Hydration of Olefins into Alcohols
DOI:
https://doi.org/10.18321/ectj22Abstract
Review on hydration of olefins into alcohols is presented. It is shown that mineral acids (H2SO4, H3PO4), their salts, molybdenum and tungsten heteropolyacids of 12 range and zeolites are used as the catalysts. The reaction proceeds with high selectivity at 1-100 atm pressure and 473-673 K through carbonium ion formed via interaction of adsorbed olefin with proton H+ and then with H2O yielding alcohol. It is concluded that for gas phase hydration of olefins use of proton substituted zeolites with ratio Si / Al = 7 - 9 and strength of Bronsted centers from -8.2 to - 5.6, with high heat of adsorption for olefins and low heat of adsorption for water is effective instead of mineral acids on SiO2.
References
2. Dossumov K., Tungatarova S.A., Massalimova B.K., Kuzembay K.K. MoCrGa catalyst of selective oxidation of oil gas into ketons, aldehydes and alcogols//XVIII Mendeleev congress in the general and inorganic chemistry, Moscow., Russia. 3, 253 p. (2007).
3. Dzisko M.T. Prospects for development of heterogeneous catalytic processes, Abstract of XIV International conference on chemical reactors. Tomsk, 14 IC SB, Novosibirsk, (1998).
4. Tanabe K. Catalysts and catalytic processes. M. Mir, (1993), 172 p.
5. Valakin V.P., Production of synthetic ethanol.M., Chimia, (1976).
6. Brunstein B.A., Klimenko V.L., Cyrkin E.B. Production of alcohols from oil and gas raw materials. Leningrad, Nedra (1964), 198 p.
7. Agaguseynova M.M., Abdullayeva G.N. Oxygenated Complexes of Transition Metals in Alkene Oxidation Reaction//Materials of Azerbaijan-Russian Symposium with international participation “Catalysis for solving the problems of petrochemistry and oil refining”. September 28-30, 2010. Baku, Azerbaijan. PP-1. P.123-124.
8. A. Magauov. Oil & Gas of Kazakhstan, 4-5, 2010. P.127.
9. Innov. Patent RK # 21794, 2009, C07C 49/08
10. Okazaki S, Kurimata M., Jizuka T., Tanabe K., Bull. Chem. Soc, Japan, 60: 37, (1987).
11. Jsobe A., Yabyuchi Y., Jwasa N., Fakezawa N., Appl. Catalysis A: Gener. 194-195: 395 (2000).
12. Dorfman Y.A., Investigation of catalytic acetylene hydration in electrochemical system Ph.D. Thesis, ICN AS KazSSR, Almaty, (1966), 17 p.
13. Nogerbekov B.Y. Investigation of acetylene hydration in the presence of homogeneous catalysts based on copper complexes, Ph.D. Thesis, ICN AS KazSSR, Almaty, (1970), 21 p.
14. Segizbaeva S. Catalytic acetylene hydration in the presence of palladium and iron salts, Ph.D.Thesis. Almaty KazGU (1970), 18 p.
15. Aoshima A., Yamamtsu S., Yamaguchi T, Nippon Kagaku Kaishi 976 (1987).
16. Kozhevnikov I.V., Khankhasaeva S.T., Kulikov S.M. Kinet. Katal 29: 76, (1998).
17. Kozhevnikov I.V., Khankhasaeva S.T., Kulikov S.M., 30:50, (1989).
18. Ushikubo T., Kurashige M. and al., Catal Lett.,69:83 (2000).
19. Kaiser J.K., Beuther H., Mooree L.D. at al., J. GEC. Product Research and Development, 296, (1962).
20. Zakumbaeva G.D., Shapovalova L.B. Eurasian Chem. Tech.J., 2: 11 (2000).
21. Isakov Y.I. Neftekhimia, 38 : (6), 404. (1998).
22. Minachev C.M., Mortikov E.S. Masloboev A.A. et al. Neftekhimia, 16: (p): 846, (1976).
23. Tsydulevsky A.M., Novikova L.A., Kondratiev V.A. Neftekhimia, 19: (5): 771, (1979).
24. Tolkacheva L.N., Novikova L.A., Plakhotnik V.A., et al. Neftekhimia, 23 : (p): 803, (1983).
25. Tolkacheva L.N., Afanasiev B.A., Novikova L.A., et al. Neftekhimia, 26 : (5), (1987).
26. Tolkacheva L.N., Dmitriev R.V., Afanasiev B.A., et al. Neftekhimia, 25 : (5), 646, (1986).
27. Tolkacheva L.N., Novikova L.A., Mikheikin N.D., et al. Neftekhimia, 25: (5), 610, 1985).
28. Novikova L.A., Tolkacheva L.N., Plakhotnik V.A., et al. Neftekhimia 23 : (1), 72, (1983).
29. Iwamoto N., Tayima M., Kagawa Sn., J. Catal. (101): 195, (1986).
30. Ishihara T., Matsuo J., Ito M. and al., Ind. Eng. Chem. Res. 36 : 4427, (1997).
31. Francois Fayula, Rafael Jbarra and al., J. Catal. 88 : 60, (1984).
32. EP 798040A1, 1997, C07C 29/04.
33. US Patent # 5488185, 1996, C01C 29/04.
34. US Patent # 4956506, 1990, C07C 41/05.
35. US Patent # 5144084, 1992, C07C 31/10.
36. UK Patent # 2145415, 1985, C07C 29/04.
37. UK Patent # 2147290, 1985, C07C 29/04.
38. US Patent # S484013, 1984, C07C 29/04.
39. Tanabe K. Solid acids and bases. Mir, M. (1973), M.87,132.
40. Skibida N.P., Sakharov A.M., Emmanuel O.N. Totals of science and technology. Ser. Kinetika I Kataliz M., VINITI, 1986, vol.15, p.110.
41. Minachev K.M., Usachev M.Y., Rodin A.P. et al. Neftekhimia, 19:5,751,(1979).
42. Lenarda M. et al., J. Mol. Cat., 92 : (2), 201, (1994).
43. Adzhamov K.Y., Kasymov F.B., Alkhazov T.G. In: Mechanisms of Catalytic Reactions, III USSR Conference. Novosibirsk, IC SB RAS 1982, p. 66.
44. Alkhazov T.G., Adzhamov K.Y., Bagiev V.A. Neftekhimia, 19 : (5),757, 1979.
Downloads
Published
How to Cite
Issue
Section
License
You are free to: Share — copy and redistribute the material in any medium or format. Adapt — remix, transform, and build upon the material for any purpose, even commercially.
Eurasian Chemico-Technological Journal applies a Creative Commons Attribution 4.0 International License to articles and other works we publish.
Subject to the acceptance of the Article for publication in the Eurasian Chemico-Technological Journal, the Author(s) agrees to grant Eurasian Chemico-Technological Journal permission to publish the unpublished and original Article and all associated supplemental material under the Creative Commons Attribution 4.0 International license (CC BY 4.0).
Further distribution of this work must maintain attribution to the author(s) and the published article’s title, journal citation, and DOI.
