Sorption of Richlokain on Polycarboxylic Acid Gels
DOI:
https://doi.org/10.18321/ectj319Abstract
The sorption immobilization of richlokain on gels of polyacrylic acid (PAAG) or polymethacrylic acid (PMAAG) has been studied. By a number of methods – equilibrium swelling, potentiometry, IR-spectroscopy, and sorption it has been shown that binding of richlokain with these gels leads to the complex formation owing to the electrostatic interaction, which is stabilised by the hydrophobic and hydrogen bonds. Effect of an ionic force, reagent concentration, cross-link degree, hydrophobic nature of gels, and pH of solutions on the sorption process has been studied.
References
1. I.V. Bereszin. "Study in the field of fermentative catalysis and enzyme engineering", Selected papers.
Moscow, Nauka, 1990, p. 384.
2. I.Yu. Galaeve, B. Mattiason. Trends in Biotechnology, 1999, V.17, p.335.
3. G.Ya. Kivman, Yu.V. Lyashenko, E.Z. Rabinovich, L.I. Fleyderman. Journ.Chem.Pharm (Russia), 1994, No3,
p. 21.
4. E.N. Efremenko, V.J. Lozinsky, V.S. Sergeva et al. J. Biochem. Biophys. Methods. 51, 2002, p. 1957.
5. "Immobilized ferments: The modern state and perspectives" Edit. I.V. Berezin et al. Moscow: MSU, 1976, V.1, p. 296, V.2, p. 356.
6. M.K. Beisebekov, J.A. Abilov, A.K. Toktabayeva, N.M. Zhunusbekova, K.A. Zhyirenchina. Abstracts of the International Microsymposium "Colloids and surfaces", Almaty, 1998. p. 29.
7. A.K. Toktabayeva, A.K. Abilov, M.K. Beisebekov and Sh. S. Ahmedova. Proceed. The 5th Intern. Symp. of Turkish Languages Countries on Polymers and Polymer Composites. Almaty, 1999, p. 37.
8. K.M. Saldadze. Ion-exchange tar. Edition of the Academy of Sciences of USSR, 1959, p.55.
9. A.S. Sharifkanov, S.S. Akhmedova, K.B. Murzagulova, G.I. Samorina, G.A. Galenko-Yaroshevskii. Patent of the RK (Kazakhstan), No1391, 1998.
10. S.R. Rafikov, V.P. Budtov and Yu.B. Monakov. Introduction in physico-chemistry of polymers, Moscow, Nauka, 1978, p. 335.
11. M.M. Feldshtein, A.B. Zezin. Molec. Biology (Russia), 1974, V. 8, No1, p. 142.
12. H.K. Ospanov. The thermodynamic and kinetic of heterogeneous processes. Almaty (Kazakhstan),
Kitap, 1990, p. 155.
13. E. Marshell. Biophysical chemistry. Moscow: Mir, 1981. p. 358.
14. M.A. Landau. Molecular mechanism of action of physiologically active compounds. Moscow: Nauka, 1981, p. 259.
15. N.I. Nikolaev. Diffusion in membranes. Moscow: Chimiya. 1980, p. 132.
16. Crank I. The Mathe matics of Diffusion. Oxford, Clarendon Press.1956, p. 347.
17. V.R. Ryabina, S.G. Starodubtsev and A.R. Khokhlov. Journ. Vysokomol. Soed (Russia), 1990, V. (A) 32, No5,
p. 969.
18. Yu.E. Kirsh and L.V. Sokolova. Journ. Chem.- Pharm. (Russia), 1983, No6, p. 711.
19. E.A. Bekturov, L.A. Bimendina, and G. K. Mamytbekov. Complex of water soluble polymers and hydrogels. Almaty: "Gylym" (Kazakhstan), 2002, p. 220.
20. Eishun Tsuchida, Koji Abe. Adv. Polym. Sci., 1982, V.45, p. 1.
21. G.V. Samsonov, E.B. Troyanskaya and G.E. Elkin. "Ion exchange. Sorption of organic compounds",
Leningrad, Nauka, 1969, p. 335.
22. G.E. Boyd, A.W. Adamson, L.S. Meyers. J. Amer. Chem. Soc., 1947, 69, p. 2836.
23. E.A. Bekturov and I.Z. Suleimenov. "Polymer hydrogels", Almaty (Kazakhstan), Nauka, 1998, p. 240.
24. T.B. Zheltonozhkaya, V.B. Rudnitskaya, B.V. Eremenko and V.G. Syromyatnikov. The colloidal Journal (Russia), 1996, V. 58, No3, p. 335.
25. V.B. Skobeleva, A.V. Zinchenko, V.B. Rogacheva, A.B. Zezin and V.A. Kabanov. Journ. Vysokomol.
Soed (Russia), 2001, V.(A) 43, No3, p. 505.
26. G.V. Samsonov. "Ion exchange", Moscow, Nauka, 1981, p. 137.
27. G.V. Samsonov and A.T. Melenevskii. "Soption and chromatographic methods of physico-chemical
bio-technology", Leningrad, Nauka, 1986, p. 230.
28. H. Kishimoto, K. Sumiola, Nagaya shiritsu daigaku yulzugakubu kerkun nempo. Annual Rept. Fac. Nagaya City Univ., 1971, No19, p. 45.
29. G. Nemethy, H.A. Scheraga, J.Phys. Chem., 1962, No66, p. 1773.
30. V.V. Pchelin, The colloidal Journ (Russia), 1972, V. 34, No5, p. 783.
31. M.K. Beisebekov. In: "Synthetic polyelectrolytes and surface-active compounds", MHSE of KazSSR, Alma-Ata (KazSSR), 1986, p. 57.
Moscow, Nauka, 1990, p. 384.
2. I.Yu. Galaeve, B. Mattiason. Trends in Biotechnology, 1999, V.17, p.335.
3. G.Ya. Kivman, Yu.V. Lyashenko, E.Z. Rabinovich, L.I. Fleyderman. Journ.Chem.Pharm (Russia), 1994, No3,
p. 21.
4. E.N. Efremenko, V.J. Lozinsky, V.S. Sergeva et al. J. Biochem. Biophys. Methods. 51, 2002, p. 1957.
5. "Immobilized ferments: The modern state and perspectives" Edit. I.V. Berezin et al. Moscow: MSU, 1976, V.1, p. 296, V.2, p. 356.
6. M.K. Beisebekov, J.A. Abilov, A.K. Toktabayeva, N.M. Zhunusbekova, K.A. Zhyirenchina. Abstracts of the International Microsymposium "Colloids and surfaces", Almaty, 1998. p. 29.
7. A.K. Toktabayeva, A.K. Abilov, M.K. Beisebekov and Sh. S. Ahmedova. Proceed. The 5th Intern. Symp. of Turkish Languages Countries on Polymers and Polymer Composites. Almaty, 1999, p. 37.
8. K.M. Saldadze. Ion-exchange tar. Edition of the Academy of Sciences of USSR, 1959, p.55.
9. A.S. Sharifkanov, S.S. Akhmedova, K.B. Murzagulova, G.I. Samorina, G.A. Galenko-Yaroshevskii. Patent of the RK (Kazakhstan), No1391, 1998.
10. S.R. Rafikov, V.P. Budtov and Yu.B. Monakov. Introduction in physico-chemistry of polymers, Moscow, Nauka, 1978, p. 335.
11. M.M. Feldshtein, A.B. Zezin. Molec. Biology (Russia), 1974, V. 8, No1, p. 142.
12. H.K. Ospanov. The thermodynamic and kinetic of heterogeneous processes. Almaty (Kazakhstan),
Kitap, 1990, p. 155.
13. E. Marshell. Biophysical chemistry. Moscow: Mir, 1981. p. 358.
14. M.A. Landau. Molecular mechanism of action of physiologically active compounds. Moscow: Nauka, 1981, p. 259.
15. N.I. Nikolaev. Diffusion in membranes. Moscow: Chimiya. 1980, p. 132.
16. Crank I. The Mathe matics of Diffusion. Oxford, Clarendon Press.1956, p. 347.
17. V.R. Ryabina, S.G. Starodubtsev and A.R. Khokhlov. Journ. Vysokomol. Soed (Russia), 1990, V. (A) 32, No5,
p. 969.
18. Yu.E. Kirsh and L.V. Sokolova. Journ. Chem.- Pharm. (Russia), 1983, No6, p. 711.
19. E.A. Bekturov, L.A. Bimendina, and G. K. Mamytbekov. Complex of water soluble polymers and hydrogels. Almaty: "Gylym" (Kazakhstan), 2002, p. 220.
20. Eishun Tsuchida, Koji Abe. Adv. Polym. Sci., 1982, V.45, p. 1.
21. G.V. Samsonov, E.B. Troyanskaya and G.E. Elkin. "Ion exchange. Sorption of organic compounds",
Leningrad, Nauka, 1969, p. 335.
22. G.E. Boyd, A.W. Adamson, L.S. Meyers. J. Amer. Chem. Soc., 1947, 69, p. 2836.
23. E.A. Bekturov and I.Z. Suleimenov. "Polymer hydrogels", Almaty (Kazakhstan), Nauka, 1998, p. 240.
24. T.B. Zheltonozhkaya, V.B. Rudnitskaya, B.V. Eremenko and V.G. Syromyatnikov. The colloidal Journal (Russia), 1996, V. 58, No3, p. 335.
25. V.B. Skobeleva, A.V. Zinchenko, V.B. Rogacheva, A.B. Zezin and V.A. Kabanov. Journ. Vysokomol.
Soed (Russia), 2001, V.(A) 43, No3, p. 505.
26. G.V. Samsonov. "Ion exchange", Moscow, Nauka, 1981, p. 137.
27. G.V. Samsonov and A.T. Melenevskii. "Soption and chromatographic methods of physico-chemical
bio-technology", Leningrad, Nauka, 1986, p. 230.
28. H. Kishimoto, K. Sumiola, Nagaya shiritsu daigaku yulzugakubu kerkun nempo. Annual Rept. Fac. Nagaya City Univ., 1971, No19, p. 45.
29. G. Nemethy, H.A. Scheraga, J.Phys. Chem., 1962, No66, p. 1773.
30. V.V. Pchelin, The colloidal Journ (Russia), 1972, V. 34, No5, p. 783.
31. M.K. Beisebekov. In: "Synthetic polyelectrolytes and surface-active compounds", MHSE of KazSSR, Alma-Ata (KazSSR), 1986, p. 57.
Downloads
Published
10-12-2003
How to Cite
Beysebekov, M. K., Toktabaev, A. K., & Abilov, Z. A. (2003). Sorption of Richlokain on Polycarboxylic Acid Gels. Eurasian Chemico-Technological Journal, 5(4), 311–318. https://doi.org/10.18321/ectj319
Issue
Section
Article
