Physicochemical Particular Qualities of the Crystallization Process of Inorganic Heat-Storage Materials’ Melts

Sh. Amerkhanova; V. Aleksandrov; R. Shlyapov; A. Uali

doi:10.18321/ectj868

Authors

Sh. Amerkhanova L.N.Gumilyov Eurasian National University, K. Munaitpassov St., 13, Astana, Republic of Kazakhstan, 010008
V. Aleksandrov Donbass National Academy of Civil Engineering and Architecture, Derzhavin st., 2, Makеyеvka, Ukraine, 86123
R. Shlyapov L.N.Gumilyov Eurasian National University, K. Munaitpassov St., 13, Astana, Republic of Kazakhstan, 010008
A. Uali L.N.Gumilyov Eurasian National University, K. Munaitpassov St., 13, Astana, Republic of Kazakhstan,

DOI:

https://doi.org/10.18321/ectj868

Keywords:

supercooling, cluster-coagulation model, sodium selenate, tellurate, molybdate, tungstate, heat content

Abstract

Investigations of the cluster-coagulation model for some inorganic substances and mixtures of sodium thiosulfate with salts of elements (VI) of A, B groups have been carried out. The doping of sodium thiosulfate pentahydrate with sodium selenate, tellurate, molybdate and tungstate has been carried out. The thermodynamic parameters of associate formation processes between sodium thiosulfate and salts formed from oxygen-containing acids of selenium, tellurium, molybdenum and tungsten have been calculated. The amount of heat introduced by the modifier (selenate, tellurate, molybdate and tungstate of sodium) into the total heat-accumulating effect of the mixture Na₂S₂O₃∙5H₂O – Na₂XO₄ (X – Se, Te, Mo or W) mixture has been calculated. The number of n-particle clusters and the diameter of clusters that are formed in the melt of the Na₂S₂O₃∙5H₂O – Na₂XO₄ mixture have been calculated. It is shown that special effects of systems based on mixtures consisting from sodium thiosulfate pentahydrate and salts of selenium, telluric, molybdenum, tungsten acids could be explained by more excessive tendency of these structures to the hydrate formation, associative stability and polymerization for the reason that rare elements’ ions in anionic form stabilize associates of sodium thiosulfate with water molecules that leads to growth the heat storage capacity. The scientific and practical significance of this research refers to the probability of prediction physicochemical properties of modified heat-accumulating materials based on the cluster-coagulation model.

References

(1). M. Aneke, M. Wang, Appl. Energ. 179 (2016) 350‒377. Crossref DOI: https://doi.org/10.1016/j.apenergy.2016.06.097

(2). M. Li, Zh. Wu, M. Chen, Energ. Buildings 43 (2011) 2314‒2319. Crossref DOI: https://doi.org/10.1016/j.enbuild.2011.05.016

(3). M.K. Rathod, J. Banerjee, Renew. Sust. Energ. Rev. 18 (2013) 246‒258. Crossref DOI: https://doi.org/10.1016/j.rser.2012.10.022

(4). A. Mao, J. H. Park, G.Y. Han, T. Seo,Y. Kang, Korean J. Chem. Eng. 27 (2010) 1452–1457. Crossref DOI: https://doi.org/10.1007/s11814-010-0260-1

(5). R. Zeng, X. Wang, W. Xiao, Front. Energy Power Eng. China 4 (2010) 185–191. Crossref DOI: https://doi.org/10.1007/s11708-009-0079-9

(6). F. Yuan, M. Li, Zh. Ma, B. Jin, Zh. Liu, Int. J. Heat Mass Trans. 118 (2018) 997–1011. Crossref DOI: https://doi.org/10.1016/j.ijheatmasstransfer.2017.11.024

(7). V.D. Aleksandrov, O.V. Sobol, A.Y. Sobolev, Y.A. Marchenkova. Bulletin of the Donetsk Academy of Automobile Transport [Vestnik Doneckoj Akademii Avtomobil'nogo Transporta] 1 (2015) 34–41 (in Russian).

(8). X. Yang, Ya.Yuan, N. Zhang, X. Cao, Ch. Liu, Sol. Energy 99 (2014) 259–266. Crossref DOI: https://doi.org/10.1016/j.solener.2013.11.021

(9). E. Baştürk, D. Yüksel Deniz, M. Vezir Kahraman, Mater. Chem. Phys. 177 (2016) 521–528. DOI: https://doi.org/10.1016/j.matchemphys.2016.04.064

(10). R.J. Warzoha, A.S. Fleischer, Int. J. Heat Mass Trans. 79 (2014) 314–323. Crossref DOI: https://doi.org/10.1016/j.ijheatmasstransfer.2014.08.009

(11). G. Patience, Experimental Methods and Instrumentation for Chemical Engineers, Elsevier, 2013, p. 416.

(12). A.K. Mamyrbekova, Russ. J. Phys. Chem. 87 (2013) 414–417. Crossref DOI: https://doi.org/10.1134/S0036024413030163

(13). J.J. Valencia, P.N. Quested, Thermophysical Properties, ASM Handbook Committee, 15 (2018) 468–481. Crossref DOI: https://doi.org/10.31399/asm.hb.v15.a0005240

(14). V.D. Aleksandrov, O.A. Pokyntelytsia, Russ. J. Phys. Chem. A 90 (2016) 1839–184. Crossref DOI: https://doi.org/10.1134/S0036024416090028

(15). V.D. Aleksandrov, Kinetics of nucleation and mass crystallization of supercooled liquids and amorphous media, Donbass, 2011, 580 p.

(16). V.D. Aleksandrov, N.N. Golodenko, V.V. Dremov, V.A. Postnikov, O.V. Sobol, M.V. Stasevich, N.V. Shchebetovskaya, Tech. Phys. Lett. 35 (2009) 415–417. Crossref DOI: https://doi.org/10.1134/S1063785009050095

(17). YU.V. Harybina, Technological audit and production reserves [Tekhnologicheskij audit i rezervy proizvodstva] 5 (2016) 7‒11 (in Russian). Crossref DOI: https://doi.org/10.15587/2312-8372.2016.80422

(18). V. Gurzhiy, S.O. Tyumentseva, I. Kornyakov, S. Krivovichev, G.I. Tananaev, J. Geosci. 59 (2014) 123‒133. Crossref DOI: https://doi.org/10.3190/jgeosci.165

(19). S. Konaka, Y. Ozawa, A. Yagasaki, Inorg. Chem. 47 (2008) 1244‒1245. Crossref DOI: https://doi.org/10.1021/ic701578p

(20). Sh.K. Amerkhanova, D.S. Belgibayeva, R.M. Shlyapov, D. Dastanova, Theoretical and Experimental Chemistry: Abstracts of the Vth Internat. Scien. Conf., Karaganda, Kazakhstan, 2014. p. 52 (in Russian)

(21). Sh.K. Amerkhanova, R.M. Shlyapov, A.S. Uali, Bulletin of the Karaganda State University (chemical series) 4 (2015) 27‒33 (in Russian).

(22). Sh.K. Amerhanova, R.M. Shlyapov, Problems of theoretical and experimental chemistry: thesis doc. XXVI all-Russian youth scientific. Conf., Yekaterinburg, 2016. p. 370‒371 (in Russian).

(23). Sh.K. Amerhanova, V.D. Aleksandrov, D.S. Belgibaeva, R.M. Shlyapov, A.S. Uali, Bulletin of ENU L.N. Gumilev (series of natural and technical sciences) 6 (2015) 288–295 (in Russian).

(24). M.N. Zhidkova, V.K. Laurinavichyute, Yu.V. Nelyubina, V.Yu. Kotov, J. Solution Chem. 44 (2015) 1240–1255. Crossref DOI: https://doi.org/10.1007/s10953-015-0336-y

(25). V.P. Malyshev, N.S. Bekturganov, A.M. Turdukozhaeva, Viscosity, fluidity and density of substances as a measure of their chaos, Moscow, Scientific world, 2012, 288 p. (in Russian).