Norbornadiene as a Universal Substrate for Organic and Petrochemical Synthesis

Authors

  • V. R. Flid Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571 Russia
  • O. S. Manulik Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571 Russia
  • D. V. Dmitriev Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571 Russia
  • V. B. Kouznetsov Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571 Russia
  • E. M. Evstigneeva Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571 Russia
  • A. P. Belov Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571 Russia
  • A. A. Grigor’ev Lomonosov State Academy of Fine Chemical Technology, pr. Vernadskogo 86, Moscow, 117571 Russia

DOI:

https://doi.org/10.18321/ectj549

Abstract

A wide range of rare polycyclic hydrocarbons can be obtained through catalytic processes involving  norbornadiene (NBD). The problem of selectivity is crucial for such reactions. The feasibility of controlling
selectivity and reaction rate has been shown for cyclic dimerization, co-dimerization, isomerization and allylation of NBD. Kinetic rules have been scrutinized. Consistent mechanisms have been proposed. Factors
affecting directions of the reactions and allowing us to obtain individual stereoisomers quantitatively, have been established. A series of novel unsaturated compounds has been synthesized; they incorporate a set of double bonds with different reactivity and can find an extremely wide range of applications.

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Published

2001-08-20

How to Cite

Flid, V. R., Manulik, O. S., Dmitriev, D. V., Kouznetsov, V. B., Evstigneeva, E. M., Belov, A. P., & Grigor’ev, A. A. (2001). Norbornadiene as a Universal Substrate for Organic and Petrochemical Synthesis. Eurasian Chemico-Technological Journal, 3(2), 73–90. https://doi.org/10.18321/ectj549

Issue

Vol. 3 No. 2 (2001)

Section

Articles

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