Hydrocarbon Synthesis from CO2 and H2 Using the Ultrafine Iron-Containing Catalytic Systems Based on Carbonized Cellulose

M.V. Kulikova; M.V. Chudakova; M.I. Ivantsov; О.S. Dementyva; A.L. Maksimov

doi:10.18321/ectj1327

Authors

M.V. Kulikova A.V. Topchiev Institute of Petrochemical Synthesis, RAS, 29 Leninsky ave., Moscow, Russia
M.V. Chudakova A.V. Topchiev Institute of Petrochemical Synthesis, RAS, 29 Leninsky ave., Moscow, Russia
M.I. Ivantsov A.V. Topchiev Institute of Petrochemical Synthesis, RAS, 29 Leninsky ave., Moscow, Russia
О.S. Dementyva A.V. Topchiev Institute of Petrochemical Synthesis, RAS, 29 Leninsky ave., Moscow, Russia
A.L. Maksimov A.V. Topchiev Institute of Petrochemical Synthesis, RAS, 29 Leninsky ave., Moscow, Russia

DOI:

https://doi.org/10.18321/ectj1327

Keywords:

Hydrothermal carbonization, Carbon carrier, CO2 hydrogenation, Product distribution

Abstract

Carbon materials were formed by the hydrothermal carbonization of cellulose, which were used as support for carbon dioxide hydrogenation catalysts (Fe/C and Fe-Mn/C). In the presence of these catalytic systems, CO₂ conversion reached 50%. It is shown that the manganese introduction into the Fe-containing catalytic system significantly affects the distribution of gaseous С₁-С₄ products and liquid С₅₊ hydrocarbons. Promotion leads to the suppression of methane formation and an increase in the proportion of C₂-C₄ light olefins in gaseous products, as well as to intensification of secondary processes with the formation of a significant amount of iso-structures in liquid products. The different distribution of С₁-С₆ alcohols in the oxygen-containing products on the Fe/C and Fe-Mn/C catalysts indicates the manganese effect on the routes of their formation.

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