Hydrocarbon Synthesis from CO2 and H2 Using the Ultrafine Iron-Containing Catalytic Systems Based on Carbonized Cellulose

  • M.V. Kulikova A.V. Topchiev Institute of Petrochemical Synthesis, RAS, 29 Leninsky ave., Moscow, Russia
  • M.V. Chudakova A.V. Topchiev Institute of Petrochemical Synthesis, RAS, 29 Leninsky ave., Moscow, Russia
  • M.I. Ivantsov A.V. Topchiev Institute of Petrochemical Synthesis, RAS, 29 Leninsky ave., Moscow, Russia
  • О.S. Dementyva A.V. Topchiev Institute of Petrochemical Synthesis, RAS, 29 Leninsky ave., Moscow, Russia
  • A.L. Maksimov A.V. Topchiev Institute of Petrochemical Synthesis, RAS, 29 Leninsky ave., Moscow, Russia
Keywords: Hydrothermal carbonization, Carbon carrier, CO2 hydrogenation, Product distribution

Abstract

Carbon materials were formed by the hydrothermal carbonization of cellulose, which were used as support for carbon dioxide hydrogenation catalysts (Fe/C and Fe-Mn/C). In the presence of these catalytic systems, CO2 conversion reached 50%. It is shown that the manganese introduction into the Fe-containing catalytic system significantly affects the distribution of gaseous С1-С4 products and liquid С5+ hydrocarbons. Promotion leads to the suppression of methane formation and an increase in the proportion of C2-C4 light olefins in gaseous products, as well as to intensification of secondary processes with the formation of a significant amount of iso-structures in liquid products. The different distribution of С1-С6 alcohols in the oxygen-containing products on the Fe/C and Fe-Mn/C catalysts indicates the manganese effect on the routes of their formation.

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Published
2022-07-25
How to Cite
[1]
M. Kulikova, M. Chudakova, M. Ivantsov, DementyvaО., and A. Maksimov, “Hydrocarbon Synthesis from CO2 and H2 Using the Ultrafine Iron-Containing Catalytic Systems Based on Carbonized Cellulose”, Eurasian Chem.-Technol. J., vol. 24, no. 2, pp. 149-156, Jul. 2022.
Section
Articles