Carbon Dioxide as a Source of Carbon in Chemical Synthesis
DOI:
https://doi.org/10.18321/ectj32Abstract
The catalytic activity of nanostructurized low per cent (1%) Co-Ni catalysts on the basis of glass cloth, obtained by “solution combustion” (SC) method, in the reaction of carbon dioxide of methane was studied. The physico - chemical characteristics of the obtained species were studied by the methods of X-ray phase analysis, SEM, TEM, TGA. It is found that SC method allows to obtain an active component on the surface of glass cloth in the form of nanopaticles. A high activity of the catalyst, the active component of which is cobalt, is revealed; the decrease in Co concentration in the matrix of glass cloth results in the decrease of activity in the reaction of carbon dioxide conversion of methane.
References
2. Krylov O.V., Mamedov A.H., Uspekhi khimii. 64: 935 (1995).
3. The patent of Germany 242627 (1973); C.A., 82: 7233 (1975).
4. The patent of Japan 7488819 (1972); C.A., 82: 125812 (1975).
5. Inomoto E., Chem. Letters. 427 (1974).
6. The patent of Japan 7588004 (1975); C.A., 83:178338 (1975).
7. Lapidus A.L., Yan Ju.B., Uspekhi khimii. 50:111 (1981).
8. Sheludjakov V.D., Kirilin A.D., Mironov V.F., Journal of General Chemistry. 45: 707 (1975).
9. Bestmann H.J., Denzel Th., Salbaum H., Tetrahedron Letters. 1275 (1974).
10. Yan Ju.B., Nefedov B.K. Synthesis based on carbon oxides . Moscow: Chemistry, 1987.
11. Kolomnikov I.S., Grigorjan M.H., Uspekhi khimii. 47: 603 (1978).
12. Kolomnikov I.S., Lysjak T.V., Uspekhy khimii. 59: 589 (1990).
13. Kolomnikov I.S., Stepanovska G., Tyrlin S., Volpin M.E., Journal of General Chemistry. 44: 1743 (1974).
14. Kolomnikov I.S., Lysjak T.V., Kolomnikov S.L., Kharitonov Ju., Uspekhi khimii. 57: 729 (1988).
15. Lapidus A.L., Pirozhkov S.A., Korjakin A.A., Izvestiya AN USSR. Ser. Chem. 2814 (1978).
16. Suerbaev Kh.A., Seilkhanov T.M. Polymeric materials based on carbon dioxide. Kokshetau:Sh.Ualikhanov
Kokshetau State University, 2006. 153 p.
17. Sakharov A.M., Rusak V.V., Iljin V.V., Zaretskii M.I., Nysenko Z.N., Semenov V.V., Proceedings of the VIII Intern. Scientific Conference on problems of the chemical technologies. Ufa: the Reactive, 2002. P. 177.
18. Rozovskii A.J., Lin G.I., Theoretical bases of methanol synthesis. Moscow: Chemistry, 1990. 272 p.
19. Rozovskii A.J., Uspekhy khimii. 58: 68 (1989).
20. Rozovskii A.J., Kinetica and Catalysis. 21: 97 (1980).
21. Tenner S., Hydrocarbon Process. 64: 106 (1983).
22. Rostrup-Nielsen J.R. Hansen J.H.B., J. Catal. 144: 38 (1993).
23. Rostrup-Nielsen J.R. Proceedings of the Symposium on Production of Fuels and Chemicals from Natural Gas. Amsterdam: Elsevier. 1988. P. 73.
24. M.Aresta and G.Forti. (ed.), Carbon Dioxide as a Source of Carbon: Biochemical and Chemical Uses. D. Reidel Publishing Company, Dordrecht 1987. 423 p.
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