Carbon Dioxide Reforming of Methane over Zeolite-containing Catalysts

Authors

  • S. S. Itkulova D.V. Sokolsky Institute of Organic Catalysis & Electrochemistry 142, Kunaev str., Almaty, 050010, Kazakhstan

DOI:

https://doi.org/10.18321/ectj285

Abstract

Reforming of methane by carbon dioxide (dry reforming of methane) has been studied over the series of the 5% Со-М/Al2O3+zeolite catalysts. The effect of zeolite (type, module, and amount) added to support composition on performance of the Со-М/Al2O3 catalyst in dry reforming has been examined. It has been shown that syngas is a main product of dry reforming over the zeolite-containing catalysts. Also, some amount (up to 3%) of acetic acid is produced. The yield of syngas and acetic acid depends on nature and amount of zeolite and process conditions.

References

1. Wilhelm, D.J., Simbeck D.R., Karp, A.D., and Dickenson, R.L., Fuel Processing Technology (2001) 71, P. 139.

2. Claridge, J. B., York, A.P. E., Brungs, A.J., Marquez-Alvarez, C., Sloan J., Tsang, S. C., and Green M.L.H., J. Catal. (1998) 180, P.85.

3. Baiker A., In Creenhouse Control Technologies; Riemer, P., Eliasson, B., Wokaun, A., Eds.; Elsevier Science Ltd.: New York (1999), P. 391.

4. Rostrup-Nielsen J.H., Hansen J.H.B., J.Catal. (1993) V. 144, P. 38.

5. Erdohelyi, A., Czerenyi J., Papp E., and Solymosi, F., Appl. Catal. A (1994) V. 105, P. 205.

6. Vernon, P.D.F., Green, M.L.H., Cheetman, A.K., and Ashcroft A.T., Catal. Today (1992) V.13, P. 17.

7. Krylov, O.V., Mamedov, A.K., and Mirzabekova, S.R., Catal. Today (1998) V. 42, P. 211.

8. Zhang, Z. L., Tsipouriari, V. A., Efstathiou, A. M., and Verykios, X. E., J. Catal. (1996) V. 158, P. 51.

9. Zhang, K., Kogelschatz, U., and Eliasson, B., Energy & Fuels (2001) V. 15, P. 395.

10. Tsang, S.C., Claridge, J.B., and Green, M.L.H., Catalysis Today (1995) V. 23, P. 3.

11. Souza, M. M. V. M, Aranda, D. A. G., and Schmal, M., J. of Catal. (2001) V. 204, P. 498.

12. Ruckenstein, E., and Wang, H. Y., J. Catalysis (2002) V. 205, P. 289.

13. Itkulova Sh. S., Zhunusova K. Z., and Zakumbaeva G. D., J. Appl. Organometal. Chem. (2000) V. 14, P. 850.

14. Itkulova, Sh. S., Zhunusova, K. Z., Chanycheva, I. S., Zakumbaeva, G. D., Eur.ChemicoTechnological
Journal (2000) V. 2, N 1, P.41.

15. Itkulova Sh. S., in NATO Science Series, II: 69 (Principles and Methods for Accelerated Catalyst Design and Testing), Eds.: E.G. Derouane, V. Parmon, F. Lemos, and F. Ribeiro. Springer (2002) P. 407.

16. Itkulova, Sh.S., Zhunusova, K.Z., and Zakumbaeva G.D., Bull. Korean Chem. Soc. (2005) V. 26, No 12, P. 2017.

17. Richardson, J. T., and Paripatyadar, S. A., Appl. Catal. (1990) 61, P. 293.

18. Qin, D., and Lapszewicz, J., Catal. Today 21, 551 (1994).

19. Nakamura, J., Aikawa, K., Sato, K., and Uchijima, T., Catal. Lett. (1994) 25, P. 265.

20. Kim, J. H., Sub, D. J., Park, T. J., Kim, and K. L., Appl. Catal. A (2000) 197, P. 191.

21. Taniguchi, Y., Hayashida, T., Kitamura,T., and Fujiwara, Y. Advances in Chemical Conversions for Mitigating Carbon Dioxide. Inui, T., Anpo, M., Izui, K., Yanagida, S., Yamaguchi T. (Editors). Studies in Surface Science and Catalysis (1998) V.114.

22. Chang, J.-S., Park, S-E., Yoo, J. W., and Park, J.-N. J. Catal. (2000)195, P. 1.

23. Osaki, T., Horiuchi, T., Suzuki, K., and Moil, T. Appl. Catal. A: General (1997) 155, P. 229.

24. Horiuchi, T., Sakuma, K., Fukui, T., Kubo, Y., Osaki, T., and Mori, T., Appl. Catal. A:General (1996) 144, P.111.

25. Zhang, K., Kogelschatz, U. , and Eliasson, B., Energy & Fuels (2001)15, No. 2,P. 401.

26. Zhang, Z. L., Tsipouriari, V. A., Efstathiou, A. M., and Verykios, X. E., J. Catal. (1996) V. 158, P. 51.

27. Zhang, Z. L., Verykios, X. E., MacDonald, S. M., and Affrossman, S., J. Phys. Chem. (1996) 100, P. 744.

28. Stagg, S. M., Romeo, E., Padro, C., and Resasco, D. E., J. Catal. (1998) V. 178, P. 137.

29. Bitter, J. H., Seshan, K., and Lercher, J. A., J. Catal. (1999) V. 183, P. 336.

30. Kim, J. H., Sub, D. J., Park, T. J., Kim, and K. L., Appl. Catal. A (2000) 197, P. 191.

31. Rostrup-Nielsen, J. R., in “Catalysis Science and Technology”, J. R. Anderson and M. Boudart, Eds., Springer-Verlag, Berlin (1984) V. 5, P. 1.

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Published

2009-09-20

How to Cite

Itkulova, S. S. (2009). Carbon Dioxide Reforming of Methane over Zeolite-containing Catalysts. Eurasian Chemico-Technological Journal, 11(3), 231–237. https://doi.org/10.18321/ectj285

Issue

Vol. 11 No. 3 (2009)

Section

Articles

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