Iglesias, M., and Sánchez, F., J. Chem. Soc., Chem. Commun., 1635 (1995).
28. Mombarg, E.J.M., Osnabrug, S.J.M., van Rantwijk, F., and van Bekkum, H., in. H.U. Blaser, A. Baiker, and R. Prins (Eds.), Heterogeneous Catalysis and Fine Chemicals IV, Stud. Surf. Sc. Catal., vol. 108, p. 885. Elsevier, Amsterdam, 1997.
29. Martínez Velarde, A., Bartl, P., Niessen, T.E.W., and Hoelderich, W., J. Mol. Catal. A, 157, 225 (2000).
30. Derouane, E., J. Mol. Catal. A, 134, 29 (1998).
31. Langhendries, G., De Vos, D.E., Baron, G., and Jacobs, P.A., J. Catal., 187, 453 (1999).
32. Clerici, M.G., and Ingallina, P., J. Catal., 140, 71 (1993)
33. van der Waal, J.C., Lin, P., Rigutto, M.S., and van Bekkum, H., Stud. Surf. Sc. Catal., vol. 105, 1093 (1997).
34. Clerici, M.G., Topics Catal., 15, 257 (2001).
35. Clerici, M.G., Appl. Catal. A, 68, 249 (1991).
36. Neurock, M., and Manzer, L.E., J. Chem. Soc., Chem. Commun., 1133 (1966).
37. Gunnewegh, E.A., Downing, R.S., and van. Bekkum, H., in: L. Bonneviot and S. Kaliaguine (Eds.), A Refined Tool for Designing Catalytic Sites, Stud. Surf. Sc. Catal., vol 97, p. 447.Elsevier, Amsterdam, 1995.
38. Hoefnagel, A.J., and van Bekkum, H., Appl. Catal. A, 97, 87 (1993).
39. Richard, F., Careyre, H., and Pérot, G., J. Catal., 159, 427 (1996).
40. Harvey, G., Vogt, A, Kouwenhoven, H.W., and Prins, R., in: R. von Ballmoos, J.B. Higgins, and M.M.J. Treacy (Eds.), Proc. 9th Zeol. Conf, Montreal 1992, p.363. Butterworth-Heinemann, Boston, 1993.
41. Rohan, D., Canaff, C., Fromentin, E., and Guisnet, M., J. Catal., 177, 298 (1998).
42. Gaare, K., and Akporiyae, D., Appl. Catal. A, 109, 177 (1996).
43. Lecompte, J., Finiels, A., Geneste, P., and Moreau, C., Appl. Catal. A, 168, 235 (1998).
44. Lecompte, J., Finiels, A., Geneste, P., and Moreau, C., J. Mol.. Catal. A, 133, 283 (1998).
45. Moreau, C., Fajula, F., Finiels, A., Razigade, S., Gilbert, L., Jacquot, R., and Spagnol, M., Catal. Org. React (Dekker), 51 (1998).
46. Harvey, G., and Mäder, G., Collect. Czech. Chem. Commun., 57, 862 (1992).
47. Andy, P., Garcia-Martinez, J., Lee, G., Gonzalez, H., Jones, C.W., and Davis, M.E., J. Catal.,192, 215 (2000).
48. Casagrande, M., Storaro, L., Lenarda, M., and Ganzerla, R., Appl. Catal. A, 201, 263 (2000).
49. Wu, P., Komatsu, T., and Yashima, T., Stud. Surf. Sc. Catal., Vol. 105, p.663. Elsevier, 1997.
Downloads
Published
2001-12-25
How to Cite
Clerici, M. G. (2001). Zeolites for Fine Chemical Production State of Art and Perspectives. Eurasian Chemico-Technological Journal, 3(4), 231–239. https://doi.org/10.18321/ectj573
Issue
Section
Articles
License
You are free to: Share — copy and redistribute the material in any medium or format. Adapt — remix, transform, and build upon the material for any purpose, even commercially.
Eurasian Chemico-Technological Journal applies a Creative Commons Attribution 4.0 International License to articles and other works we publish.
Subject to the acceptance of the Article for publication in the Eurasian Chemico-Technological Journal, the Author(s) agrees to grant Eurasian Chemico-Technological Journal permission to publish the unpublished and original Article and all associated supplemental material under the Creative Commons Attribution 4.0 International license (CC BY 4.0).
Further distribution of this work must maintain attribution to the author(s) and the published article’s title, journal citation, and DOI.
