Interaction Between Propylene and H2O over Ru-Co/SiO2 -Catalysts of Clusters Type. Communication 2.
DOI:
https://doi.org/10.18321/ectj368Abstract
The interaction between propylene and H2O on Ru-Co/SiO2-catalyst was studied. It was determined that the process of the water addition to olefin molecule is carried out with n-propanol, i-propanol and acetone formation. For clarification of the adsorption mechanism of propylene on Ru-Co-clusters the quantum- chemical calculation of interaction between it and Ru-Co, Ru-Ru, Co-Co clusters were carried out.
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(5). Andersen A.B., Hong S.Y., Smialec J.L. J. Phys. Shem., 1987, V.91, P.4245.
(6). Ammeter J.H., Bardi H.B., Thibealt J.C., Hoffman R. J. Amer. Chem. Soc. 1978, V.100, P. 368.
(7). Mealli C., Proserpio D.M. J. Chem. Educ. 1990, V.67, P.339.
(8). Thorn D.L., Hoffman R. Inorg. Chem. 1978, V.17, В№1, P. 126.
(9). Gurvitch L.V., Karatshetsov G.V., Kondratiev V.J. and alt. The potenziols of the ionisation and the affinity with the electrons. M., Nauka, 1974, 134P.
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Published
12-06-2000
How to Cite
Zakumbaeva, G. D., Shapovalova, L. B., & Shurtbaeva, A. A. (2000). Interaction Between Propylene and H2O over Ru-Co/SiO2 -Catalysts of Clusters Type. Communication 2. Eurasian Chemico-Technological Journal, 2(2), 117–124. https://doi.org/10.18321/ectj368
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