The Kinetics and Mechanism of the Sulfur Dioxide Oxidation by the Oxygen in the Presence of the Cobalt and Nickel Complexes, Fixed on Polymer Matrix

V. S. Emelyanova; K. A. Zhubanov; T. V. Shakieva; G. A. Yuldasheva

doi:10.18321/ectj348

The Kinetics and Mechanism of the Sulfur Dioxide Oxidation by the Oxygen in the Presence of the Cobalt and Nickel Complexes, Fixed on Polymer Matrix

Authors

V. S. Emelyanova Research institute of new chemical technologies and materials, Almaty, Kazakhstan
K. A. Zhubanov Research institute of new chemical technologies and materials, Almaty, Kazakhstan
T. V. Shakieva Research institute of new chemical technologies and materials, Almaty, Kazakhstan
G. A. Yuldasheva Research institute of new chemical technologies and materials, Almaty, Kazakhstan

DOI:

https://doi.org/10.18321/ectj348

Abstract

Catalytic sulphur dioxide oxidation by oxygen on the cobalt and nickel complexes fixed on polyetheleneamine was investigated. On the base of kinetics study it was established that SO₂ and oxygen interact in inner sphere mechanism. UV-spectra and quantum-chemical calculations are presented, and on the base of them the ways of oxygen activation are discussed.

References

(1). Masters K. Gomogennyi kataliz perekhodnymi metallami. M.: Mir. 1983.

(2). Bugaenko L.T. Vestnik MGU. Khimiya. 1977. p.186.

(3). Emelyanova V.S., Sarmurzina A.G., Vestnik KazGU. 1998. p. 27.

(4). Bushtein I.F., Zh. Struct. Khim. 1998. v. 39, № 4, p. 25.

(5). Romanenko G.V. Zh. Struct. Khim. 1997. v. 38, № 25, p. 930.

(6). Lurye U.U. Spravochnik po analiticheskoi khimii. M. 1977. p. 275.

Downloads

Published

10-11-1999

How to Cite

Emelyanova, V. S., Zhubanov, K. A., Shakieva, T. V., & Yuldasheva, G. A. (1999). The Kinetics and Mechanism of the Sulfur Dioxide Oxidation by the Oxygen in the Presence of the Cobalt and Nickel Complexes, Fixed on Polymer Matrix. Eurasian Chemico-Technological Journal, 1(1), 65–81. https://doi.org/10.18321/ectj348