Olefine Production from Syngas over Bimetallic Supported
DOI:
https://doi.org/10.18321/ectj360Abstract
Bimetallic cobalt-containing catalysts supported on alumina have been studied in the Fischer-Tropsch synthesis. It has been shown that a promotion of Co/Al2O3 by iridium leads to dispergation of both metals. It was supposed that the metal dispergation occurred due to M-M interaction with formation of the bimetallic nano-particles of cluster type. These particles have the high catalytic activity, selectivity and stability in the Fischer-Tropsch synthesis. It was observed that by regulation of the process conditions it is possible to obtain the definite hydrocarbon fractions. Thus, the increase both CO+H2 ratio and space velocity is accompanied by high olefin yield.
References
(2). Erdoehely A., Cserenyi J., Papp E., Solymosi F., Appl.Catal., 108A (1994) 205. <a href="https://doi.org/10.1016/0926-860x(94)85071-2">Crossref</a>
(3). Bhaduri A.K., Chem. Age India, V.38, No 11 (1987) 595.
(4). Kotowski W., Kowalski Z., Przem. Chem.,V.66, No 8 (1987) 365.
(5). Timm D., Becker K., Derdulla H.-J., Striegler H., Weber M., DDR Pat. No 245655 (1987).
(6). Sinfelt J.H., Via G.H., Lyttle F.W., J.Chem.Phys., 72, No 9 (1980) 4832. <a href="https://doi.org/10.1063/1.439821">Crossref</a>
(7). Shpiro E.S., Minachev H.M., Photoelectron Microscopy and Its Application in Catalysis, USSR, Moskva (1981).
(8). Katrib A., Stanislaus A., Yousef R.M., J.Mol. Structure, 129, No 1-2 (1985) 151. <a href="https://doi.org/10.1016/0022-2860(85)80201-5">Crossref</a>
(9). Zakumbaeva G.D., Itkulova, Sh.S. Urumbaeva Sh.U. and Dagirov T.S., USSR Author Certificate No 1617716 (1989).
(10). Itkulova Sh.S., The News of Kazakstan Science, 4 (1994) 17.
(11). Zakumbaeva G.D., Itkulova Sh.S., vol.1 , Proceed. of the World Congress on Air Pollution in Developing Countries. San Jose, Costa Rica, 1996, 80.
(12). Zakumbaeva G.D., Shapovalova L.B., Dostijarov A.M., Itkulova Sh.S., Russian Chem. Journ., 4 (1993) 102.
(13). Zakumbaeva G.D., Itkulova Sh.S., Shapovalova L.B., vol. 5, Proceed. of 5-th Intern.Confer. Energex-5. Seoul, Korea, 1993, 305.
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