Analytical and Numerical Study of the Impact of Methanogenic Bacteria on Gas Composition in Underground Hydrogen Storages

Authors

  • A. Toleukhanov Al-Farabi Kazakh National University, Almaty, Kazakhstan
  • M. Panfilov Laboratoire d’Energétique et de Mécanique Théorique et Appliquée, CNRS/University of Lorraine, France
  • A. Kаltayev Al-Farabi Kazakh National University, Almaty, Kazakhstan

DOI:

https://doi.org/10.18321/ectj250

Abstract

Unlike natural gas, hydrogen gas mixtures stored in underground reservoirs undergo active chemical transformations under the influence of methanogenic microorganisms inhabiting in porous reservoirs. They lead to reduction of hydrogen and carbon dioxide concentrations and increase methane concentration. This chemical activity coupled with bacterial dynamics and gas/water flow through porous medium causes the phenomenon of self-organization such as the occurrence of autowave spatial structures, whose dynamics is characterized by a multiplicity of scenarios and bifurcations between them. In this paper we continue to develop the qualitative theory of self-organization in underground hydrogen storage, for more complicated
cases that include the mechanism of chemotaxis, which is one of the main types of bacterial movement, and takes into account the flow of both phases. The analysis of scenarios is based on the model of two-phase compositional flow coupled with population dynamics.

References

[1]. J. Andrews, B. Shabani, Int. J. Hydrogen Energy 37(2) (2012) 1184–203.

[2]. D.R. Simbeck, Energy 29 (2004) 1633–1641.

[3]. W. Zittel, and R. Wurster, Hydrogen in the energy sector. Laudwig-Bolkow Systemtechnik GmbH, 7, Aug., 1996.

[4]. J.B. Taylor, J.E.A. Alderson, K.M. Kalyanam, A.B. Lyle, L.A. Phillips, Int. J. Hydrogen Energy 11(1) (1986) 5–22.

[5]. G.G. Bulatov, Underground storage of hydrogen.Ph.D. Thesis, Moscow Gubkin Oil and Gas University, 1979 (in Russian).

[6]. P.O. Carden and L. Paterson, Int. J. Hydrogen Energy 4(6) (1979) 559–569.

[7]. F. Buzek, V. Onderka, P. Vancura, I. Wolf, Fuel 73(5) (1994) 747–752.

[8]. P. Smigai, M. Greksak, J. Kozankova, F. Buzek, V. Onderka, I. Wolf, FEMS Microbiol. Ecol. 73 (1990) 221–224.

[9]. M. Panfilov, G. Gravier, S. Fillacier, Underground storage of H2 and H2–CO2–CH4 mixtures. In: Proc. ECMOR-X: 10th European Conference on the Mathematics of Oil Recovery, 4–7 September 2006 Amsterdam, the Netherlands, Ed. EAGE, 2006, paper A003.

[10]. M. Panfilov, Undeground storage of hydrogen: self-organisation and methane generation. Transport in Porous Media 85 (2010) 841–865.

[11]. M. Panfilov, Underground and pipe-line storage of hydrogen. In: Compendium of Hydrogen Energy, Ed. R.B. Gupta, Eslevier, 2015, 91–115.

[12]. A. Toleukhanov, M. Panfilov, I. Panfilova, A. Kaltayev: Bio-reactive two-phase transport and population dynamics in underground storage of hydrogen: natural self-organisation. In: Proc. ECMOR-XIII: 13th European Conference on the Mathematics of Oil Recovery, 10–13 September 2012 Biarritz, France, Ed. EAGE, 2012, paper B09.

[13]. A.M. Turing, Philos. Trans. R. Soc. London, Ser. B 237 (1952) 3–72.

[14]. Handbook of Mathematical Functions with Formulas, Graphs, and Mathematical Tables, Eds. M. Abramowitz and I.A. Stegun “Chapter 10”, New York: Dover, p. 446, (1965).

[15]. D. George Parker, “Hydrogen Cavern operation”, Presentation at IPCE 2006, ConocoPhillips, Bartlesville, OK, USA.

[16]. A.S. Lord, “Overview of Geological Storage of Natural Gas with Emphasis on Assessing the Feasibility of Storing Hydrogen”, Sandia Report, California, July 2008.

[17]. Howard B.J. Stone, Ivo Veldhuis and R. Neil Richardson, Underground hydrogen storage in the UK, Geological Society, London, Special Publications, 313 (2009) 217–226.

[18]. C. Padró, V. Putsche, “Survey of the Economics of Hydrogen Technologies”; Technical Report, National Renewable Energy Laboratory, Colorado, USA 1999.

[19]. S. Foh, M. Novil, E. Rockar, P. Randolph, “Underground Hydrogen Storage”, Institute of Gas Technology, Brookhaven National Laboratory, New York, December 1979.

Downloads

Published

2015-07-20

How to Cite

Toleukhanov, A., Panfilov, M., & Kаltayev A. (2015). Analytical and Numerical Study of the Impact of Methanogenic Bacteria on Gas Composition in Underground Hydrogen Storages. Eurasian Chemico-Technological Journal, 17(3), 243–249. https://doi.org/10.18321/ectj250

Issue

Section

Articles