HPAM-Cr (III) Gel Syneresis in Bulk Volume
DOI:
https://doi.org/10.18321/ectj1608Keywords:
gels, polymer, brine, syneresis, oil recoveryAbstract
This paper explores the crucial factors influencing the stability of polymer gels utilized in oil well treatments, with a focus on the effects of polymer mixing time and concentrations of polymer and crosslinker. Operating within a practical constraint of a 30-minute mixing time in surface facilities, our findings reveal that incomplete polymer dissolution leads to gel segregation and substantial water release over extended aging at 50 ºC. Notably, a reduction in the crosslinker/ polymer ratio, achieved by lowering crosslinker concentration or increasing polymer concentration, proves effective in mitigating water release to as low as 0‒1% over 90‒185 h of aging. Furthermore, gels prepared in sea and reservoir brines exhibit superior stability compared to those in distilled water, suggesting that ion presence in brines counteracts the repulsion between charged polymer chains observed in distilled water. This study provides valuable insights for optimizing polymer gel formulations under time constraints.
References
(1). D. Perez, L.F. Muñoz, W. Acosta, J. Falla, J. Martínez, G. Vidal, E. Manrique, F. Cabrera, J. Romero, M. Izadikamoue, C. Norman, Improving Sweep Efficiency In A Mature Waterflood: Balcon Field, Colombia, in: All Days, SPE, 2012. Crossref
(2). G. Maya, R. Castro, J. Sandoval, Z. Pachon, R. Jimenez, K. Pinto, V. Diaz, J. Zapata, L. Perdomo, S. Muñoz, Successful Polymer Gels Application in a Highly Channeled Peripheral Injection Well: Tello Field Pilot, in: Day 3 Fri, May 23, 2014, SPE, 2014. Crossref
(3). H. Jia, P. Li, Y. Zhang, SPE J. 29 (2024) 243–259. Crossref
(4). W. Kang, X. Kang, Z.A. Lashari, Z. Li, et al., Adv. Colloid Interface Sci. 289 (2021) 102363. Crossref
(5). I. Gussenov, Study of the possibility of gel-forming polymer application for the productivity increase of oil wells. Manuscript for the PhD degree, Kazakh National Research Technical University. N/A K.I. Satbayev, 2017.
(6). Yu.A. Ketova, B. Bai, A.L. Kazantsev, S.V. Galkin, Perm Journal of Petroleum and Mining Engineering 19 (2019) 251–262. Crossref
(7). M. Unomah, S. Thach, R. Shong, J. App, T. Zhang, D.H. Kim, T. Malik, V. Dwarakanath, Performance of Conformance Gels Under Harsh Conditions, in: Day 3 Mon, April 16, 2018, SPE, 2018. Crossref
(8). A. Al Brahim, Y. Eriyagama, B. Bai, T. Schuman, SPE J. 28 (2023) 1829–1841. Crossref
(9). H. Guo, J. Ge, Q. Wu, Z. He, et al., Gels 8 (2022) 166. Crossref
(10). G. Zhang, L. Chen, J. Ge, P. Jiang, X. Zhu, Colloids Surf. A Physicochem. Eng. Asp. 483 (2015) 96–103. Crossref
(11). S.L. Bryant, M.R. Rabaioli, T.P. Lockhart, SPE Prod. Fac. 11 (1996) 209–215. Crossref
(12). I. Gussenov, Eurasian Chem.-Technol. J. 25 (2023) 157–163. Crossref
(13). M.W. Donnelly, M. Hailemichael, M.W. Liberatore, J. Appl. Polym. Sci. 132 (2015). Crossref
(14). R.S. Seright, “Clean Up” of Oil Zones after a Gel Treatment, in: All Days, SPE, 2005. Crossref
(15). R.S. Seright, Optimizing Disproportionate Permeability Reduction, in: All Days, SPE, 2006. Crossref
(16). X. Sun, B. Bai, Understanding the Plugging Performance of HPAM-Cr(III) Polymer Gel For CO2 Conformance Control, in: All Days, CMTC, 2019. Crossref
(17). K. Asghari, L. Taabbodi, Laboratory Investigation of Indepth Gel Placement for Carbon Dioxide Flooding in Carbonate Porous Media, in: All Days, SPE, 2004. Crossref
(18). L. Kuzmichonok, K. Asghari, P. Nakutnyy, Performance of Polyacrylamide-Chromium (III) Gel in Carbonate Porous Media: Effect of Source of Crosslinker on Disproportionate Permeability Reduction and Gel Strength, in: Canadian International Petroleum Conference, Petroleum Society of Canada, 2007. Crossref
(19). P. Valois, E. Verneuil, F. Lequeux, L. Talini, Soft Matter 12 (2016) 8143–8154. Crossref
(20). S. Karimi, S. Kazemi, N. Kazemi, J. Nat. Gas Sci. Eng. 34 (2016) 1027–1033. Crossref
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