Catalytic Synthesis of Organophosphorus Compounds from Inorganic Derivatives of Low Valence Phosphorus

Authors

  • G. S. Polimbetova D.V.Sokolsky Institute of Organic Catalysis and Electrochemistry
  • R. R. Abdreimova D.V.Sokolsky Institute of Organic Catalysis and Electrochemistry
  • F. Kh. Faisova D.V.Sokolsky Institute of Organic Catalysis and Electrochemistry

DOI:

https://doi.org/10.18321/ectj352

Abstract

A variety of new reactions of inorganic compounds of elemental and low valence phosphorus (phosphine, white phosphorus, sodium hypophosphite) with various organic substrates (alcohols, olefins, quinones) catalysed by different transition metal (PdII, HgII, PtII, PtIV, AgI, FeIII, CuII) salts leading to the formation of valuable organophosphorus derivatives (trialkylphosphates, dialkylphosphites, trialkylphoshinoxides, phosphonium salts) are reviewed. The principal features of the oxidative phosphorylation reactions which are of great practical importance are described. The mechanisms of the catalytic oxidative P-O and P-C coupling of phosphine, white phosphorus and hypophosphite with alcohols, olefins and quinones are considered. It has been shown that this catalytic protocol allows to provide a highly selective conversion of relatively inexpensive feedstocks to desirable higher added-value products.

References

(1). Dorfman, Ya.A., Aleshkova, M.M., Polimbetova, G.S., Levina, L.V., Petrova, T.V., Abdreimova, R.R., Doroshkevich, D.M., Russian Chemical Reviews 62:877 (1993).

(2). R.F. Hudson. Structure and Mechanism in Organophosphorus Chemistry. M.: Mir, (1967). 361 p.

(3). O.N.Erastov, G.E. Niconov. Funktsional’no Zameshchennye Fosfine i Ikh Proizvodnye (Phosphines with Functional Group Substituents and Their Derivatives). M.: Nauka (1986). 306 p.

(4). Dorfman, Ya.A., Polimbetova, G.S., Koord.Khim. 21:191 (1995).

(5). Dorfman, Ya.A., Polimbetova, G.S., Aibasov, E.Zh., Zh.Obshch.Khim. 65:970 (1995).

(6). Dorfman, Ya.A., Polimbetova, G.S., Aibasov, E.Zh., Zh.Obshch.Khim. 65:1849 (1995).

(7). Dorfman, Ya.A., Polimbetova, G.S., Aibasov, E.Zh., Zh.Obshch.Khim. 66:240 (1996).

(8). Dorfman, Ya.A., Polimbetova, G.S., Aleshkova, M.M., Borangazieva A.K., Koord. Khim. 25:520 (1999).

(9). D.E.C.Corbridge, In Phosphorus. An Outline of its Chemistry, Biochemistry and Technology (Edited by Elsevier sci. publ. company, New York (1980). 680 p.

(10). Abdreimova, R.R., Akbayeva, D.N., Faisova, F.Kh., Aibasova, S.M., Proceedings of the Ministry of Science-Academy of Sciences of the Republic of Kazakhstan, Chemical Series, 4:65 (1998).

(11). Dorfman, Ya.A., Aleshkova, M.M., Zh. Obshch. Khim. 65:577 (1995).

Downloads

Published

2000-02-20

How to Cite

Polimbetova, G. S., Abdreimova, R. R., & Faisova, F. K. (2000). Catalytic Synthesis of Organophosphorus Compounds from Inorganic Derivatives of Low Valence Phosphorus. Eurasian Chemico-Technological Journal, 2(1), 21–27. https://doi.org/10.18321/ectj352

Issue

Vol. 2 No. 1 (2000)

Section

Articles

License

You are free to: Share — copy and redistribute the material in any medium or format. Adapt — remix, transform, and build upon the material for any purpose, even commercially.

Eurasian Chemico-Technological Journal applies a Creative Commons Attribution 4.0 International License to articles and other works we publish.

Subject to the acceptance of the Article for publication in the Eurasian Chemico-Technological Journal, the Author(s) agrees to grant Eurasian Chemico-Technological Journal permission to publish the unpublished and original Article and all associated supplemental material under the Creative Commons Attribution 4.0 International license (CC BY 4.0).

Further distribution of this work must maintain attribution to the author(s) and the published article’s title, journal citation, and DOI.