The Difference of the Complex Formation of the Samarium (3+) Ion with the L-malic Acid as Compared to the Neodymium (3+) Ion

Authors

  • Vladimir Yu. Buzko Department of General and Inorganic Chemistry, Kuban State University, Krasnodar 350040, Stavropolskaya Street 149, Russia
  • Igor V. Sukhno Department of General and Inorganic Chemistry, Kuban State University, Krasnodar 350040, Stavropolskaya Street 149, Russia
  • Margarita B. Gavriluyk Department of General and Inorganic Chemistry, Kuban State University, Krasnodar 350040, Stavropolskaya Street 149, Russia
  • Victor T. Panyushkin Department of General and Inorganic Chemistry, Kuban State University, Krasnodar 350040, Stavropolskaya Street 149, Russia

DOI:

https://doi.org/10.18321/ectj596

Abstract

The complex formation of the neodymium Nd3+ ion and the samarium Sm3+ ion with L-malic acid (H3Mal) in the aqueous solutions was studied by pH-metric titration in pH region 2.80 to 10.00 and constant ionic strength 0.1 M KCl at 25 °C. The ratios of the concentrations of the rare-earth elements (Ln) and the L-malic acid were 1:0.5, 1:1 and 1:2. The number of experimental points of each curve of pH-metric titration was 160-190 at 5-6 independent titrations. Inasmuch as the literature data give mainly the dissociation constants for the racemic DL-malic acid, acid-base equilibria of L-malic acid at ionic strength of 0.1 M KCl were also previously studied in pH 3.1-11.0 range. The number of experimental points for the each titration curve of L-malic acid was 70-100 at 8 independent titrations. The dissociation constants of Lmalic acid were calculated. The compositions and the stability constants of the rare-earth element complexes with L-malic acid were calculated by SuperQuad program for complex equilibria. It was shown, that in addition to 1:1 and 1:2 complexes with differently deprotonated L-malic acid, the hydroxocomplexes and protonated complexes of the rare-earth elements are also formed. The difference of the complex formation of the Sm3+ ion with Lmalic acid as compared to the Nd3+ ion was discussed.

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Published

2004-06-28

How to Cite

Buzko, V. Y., Sukhno, I. V., Gavriluyk, M. B., & Panyushkin, V. T. (2004). The Difference of the Complex Formation of the Samarium (3+) Ion with the L-malic Acid as Compared to the Neodymium (3+) Ion. Eurasian Chemico-Technological Journal, 6(2), 91–97. https://doi.org/10.18321/ectj596

Issue

Vol. 6 No. 2 (2004)

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