Nanodispersed Ni-catalysts with Additives in Partial Oxidation of Methane

Authors

  • N. A. Zakarina D.V.Sokolsky Institute of Organic Catalysis and Electrochemistry 142, Kunaev St., Almaty, 050010, Kazakhstan
  • G. V. Akulova D.V.Sokolsky Institute of Organic Catalysis and Electrochemistry 142, Kunaev St., Almaty, 050010, Kazakhstan
  • Ju. M. Arinkin D.V.Sokolsky Institute of Organic Catalysis and Electrochemistry 142, Kunaev St., Almaty, 050010, Kazakhstan

DOI:

https://doi.org/10.18321/ectj23

Abstract

Catalytic activity of Ni-Zn-surface-skeletal catalysts modi ed by Rh, Au, Ti, Mo and W in the reaction of methane partial oxidation has been studied. In uence of catalysts of conditions preparation on its catalytic activity was researched. It was shown that introduction of additives in Ni-Zn catalysts promote to increasing of activity in the process of methane partial oxidation to synthesis-gas and thermostability of skeletal Nicatalysts thanks to the change of its faseous composition and the predominance of reduced form of Ni in catalysts structure.

References

1. V.S. Arutyunov, O.V. Krylov Oxidative conversion of methane. Moscow: Science, (1998), 361 p.

2. S. Tang, K.L. Tan // Catal. Letters 51 (1998) 169-175.

3. N.C. Triantafyllopoulos, S.G. Neophytides // J.Catal. 217 (2003) 324-333.

4. S. Park, J.M. Vohs, R.J. Gorte // Nature (Gr. Brit.), (2000), v. 404, No 6775, pp. 265-267.

5. V.R. Choudhary, V.H. Rane, A.M. Rajput // Applid Catal. A: General 162 (1997) 235-238.

6. N.A. Zakarina, Ju.M. Arinkin, G.V. Akulova // In “Novosti nauki Kazakhstana” (Russian), Almaty, KazGosINTI, (1998), v.4, pp. 45-46.

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Published

2010-01-22

How to Cite

Zakarina, N. A., Akulova, G. V., & Arinkin, J. M. (2010). Nanodispersed Ni-catalysts with Additives in Partial Oxidation of Methane. Eurasian Chemico-Technological Journal, 12(1), 31–36. https://doi.org/10.18321/ectj23

Issue

Vol. 12 No. 1 (2010)

Section

Articles

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