The Synthesis of Styrene-Oligoester Copolymer and Investigation of Their Physico-mechanical Properties

Authors

  • G. Ahmedova Selcuk University, Department of Chemistry, Campus, 42079 Konya, Turkey
  • H. Kara Selcuk University, Department of Environmental Engineering, Campus, 42079 Konya, Turkey
  • Y. Cengeloglu Selcuk University, Department of Environmental Engineering, Campus, 42079 Konya, Turkey
  • E. Özcan Selcuk University, Department of Environmental Engineering, Campus, 42079 Konya, Turkey
  • Y. Burdurlu Selcuk University, Department of Environmental Engineering, Campus, 42079 Konya, Turkey
  • M. Ersöz Selcuk University, Department of Environmental Engineering, Campus, 42079 Konya, Turkey
  • A. Koçak Selcuk University, Department of Environmental Engineering, Campus, 42079 Konya, Turkey

DOI:

https://doi.org/10.18321/ectj373

Abstract

The copolymerization reaction of commercial propylene oxide with glycidylmethacrilate in the presence
of BF3·O(C2H5)2 catalyst have been investigated. The composition and structure of copolymerization products and anchored functional groups have been determined using IR and gel chromatographic methods.
The physico-mechanical properties and utility of polyfunctional unsaturated oligoester were investigated.
The obtained thermoset product via the reaction of the oligoester with both styrene and oligostyrene obtained from the bottom of column as a waste material during the rectification operation of styrene in the
presence of radicalic initiator has a good adhesion capability, hardness and high heat and water resistance.
Thus the waste material was converted to the high valuable polymeric material.

References

(1). Berlin, L.N.Turovskaya, N.G.Matveyeva, Vysokomolek. Soyed., 19, 428 (1977).

(2). V. Zak. J.A. Gorin, E.I. Rogina, Zh. Prikl. Khim., 53, #11, 2693 (1980).

(3). N. J. Pugacevski, D. M.Filipenko. I.A.Sorokina, A.S. #1509363 (USSR 1989).

(4). S. S. Vezirov, S. M.Aliyev, E.S.Zenalova, J. Lakokras. Mater., 5, 41 (1990).

(5). V. A.Grigoryev, B.A.Begun, I.V.Jarsev, Plastmassy, 2, 51 (1991).

(6). L.I.Komareva, S.N.Salazkin, Y.S.Vigolski, J. Vysokomolek.Soed., 8, 32, 1571 (1990).

(7). S.T.Ahmedov, S.B.Kurbanov, L.M.Gulahmedov, G.S. Ahmedova (Kurbanova), J. Org. Chem., 22. #12, 2479 (1986).

(8). S.N.Aliyev, S.S.Vezirov, M.D.Ibrahimova, G.S.Ahmedova, A.S. #1740377, 1992 (USSR).

(9). I.A.Arbuzova, V.N.Eframova, Vysokomolek Soed, 1. #3.455, (1959).

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Published

2000-06-12

How to Cite

Ahmedova, G., Kara, H., Cengeloglu, Y., Özcan, E., Burdurlu, Y., Ersöz, M., & Koçak, A. (2000). The Synthesis of Styrene-Oligoester Copolymer and Investigation of Their Physico-mechanical Properties. Eurasian Chemico-Technological Journal, 2(2), 157–160. https://doi.org/10.18321/ectj373

Issue

Vol. 2 No. 2 (2000)

Section

Articles

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