Hydroxylation of Phenol over M-MCM-48
DOI:
https://doi.org/10.18321/ectj418Abstract
The synthesis and characterization of M-MCM-48 (M= Si, Ti, V, Cr and Mn) materials have been carried out. These systems promote hydroxylation of phenol with 30 % H2O2 and the hydroxylation activity is highest for Ti-MCM-48. Water appears to be a better solvent than acetone and acetonitrile.
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2. P. Maggioni, German Offenlegunschrift. 2, 341, 743 (1974).
3. A.V. Eliseev, React. Kine. Catal. Lett. 43, 419 (1991).
4. M.B. Hocking, J. Chem. Tech. Biotech. Chem. Technol. 35A, 365 (1985).
5. P. Maggioni, Chem. Ind. (Milan) 59, 239 (1977).
6. A.I. Brodskii, Zh. Obshch. Khim. 32, 2273 (1962).
7. A.P. Eremeev, Zh. Prikl. Khim. 53, 386 (1980).
8. Z. Masari, M. Hronec, in “Dioxygen Activation and Homogeneous Catalytic Oxidation“ ( L. I.Simandico, Ed) Elsevier, Amsterdam (1991).
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10. D.R.C. Huybrechts, Catal. Lett. 8, 273 (1991).
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13. J.C. Vartuli, K.D. Schmitt, C.T. Kresge, W.J. Roth, M.E. Leonowicz, S.B. McCullen, S.D. Hellring, J.S. Beck, J.L. Schlenker, D.H. Olson, E.W. Sheppard, Chem.Mater. 6, 2317 (1994). 13.
14. P.T. Tanev and T.J. Pinnavaia, Science 267 (1995) 865.
15. K.M. Reddy, I. Moudrakovski and A. Sayari, J. Chem. Soc. Chem. Commun.(1994) 1059.
16. N. Ulagappan, C.N.R. Rao, J. Chem. Soc. Chem. Commun, (1995) 875.
17. Rohit Kumar Rana, B. Viswanathan, Catal. Lett. 52, 25, 1998.
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19. Chibiao Liu, Yongkui Shan, Xiangguang Yang, Xingakai, Yue Wu, J. Catal. 168, (1997) 35.
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Published
20-03-2001
How to Cite
Subrahmanyam, C., Louis, B., Viswanathan, B., Renken, A., & Varadarajan, T. (2001). Hydroxylation of Phenol over M-MCM-48. Eurasian Chemico-Technological Journal, 3(1), 59–63. https://doi.org/10.18321/ectj418
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