Chemistry and Technology of Samarium Monosulfide

Authors

  • O. V. Andreev Tyumen State University, Volodarskogo str. 6, Tyumen, 625003 Russia
  • V. V. Ivanov Closed joint-stock company "TECHNOCOMPLEKT" , Shkolnaya str. 10a, Dubna, Moscow oblast, 141981 Russia
  • A. V. Gorshkov Closed joint-stock company "TECHNOCOMPLEKT" , Shkolnaya str. 10a, Dubna, Moscow oblast, 141981 Russia
  • P. V. Miodushevskiy Dubna International University, Universtitetskaya str. 19, Dubna, 141980 Russia
  • P.O. Andreev Tyumen State University, Volodarskogo str. 6, Tyumen, 625003 Russia

DOI:

https://doi.org/10.18321/ectj396

Abstract

Samarium monosulfide SmS (Fm3m, а = 5.967 Å, ΔЕ = 0.23 V, n = 1020 cm–1, σ = 500 Ω–1 cm–1, α = 350 μВ/K) is a thermoelectric material (Z>1) and, at the same time, a pressure-sensitive material (K≥40–50). Samarium monosulfide is a daltonide phase with a solid solution whose extent is mostly in the range of cationic vacancies: Sm1+x S1-x2x (x = 0–0.035; 1750 K). The congruent melting temperature of SmS is 2475 K. In the Sm–S system, Sm3S4 crystallizes from melt without change in composition. Samarium monosulfide thermally dissociates to Sm3S4 and Sm. Largescale SmS lots are produced from samarium and sulfur. Synthesis is carried out in sealed-off silica glass ampoules at 500–1350 K followed by heat treatment in tantalum crucibles at 1500–2400 K. The reaction of metal samarium with sulfur results in the formation of sulfide phases that coat the samarium surface in the following order: SmS, Sm3S4, Sm2S3, and SmS2. Subsequent annealing at 1500–1800 K provides SmS yields up to 96–97 mol %. Equilibrium minor phases for SmS are Sm3S4, Sm2О2S, and Sm. X-ray amorphous SmS was prepared by reacting organic samarium compounds with sulfur or H2S. The samarium (+2) oxidation state determines the chemical specifics of SmS. 90–120 μm SmS powders are thermally hydrolyzed starting at 600 K with Н2 evolution and oxidize starting at 520 K to yield Sm3S4 and then Sm2О2S phases. A 90–120 μm SmS fraction for film deposition by flash evaporation is prepared by milling annealed SmS samples. Tablets 75 mm in diameter for use in magnetron sputtering are pressed from a <60-μm fraction.

References

[1]. I. Groshev, I. Poluhin, Komponenty i tehnologii [Components and technologies] 8 (2014) 126–133 (in Russian).

[2]. V.V. Kaminskiy, N.N. Stepenov, N.M. Volodin, Yu.N. Mishin, raketnaja tehnika i kosmonavtika [Astronautics and missilery] 17 (1) (2013) 11–16 (in Russian).

[3]. O.V. Andreev, L.N. Monina, V.O. Andreev, A.V. Elyishev, O.Yu. Mitroshin. Phase equilibria, synthesis, phase structure in the 3d-, 4f-elements sulphides systems. Textbook. Tyumen: Tyumen State University Publishing. 2014. 512 p. (in Rissian).

[4]. A.V. Golubkov, V.M. Sergeeva, Russian Journal of General Chemistry 26 (6) (1981) 645–653.

[5]. V.V. Kaminskiy, T. Kuzuya, S.Hirai, C.M. Soloviev, Physics of the Solid State 54 (7) (2012) 1269–1271.

[6]. V.V. Kaminskiy, N.V. Sharenkova, L.V. Vasil'yev, S.M. Solov'yev, Physics of the Solid State 47 (2) (2005) 217–219.

[7]. V.V. Kaminskiy, N.N. Stepanov, A.A. Molodykh, Physics of the Solid State 52 (7) (2010) 1269–1270.

[8]. V.V. Kaminskiy, V.A. Sidorov, N.N. Stepanov, M.M. Kazanin, A.A. Molodykh, S.M. Solov'yev, Physics of the Solid State 55 (2) (2013) 257–259.

[9]. I.N. Barinov. Components and technologies 5 (2009) 12–15.

[10]. Y.I. Sucharev, T.I. Prolubnikova, I.I. Lebedeva. Eurasian Chemico-Technological Journal 14 (1) (2012) 61–72.

[11]. O. Prikhodko, N. Almasov, N. Korobova, Eurasian Chemico-Technological Journal 12 (3) (2010) 279–283.

[12]. V.M. Egorov, V.V. Kaminskiy, M.M. Kazanin, S.M. Solov'yev, A.V. Golubkov, Technical Physics Letters 41 (8) (2015) 50–54.

[13]. V.V. Kaminskiy, S.M. Solov'yev, A.V. Golubkov, Technical Physics Letters 28 (6) (2002) 29–54.

[14]. V.V. Kaminskikh, M.M. Kazanin, A.N. Klishin, S.M. Solov'yev, A.V. Golubkov, Technical Physics 81 (6) (2011) 150–152.

[15]. V.V. Kaminskiy, S.M. Solov'yev, Technical Physics Letters 31 (14) (2005) 45–49.

[16]. V.M. Egorov, V.V. Kaminskiy, Physics of the Solid State 51 (8) (2009) 1521–1522.

[17]. D.V. Zhuravskiy, G.P. Laskin, K.V. Misibk, S.Yu. Udovichenko. Tyumen state university herald 7 (2013) 98–103 (in Russian).

[18]. E.I. Yarembash and A.A. Eliseev. Rare-earth metal chalcogenides. Nauka. Moskow. 1975. 260 p. (in Russian).

[19]. I.G. Vasileva, Russian Journal of Physical Chemistry A. 80 (11) (2006) 1842–1847.

[20]. G.M. Kuz'micheva, O.V. Andreev, N.N. Parshukov, O.N. Reshetnikova, Russian Journal of Inorganic Chemistry 42 (11) (1997)1790–1792.

[21]. N.V. Podberezskaya, N.V. Pervuhina, I.G. Vasileva, S.A. Magarill, S.V. Borisov, Journal of Structural Chemistry 40 (3) (1999) 520–529.

[22]. I.G. Vasileva, Ya.I. Gibner, L.N. Kurochkina, Inorganic Materials 19 (3) (1983) 360–362.

[23]. O.V. Andreev, G.M. Kuzmicheva, N.N. Parshukov, S.S. Sikerin, Russian Journal of Inorganic Chemistry 44 (6) (1999)1024–1027.

[24]. A.A. Ganeev, A.R. Halikov, R.R. Karibov USATU Herald 11 (2) (2008) 116–122 (in Russian).

[25]. O.V. Andreev, V.B. Kharitonstsev, A.A. Polkovnikov, A.V. Elyshev, P.O. Andreev, Journal of Solid State Chemistry 7 (2015) 186–190.

[26]. V.M. Egorov, Fei Wang, V.V. Kaminskiy, Shinji Hirai, N.V. Sharenkova, Physics of the Solid State. 54 (1) (2012) 46–49.

[27]. K. Imura, K. Matsubayashi, H.S. Suzuki, K. Deguchi, N.K. Sato. Journal of Physics: Conference Series 121 (2008). P. 032014.

[28]. K. Matsubayashi, K. Imura, H.S. Suzuki, T. Mizuno, S. Kimura, T. Nishioka, K. Kodama, N.K. Sato, J. Phys. Soc. Jpn. 76 (6) (2007) 064601-1 –064601-6.

[29]. A.V. Golubkov, M.M. Kazanin, V.V. Kaminskii, V.V. Sokolov, S.M. Solov’ev, L.N. Trushinikova. Inorganic Materials 39 (12) (2003) 1251–1256.

[30]. V.G. Bamburov, O.V. Andreev, Russian Journal of Inorganic Chemistry 47 (4) (2002) 676–683.

[31]. P.V. Miodushevsky, P.O. Andreev, A.S. Vjsokih. Omsk University herald 4 (2011) 122–126 (in Russian).

[32]. O.V. Andreev, A.S. Vysokikh, V.G. Vaulin. Russian Journal of Inorganic Chemistry 53 (8) (2008) 1414–1418.

[33]. N.M. Volodin, Yu.N. Mishin, V.V. Kaminskiy, Yu.V. Zakharov. Lavochkin Association 2 (2012) 33–37 (in Russian).

[34]. N.M. Volodin, Yu.N. Mishin, V.V. Kaminskiy, Lavochkin Association 5 (2011) 51–55 (in Russian).

[35]. O.V. Andreev, N.N. Parshukov, V.M. Andreeva, Russian Journal of Inorganic Chemistry 39 (1) (1994) 6–9.

[36]. O.V. Andreev, O.A. Sadovskaya, E.Yu. Shabalina, Russian Journal of Inorganic Chemistry 35 (3) (1990) 11–16.

[37]. O.V. Andreev, M.N. Bochkarev, N.M. Volodin, T.V. Nekrasova, A.V. Protchenko, Organometallic chemistry
2 (1993) 1361–1362.

[38]. O.V. Andreev, M.N. Bochkarev, Т.V. Nekrasova, A.V. Protchenko, Russian Chemical Bulletin 44 (2) (1995) 233–235.

[39]. Michelle D. Regulacio, Neil Tomson, Sarah L. Stoll, Chem. Mater. 17 (2005) 3114–3121.

[40]. M.A. Signore, A. Taurino, M. Catalano, E. Bellini, G. DiGirolamo, A.M. Laera, F. Quaranta, L. Vasanelli, P. Siciliano, Thin Solid Films 556 (2014) 241–246.

[41]. M. Volodin, L.V. Zavyalova, A.I. Kirillov, S.V. Svechnikov, I.V. Prokopenko, A.V. Khanova, Semiconductor Physics, Quantum Electronics Optoelectronics 2 (2) (1999) 78–83.

[42]. G.A. Domrachev, L.V. Zav'yalova, G.S. Svechnikov, O.N. Suvorova, A.V. Khanova, E.A. Shchupak, L.A. Yarosh. Russian Journal of General Chemistry 73 (4) (2003) 593–599.

[43]. O.V. Andreev, V.G. Bamburov, L.N. Monina, I.A. Razumkova, A.V. Ruseykina, O.Yu. Mitroshin, V.O. Andreev. Phase equilibria in the sulfide systems of the 3d-, 4f- elements. Ekaterrinburg, 2015. 309 p. (In Russian).

[44]. A.S. Vysokikh, O.V. Andreev, L.A. Golovina. Tyumen state university herald 3 (2007) 124–129 (in Russian).

[45]. O.V. Andreev, A.S. Vysokikh, I.P. Leven. Physical chemistry of high-tech materials. Taymen. 2007. 88 р.
(in Russian).

[46]. V. V. Kaminskii, M.M. Kazanin, Technical Physics Letters 34 (4) (2008) 361–362.

[47]. A.V. Golubkov, V.A. Didik, V.V. Kaminskii, E.A. Skoryatina, V.P. Usacheva, N.V. Sharenkova. Physics of the Solid State 47 (7) (2005) 233–1235.

[48]. V.V. Kaminskii, M.M. Kazanin, L.N. Golubkov, Тechnical Physics 82 (6) (2012) 142–144.

[49]. O.V. Andreev, Russian Journal of Inorganic Chemistry 34 (6) (1989) 1603–1606.

[50]. O.V. Andreev, Russian Journal of Inorganic Chemistry 34 (2) (1989) 482–486.

Downloads

Published

2016-01-20

How to Cite

Andreev, O. V., Ivanov, V. V., Gorshkov, A. V., Miodushevskiy, P. V., & Andreev, P. (2016). Chemistry and Technology of Samarium Monosulfide. Eurasian Chemico-Technological Journal, 18(1), 55–65. https://doi.org/10.18321/ectj396

Issue

Vol. 18 No. 1 (2016)

Section

Articles

License

You are free to: Share — copy and redistribute the material in any medium or format. Adapt — remix, transform, and build upon the material for any purpose, even commercially.

Eurasian Chemico-Technological Journal applies a Creative Commons Attribution 4.0 International License to articles and other works we publish.

Subject to the acceptance of the Article for publication in the Eurasian Chemico-Technological Journal, the Author(s) agrees to grant Eurasian Chemico-Technological Journal permission to publish the unpublished and original Article and all associated supplemental material under the Creative Commons Attribution 4.0 International license (CC BY 4.0).

Further distribution of this work must maintain attribution to the author(s) and the published article’s title, journal citation, and DOI.