Hydrogenation of Aromatic Nitrocompounds on Supported Mono- and Bimetallic Catalysts

Authors

  • A. T. Massenova D.V.Sokolsky Institute of Organic Catalysis and Electrochemistry,142 Kunaev St., 480100 Almaty, Kazakhstan
  • L. R. Sassykova D.V.Sokolsky Institute of Organic Catalysis and Electrochemistry,142 Kunaev St., 480100 Almaty, Kazakhstan

DOI:

https://doi.org/10.18321/ectj363

Abstract

Catalytic hydrogenation of substituted aromatic nitrocompounds and hydrocarbons has been studied. It was established that monometallic Pd-catalysts were suitable for reduction of nitrogroups. Bifunctional catalysts such as Rh-Pt, Rh-Pd, Pd-Ru and Rh-Ru were used for hydrogenation of both aromatic ring and nitrogroup and sequence of their hydrogenation depended on support nature. Over Rh-Pt alumina supported catalysts consequent hydrogenation of NO2 and benzene ring took place, over silica supported catalysts their consecutive hydrogenation was observed. Such catalytic properties of bimetallic Rh-Pt and Rh-Pd catalysts probably connected with metal-metal interaction leading to optimal adsorption strength of uniformly adsorbed hydrogen. The optimal reaction conditions (temperature and hydrogen pressure) have been elaborated for synthesis of alicyclic amines with 95-99% yields.

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Published

2000-02-20

How to Cite

Massenova, A. T., & Sassykova, L. R. (2000). Hydrogenation of Aromatic Nitrocompounds on Supported Mono- and Bimetallic Catalysts. Eurasian Chemico-Technological Journal, 2(1), 101–105. https://doi.org/10.18321/ectj363

Issue

Vol. 2 No. 1 (2000)

Section

Articles

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