Investigation of Inhibitor Polyphosphate Properties for Rotating Steel Disk Electrode in Potassium Nitrate Solution

Authors

  • E. A. Dorokhova Department of Chemistry, al-Farabi Kazakh State National University, 95 Karasai Batyr Str., 480012, Almaty, Kazakhstan
  • B. D. Burkitbaeva Department of Chemistry, al-Farabi Kazakh State National University, 95 Karasai Batyr Str., 480012, Almaty, Kazakhstan
  • I. B. Melsitova Department of Chemistry, al-Farabi Kazakh State National University, 95 Karasai Batyr Str., 480012, Almaty, Kazakhstan
  • T. Z. Ahkmetov Department of Chemistry, al-Farabi Kazakh State National University, 95 Karasai Batyr Str., 480012, Almaty, Kazakhstan
  • V. I. Kapralova Department of Chemistry, al-Farabi Kazakh State National University, 95 Karasai Batyr Str., 480012, Almaty, Kazakhstan

DOI:

https://doi.org/10.18321/ectj375

Abstract

Inhibition properties of a number of glass-like polyphosphates on 65J steel were investigated using the gravimetry and methods potassium nitrate solution polarization curves in a 0,1M (pH=6,05). The possibilities
of optimum experimental conditions were considered as well. Basing on the experimental data the inhibition
coefficient and protective effect were found. The inhibiting action of polyphosphates, apparently, is due
to the formation of inhomogeneous protecting film on the steel surface.

References

(1). S. Konstantinov. Inventor and Rationalizer, 4:20, 1986.

(2). V.I. Kapralova, et al. Application of silicopolyphosphate inhibitors for protection of water-supply systems // Petroleum and gas, 1999, № 2, P. 114-120.

(3). Lo Zhu, Hu Rong // Proc. Conf. 28: Corros. - Tax Forever, Perts. 21-25 Nov., 1998. Vol.1. - Leederville, 1988. - P. 4/3. 1-4/3. 8.

(4). Yashiro H., Kami H., Kosaks T., Tanno K. // Werkst. Und Korros. - 1994 - 45, #1. P. R10.

(5). B.L. Geizin, I.V. Strizhevsky, F.A. Shevelev. Corrosion and protection of municipal waterpipes. M., 1979. P.398.

(6). D.S. Robinson. Corrosion inhibitors. - M., 1983. P.271.

(7). G.B. Hatch, O. Rice. Threshold treatment of water systems prevention of corrosion and scale formation by means of glass-like phosphate, Ind. Eng. Chem; 37, #8, 710-715 (1945).

(8). G.B. Hatch, O. Rice. Prevention of corrosion by means threshold water treatment- factors effecting formation of protective films on a surface of steel in water treated with glass-like phosphates, Ind. Eng. Chem, 32, 1572-1579 (1940).

(9). I.E. Apeltsin, E.F. Zolotova. Application of low soluble metaphosphates for water treatment // Water-supply and satinary facilities, №4, 34-36 (1959).

(10). I.C. Lamb, R. Eliassen . Mechanism of Corrosion Inhibition by the metaphosphate sodium // I. Am. Water Works Ass. - 1954 - 46. 445-460.

(11). I.B. Sumcden, Z.Szklarska - Smialonska. The properties of the Films Formed on Iron exposed to Suhibition Solution // Corrosion. 1978. - 345.169 - 176.

(12). S. Horner, E. Plifke. Corrosion inhibitor // Werkst und Rorrosion. - 1985. - 36, 12.545 - 553.

(13). R.B. Meaus . The Electrochemical Action of Inhibitors // Corrosion. - 1985. - 11, 8.50 - 52.

(14). G. B. Hatch, Formation of protective film by glass-like phosphates, Ind. Eng. Chem., 44, 1775 - 1780 (1952).

(15). D.A. Yakovleva, R.M. Bikchektaev et.al. Corrosion protection and increase in service life of heat-exchange equipment in cooling systems of petroleum refineries and petroleum-chemical plants. - 1985. - p. 38.

(16). A.B. Bekturov, D.Z. Serazetdinov, V.A. Urikh. Physicochemical basis for polyphosphate manure / fertilizers production. Alma-Ata, 1979. - p. 248.

(17). L.I. Antropov . Theoretical electrochemistry. M.: Higher School, 1984. p. 519.

(18). B.B. Damaskin, O.A. Petriy , B.I. Poglovchenco . Electrochemistry Practicum. M.: Higher School, 1991., p. 247.

(19). L.I. Antropov. Theoretical electrochemistry. M.: Higher School, 1969, p. 474.

(20). O.M. Agres . Alternative technique of graphical determination of corrosion inhibitor efficiency basing on polarization measurements. – Journ. Appl. Chem., 1992, v.65, № 3, p. 567-570.

(21). O. Yu. Fishbbein, V.I. Kapralova, et al. Inhibiting compositions on the basis of manganese polyphosphates // Petroleum and gas. 1999, №1.P. 55-57.

Downloads

Published

2000-06-12

How to Cite

Dorokhova, E. A., Burkitbaeva, B. D., Melsitova, I. B., Ahkmetov, T. Z., & Kapralova, V. I. (2000). Investigation of Inhibitor Polyphosphate Properties for Rotating Steel Disk Electrode in Potassium Nitrate Solution. Eurasian Chemico-Technological Journal, 2(2), 167–173. https://doi.org/10.18321/ectj375

Issue

Section

Articles