Interaction Between Propylene and H2O over Ru-Co/SiO2 -Catalysts of Clusters Type. Communication 2.

Authors

  • G. D. Zakumbaeva The Institute of Organic Catalysis and Electrochemistry of Ministry of Education and Science of the Republic of Kazakhstan
  • L. B. Shapovalova The Institute of Organic Catalysis and Electrochemistry of Ministry of Education and Science of the Republic of Kazakhstan
  • A. A. Shurtbaeva The Institute of Organic Catalysis and Electrochemistry of Ministry of Education and Science of the Republic of Kazakhstan

DOI:

https://doi.org/10.18321/ectj368

Abstract

The interaction between propylene and H2O on Ru-Co/SiO2-catalyst was studied. It was determined that the process of the water addition to olefin molecule is carried out with n-propanol, i-propanol and acetone formation. For clarification of the adsorption mechanism of propylene on Ru-Co-clusters the quantum- chemical calculation of interaction between it and Ru-Co, Ru-Ru, Co-Co clusters were carried out.

References

(1). Zakumbaeva G.D., Shapovalova L.B., Gabdrakipov A.V., Efremenko I.G. Neftechimia (Russ), 1996, В№4, P. 427-437.

(2). Zakumbaeva G.D., Shapovalova L.B., Gabdrakipov A.V., Gabdrakipov V.Z. Neftechimia (Russ), 1997, В№7, P. 492-503.

(3). Lukianovich V.M. Electron croscopy in physikochemical investigation. M., 1960, 290 p.

(4). Shimmel G. The metodic of electron microscopy. M., 1972, 299 p.

(5). Andersen A.B., Hong S.Y., Smialec J.L. J. Phys. Shem., 1987, V.91, P.4245.

(6). Ammeter J.H., Bardi H.B., Thibealt J.C., Hoffman R. J. Amer. Chem. Soc. 1978, V.100, P. 368.

(7). Mealli C., Proserpio D.M. J. Chem. Educ. 1990, V.67, P.339.

(8). Thorn D.L., Hoffman R. Inorg. Chem. 1978, V.17, В№1, P. 126.

(9). Gurvitch L.V., Karatshetsov G.V., Kondratiev V.J. and alt. The potenziols of the ionisation and the affinity with the electrons. M., Nauka, 1974, 134P.

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Published

2000-06-12

How to Cite

Zakumbaeva, G. D., Shapovalova, L. B., & Shurtbaeva, A. A. (2000). Interaction Between Propylene and H2O over Ru-Co/SiO2 -Catalysts of Clusters Type. Communication 2. Eurasian Chemico-Technological Journal, 2(2), 117–124. https://doi.org/10.18321/ectj368

Issue

Vol. 2 No. 2 (2000)

Section

Articles

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