Morphological Studies on CNT Reinforced SiC/SiOC Composites

Authors

  • L. M. Manocha Department of Materials Science, Sardar Patel University, Vallabh Vidyanagar-388120
  • A. Basak Department of Materials Science, Sardar Patel University, Vallabh Vidyanagar-388120
  • S. Manocha Department of Materials Science, Sardar Patel University, Vallabh Vidyanagar-388120
  • A. Darji Department of Materials Science, Sardar Patel University, Vallabh Vidyanagar-388120

DOI:

https://doi.org/10.18321/ectj64

Abstract

Carbon nanotubes (CNTs) have been grown on commercially available silicon carbide (SiC) fabric by the catalytic chemical vapour deposition (CCVD) technique. These CNT coated SiC fabrics were used to develop Silicon Carbide–Carbon Nanotube–Silicon oxy Carbide matrix composites (SiC/CNTs/SiOC) by sol gel technique. Silicon oxy Carbide refers to carbon containing silicates wherein oxygen and carbon atoms
share bonds with silicon in the amorphous network structure. In this approach, alkyl-substituted silicon
alkoxides, which are molecular precursors containing oxygen and carbon functionalities on the silicon, are
hydrolyzed and condensed in the presence of sucrose, which provides excess of carbon to bond into the
silicon alkoxide network during hydrolysis. A low-temperature (1000 °C) heat-treatment of the gel creates
a glassy silicate material whose molecular structure consists of an oxygen/carbon anionic network. The
microstructures of these hybrid materials and their composites have been studied using scanning electron
microscope (SEM), transmission electron microscope (TEM) and Raman spectroscope.

References

1. Schmidt H., J. Non-Cryst. Solids, Organic Modification of the Glass Structure, 112 (1989), 419.

2. Porte. L., Satre. A., J. Mat. Sci, Evidence For Silicon Oxycarbide Phase In Nicalon Silicon Carbide Fiber, 24 (27) (1989).

3. White. D. A., Oleff. S. M., Boyer. R.D., Budinger. P.A.,Fox. J. R., Adv. Ceram. Mater, Preparation of Silicon Carbide From Organosilicon Gels: II, Gel Pyrolysis And Sic Characterization, 2(1) (1987) 53.

4. Pantano C.G., Anant K.S., Zhang H., Journal of Sol-Gel Science and Technology, Silicon oxycarbide Glasses, 14 (1999) 7.

5. Luzzi D.E., Smith B. W., Carbon, Carbon Cage Structures In Single Wall Carbon Nanotubes: A New Class Of Materials, 38 (2000) 1751.

6. Bandow S.,Takizawa M., Hirahara K., Yudasaka M., and Iijima S., Chem. Phys. Lett. Raman Scattering Study of Double-Wall Carbon Nanotubes Derived from the Chains of Fullerenes in Single-Wall Carbon Nanotubes. 337 (48) (2001).

7. Lee J., Kim H., Kahng S.H., Kim G.,Son Y.W., Ihm J.,Kato H.,Wang Z.W., Okazaki T,, Shinohara H., Kuk Y., Nature, Bandgap Modulation of Carbon Nanotubes by Encapsulated Metallofullerenes, 415 (2002) 1005.

8. R. Saito, G. Dresselhaus, and M. S. Dresselhaus, Physical Properties of Carbon Nanotubes, Imperical College Press, London (1998).

9. D. Qian, G. J. Wagner, W. K. Liu, M. F. Yu, and R. S. Ruoff, Appl.Mech. Reviews. Mechanics of Carbon Nanotubes, 55 (2002) 495.

10. P. G. Colins and A. Zettl, Appl. Phys. Lett.,A Simple and Robust Electron Beam Source from Carbon Nanotubes, 69 (1996) 1969.

11. G. Z. Chen, M. S. P. Shaffer, D. Coleby, G. Dixon, W. Zhou, D. J. Fray, and A. H. Windle, Adv. Mater, Carbon Nanotube and Polypyrrole Composites: Coating and Doping, 12 (2000) 522.

12. M. Cadek, J. N. Coleman, V. Barron, K. Hedicke, and W. J. Blau, Appl. Phys. Lett., Morphological And Mechanical Properties Of Carbon-Nanotube-Reinforced Semicrystalline And Amorphous Polymer Composites, 81 (2002) 5123.

13. V. P. Veedu, A. Cao, X. Li, K. Ma, C. Soldano, S. Kar, P. M. Ajayan, and M. N. Ghasemi-Nejhad, Nat. Mater, Multifunctional Composites Using Reinforced Laminae with Carbon Nanotube Forests, 5 (2006) 457.

14. Y. Zhao, J. Liu, and Z. Zhang, Journal of Physics: Condensed Matter, Film Growth of Pillars of Multiwalled Carbon Nanotubes, 15 (2003) L565.

15. L.M. Manocha, R. Pande, Journal of Nanoscience and Nanotechnology, Growth of Carbon Nanotubes on Silicon Carbide Fabric as Reinforcement for SiC/C Composite,10 (2010) 3822.

16. E. Borowiak-Palen, T. Pichler, X. Liu, M. Knupfer, A. Graff, O. Jost, W. Pompe, R. J. Kalenczuk, and J. Fink, Chem. Phys. Lett. Reduced Diameter Distribution Of Single-Wall Carbon Nanotubes By Selective Oxidation, 363 (2002) 567.

17. H. Kajiura, S. Tsutsui, H. J. Huang, and Y. Murakami, Chem. Phys. Lett. High-Quality Single-Walled Carbon Nanotubes From ArcProduced Soot, 364 (2002) 586.

18. E. Farkas, M. E. Anderson, Z. H. Chen, and A. G. Rinzler, Chem.Phys. Lett., Length Sorting Cut Single Wall Carbon Nanotubes By High Performance Liquid Chromatography, 363 (2002) 111.

19. V. Raman, O. P. Bahl, N. K. Jha, Journal Of Materials Science Letters, Synthesis of Silicon Oxy Carbide Through Sol Gel Process, 12 (1993) 1188.

20. Lj. Cerovic, S. K. Milonjic & S. P. Zec, Ceramics International, A Comparison Of SolGel Derived Silicon Carbide Powders From Saccharose And Activated Carbon, 21 (1995) 271.

21. Guo-Qiang Jin, Xiang-Yun Guo, Microporous and Mesoporous Materials,Synthesis and Characterization of Mesoporous Silicon Carbide, 60 (2003) 207.

22. Zhang Hai-yan,Chen Jian,Liu Song-hao,Chen Di-hu,Wu Chun-yan,He Yan-yang,Liang Lizheng and Peng Shao-qi, Chinese Physics, The Raman Scattering Of Carbon Nanotubes Produced In Different Inert Gases And Their Pressures By Arc Discharge, 9 (2000) 375.

23. J. Kastner, T. Pichler, H. Kuzmany, S. Curran, W. Blau, D. N. Weldon, M. Delamesiere, S. Draper, and H. Zandbergen, Chem.Phys. Lett. Resonance Raman And Infrared Spectroscopy Of Carbon Nanotubes, 221(1994) 53.

24. H. Hiura, T. W. Ebbesen, K. Tanigaki, and H. Takahasi, Phys. LettB., Non Trivial Ground State of Closed Bosonic Membrane, 202 (1993) 509.

25. R. Kamalakaran, M. Terrones, T. Seeger, P. Kohler-Redlich, M. Ruhle, and Y. A. Kim, Appl. Phys. Lett., Synthesis of Thick and Crystalline Nanotube Arrays by Spray Pyrolysis 77 (2000) 3385.

26. F. Tuinstra and J. L. Koenig, J. Chem. Phys., Raman Spectrum of Graphite, 53 (1970) 1126.

27. P.H. Tan ,S.L. Zhang et al; J Raman Spectroscopy, Comparative Raman Study of Carbon Nanotubes Prepared by D.C. Arc Discharge and Catalytic Methods,28 (1997) 269.

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Published

2011-04-22

How to Cite

Manocha, L. M., Basak, A., Manocha, S., & Darji, A. (2011). Morphological Studies on CNT Reinforced SiC/SiOC Composites. Eurasian Chemico-Technological Journal, 13(1-2), 41–47. https://doi.org/10.18321/ectj64

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