Acylation Reaction of Polystyrene with Organic Anhydrides and Investigation of the Physico-Mechanical Properties

Authors

  • R. Kurbanova Department of Chemistry, Faculty of Science and Arts, Selcuk University, 42079 Konya, Turkey
  • R. Mirzaoglu Department of Chemistry, Faculty of Science and Arts, Selcuk University, 42079 Konya, Turkey
  • M. Ersoz Department of Chemistry, Faculty of Science and Arts, Selcuk University, 42079 Konya, Turkey
  • E. Ozcan Department of Chemistry, Faculty of Science and Arts, Selcuk University, 42079 Konya, Turkey
  • E. Guler Department of Chemistry, Faculty of Science and Arts, Selcuk University, 42079 Konya, Turkey
  • V. Pamuk Department of Chemical Engineering, Gazi University, 06100 Ankara, Turkey

DOI:

https://doi.org/10.18321/ectj370

Abstract

The acylation reaction of polystyrene with organic anhydrides, such as maleic and ace-tic anhydrides were investigated in the presence of cationic catalysis (AlCl3, BF3В·O(C2H5)2, FeCl3, SnCl4, TiCl4, ZnCl2), to synthesise some polyfunctional (carbonyl-, carboxyl-, keto-, olefinic) polystyrene. The incorporation of functional groups to polystyrene were caused an increase of adhesion capability, physico-mechanical properties, elasticity and photosensitivity polyfunctional product.

References

(1). N.G. Gaylord, R. Mehta, V. Kumar and M. Taki., J. Appl. Polym. Sci., 38, 359 (1989).

(2). N.G. Gaylord, R. Mehta, D.R. Mohan and V. Kumar., J. Appl. Polym. Sci., 44, 1941 (1992).

(3). N. Mitsuaki and A. Masuasu, J. Chem. Soc. Jpn., 70, 1452 (1970).

(4). C.-J. Wu, C.-V. Chen, E. Woo and J.F. Kuo, J. Polym. Sci. Polym. Chem., A, 31, 3405 (1993).

(5). J. Ayres and C.K. Mann., J. Polym. Sci. Polym. Phys. B, 3, 505 (1965).

(6). C.R. Harrison, P. Hodge, J. Kemp and G.M. Perry, Macromol. Chem., 176, 267 (1975).

(7). R. Kurbanova, A. Ragimov and K. Aslanov, Zh. Prikl. Khim., 1, 2311 (1979).

(8). R. Kurbanova, D. Aliyeva and A. Ragimov, J. Lakokras. Mater. 1, 51 (1980).

(9). R. Kurbanova, A. Mehraliyev and T. Orucova, J. Lakokras. Mater. N 3, 34 (1981).

(10). R. Kurbanova, R. Mirzaoglu, G. Akovali, Z.M. Rzayev, I. Karatas and A. Okudan, J. Appl. Polym. Sci., 59, 235 (1996).

(11). R. Kurbanova, R. Mirzaoglu, S. Kurbanov, I. Karatas, V. Pamuk, E. Г–zcan, A.Okudan and E. GГјler, J. Adhesion Sci. and Technol., Vol.11, N 1, 105 (1997).

Downloads

Published

2000-06-12

How to Cite

Kurbanova, R., Mirzaoglu, R., Ersoz, M., Ozcan, E., Guler, E., & Pamuk, V. (2000). Acylation Reaction of Polystyrene with Organic Anhydrides and Investigation of the Physico-Mechanical Properties. Eurasian Chemico-Technological Journal, 2(2), 131–135. https://doi.org/10.18321/ectj370

Issue

Section

Articles

Most read articles by the same author(s)