Electric Properties of Organic-on-Inorganic n-Si/VOPc Heterojunction

Authors

  • Kh. S. Karimov Physical Technical Institute, Aini St. 299/1, Dushanbe, 734063, Tajikistan
  • B. F. Irgaziev GIK Institute of Engineering Sciences and Technology, Topi 23640, NWFP, Pakistan
  • M. Mahroof-Tahir St.Cloud State University, 720 Fourth Avenue South St.Cloud ,MN 56301-4498 ,USA
  • I. Qazi GIK Institute of Engineering Sciences and Technology, Topi 23640, NWFP, Pakistan
  • I. Murtaza State Technical University, Dushanbe, 734000, Tajikistan
  • Z. M. Karieva State Technical University, Dushanbe, 734000, Tajikistan
  • H. B. Senin 5 University College of Science and Technology Malaysia, Mengabang Telipot, 21030 Kuala Terengganu, Terengganu Malaysia

DOI:

https://doi.org/10.18321/ectj304

Abstract

In the current study vanadyl-phthalocyanine (VOPc) thin films were deposited by vacuum evaporation on n-Si substrate resulting in an organic-on-inorganic (n-Si/VOPc) heterojunctions. Ag films were deposited as electrodes. Thicknesses of the VOPc films were in the range of 100-300 nm. The dark I-V characteristics exhibited rectification behavior. The rectification ratio (RR) decreased from 4 to 0.4 as the thickness of the VOPc film decreased. The dark I-V characteristics were simulated by modified Schokley equation and spaace-charge limited currents (SCLC) approach. Investigations were carried out to study the effect of VOPc films thickness on reverse saturation current , diode quality factor and mobility of charge carriers.

References

1. M. Pientka, V. Dyakonov, D. Meissner, A. Roggach, D. Talapin, H. Weller, D. Vanderzande, Nanotechnology 15 (2004) 163.

2. M. Chikamatsu, T. Taima, Y. Yoshida, K. Saito, and K. Yase, App. Phys. Lett. 82 (2004) 127.

3. P. Sullivan, S. Heutz, S. M. Schultes, and T. S. Jones. App. Phys. Lett. 84 (2004) 1210.

4. Z. Y. Xie and L. S. Hung. App. Phys. Lett. 84 (2004) 1207.

5. M. M. El-Nahass, K. F. Abd-El-Rahman, A. A. M. Farag, A. A. A. Darwish, Organic Electronics, Vol.6 (2005) , pp.129-136.

6. M. M. El-Nahass, H. M. Zeyada , M. S. Aziz, N. A. El-Ghamaz, Solid-State Electronics Vol.49 (2005) , pp. 1314-1319.

7. F. Gutman, L. E. Lyons, Organic semiconductors (Part A, Robert E. Krieger Publishing Comppany, Malabar, Florida 1980).

8. F. Gutman, H. Keyzer, L. E. Lyons, R. B. Somoano, Organic semiconductors (Part B, Robert E. Krieger Publishing Company, Malabar, Florida 1983).

9. M. I. Fedorov, Influence of the doping on condductivity and photoconductivity of the phthaloc cynanine, Ph.D. Thesis, Chernogolovka, Moscow, Russia 1973.

10. A.K.Mahapatro , S.Ghosh , Applied Physics Letters,Vol.80, No.25 (2002), pp. 4840-4842.

11. M.I.Fedorov, Investigation of organic-inorganic semicondiuctors heterojunctions, D.Sc., Thesis, Ryazan, Russia 2004.

12. Kh. S. Karimov, Kh. M. Akhmedov, A. A. Dzhuraev, M. N. Khan, S. M. Abrarov, M.I. Fiodorov, Eurasian Chem. Tech. Journal, No. 3-4 (2000) pp. 251-259.

13. Kh.S.Karimov, M.M.Ahmed, S.A. Moiz, M.I.Fedorov, Solar Energy Materials & Solar Cells, Vol.87 (2005)
pp. 61-75.

14. Haibo Wang, De Song, Junliang Yang, Bo Yu, Yanhou Geng and Donghang Yan , Applied Physics Letters, 90, 253510 (2007), pp. 1-3.

15. Lijuan Wang and Guojun Liu , Applied Physics Letters 91, 153508 (2007), pp. 1-3.

16. H.Tada, T.Kawaguchi, A.Koma, Appl.Phys. Lett. 61 (17),26 Oct., (1992), pp. 2021-2023.

17. Yong-le Pan, Xiao-dong Liao, Yingjuan Wu, Ling-bing Chen, You-yuan Zhao, Yuan- hua Shen, Fu-ming Li,
Shu-yin Shen, De-yin Huang, Thin Solid Films, 324 (1998), pp. 209-213.

18. D.E.Barlow and K.W.Hipps. J. Phys.Chem., B. 104 (2000), pp. 5993-6000.

19. M.M.El-Nahass, K.F.Abd-El-Rahman, Journaal of Alloys and Compounds, Vol.430 (2007), pp. 194-199.

20. Kh.S.Karimov, M.M.Ahmed, S.A. Moiz, M.I.Fedorov, Solar Energy Materials & Solar Cells, Vol. 87 (2005)
pp. 61-75.

21. R.C.Loutfy, J.H.Sharp, C.K.Hsiao, and R.Ho, J.Appl. Phys. Vol.52 (8), (1981), pp. 5218-5230.

22. D. A. Neamen, Semiconductor Physics and Devices, Richard D. Irwin, Inc., USA,1999.

23. A.F.Gorodetsky, A.F.Kravchenko, Semiconductor Devices, Visshaya Shkola, Moscow, 1986.

24. S.A.Moiz, M.M.Ahmed, Kh.S.Karimov, ETRI Journal, Vol.27, No.3 (2005), pp. 319-325.

25. M.A.Lampert, Current Injection in Solids, Acad demic Press, New York, 1970, p. 21.

26. M.Gratzel, Nature, Vol.414, 15 Novemver,(2001), pp. 338-344.

Downloads

Published

2009-04-20

How to Cite

Karimov, K. S., Irgaziev, B. F., Mahroof-Tahir, M., Qazi, I., Murtaza, I., Karieva, Z. M., & Senin, H. B. (2009). Electric Properties of Organic-on-Inorganic n-Si/VOPc Heterojunction. Eurasian Chemico-Technological Journal, 11(2), 115–119. https://doi.org/10.18321/ectj304

Issue

Section

Articles

Most read articles by the same author(s)