Electric Properties of Organic-on-Inorganic n-Si/VOPc Heterojunction
DOI:
https://doi.org/10.18321/ectj304Abstract
In the current study vanadyl-phthalocyanine (VOPc) thin films were deposited by vacuum evaporation on n-Si substrate resulting in an organic-on-inorganic (n-Si/VOPc) heterojunctions. Ag films were deposited as electrodes. Thicknesses of the VOPc films were in the range of 100-300 nm. The dark I-V characteristics exhibited rectification behavior. The rectification ratio (RR) decreased from 4 to 0.4 as the thickness of the VOPc film decreased. The dark I-V characteristics were simulated by modified Schokley equation and spaace-charge limited currents (SCLC) approach. Investigations were carried out to study the effect of VOPc films thickness on reverse saturation current , diode quality factor and mobility of charge carriers.
References
2. M. Chikamatsu, T. Taima, Y. Yoshida, K. Saito, and K. Yase, App. Phys. Lett. 82 (2004) 127.
3. P. Sullivan, S. Heutz, S. M. Schultes, and T. S. Jones. App. Phys. Lett. 84 (2004) 1210.
4. Z. Y. Xie and L. S. Hung. App. Phys. Lett. 84 (2004) 1207.
5. M. M. El-Nahass, K. F. Abd-El-Rahman, A. A. M. Farag, A. A. A. Darwish, Organic Electronics, Vol.6 (2005) , pp.129-136.
6. M. M. El-Nahass, H. M. Zeyada , M. S. Aziz, N. A. El-Ghamaz, Solid-State Electronics Vol.49 (2005) , pp. 1314-1319.
7. F. Gutman, L. E. Lyons, Organic semiconductors (Part A, Robert E. Krieger Publishing Comppany, Malabar, Florida 1980).
8. F. Gutman, H. Keyzer, L. E. Lyons, R. B. Somoano, Organic semiconductors (Part B, Robert E. Krieger Publishing Company, Malabar, Florida 1983).
9. M. I. Fedorov, Influence of the doping on condductivity and photoconductivity of the phthaloc cynanine, Ph.D. Thesis, Chernogolovka, Moscow, Russia 1973.
10. A.K.Mahapatro , S.Ghosh , Applied Physics Letters,Vol.80, No.25 (2002), pp. 4840-4842.
11. M.I.Fedorov, Investigation of organic-inorganic semicondiuctors heterojunctions, D.Sc., Thesis, Ryazan, Russia 2004.
12. Kh. S. Karimov, Kh. M. Akhmedov, A. A. Dzhuraev, M. N. Khan, S. M. Abrarov, M.I. Fiodorov, Eurasian Chem. Tech. Journal, No. 3-4 (2000) pp. 251-259.
13. Kh.S.Karimov, M.M.Ahmed, S.A. Moiz, M.I.Fedorov, Solar Energy Materials & Solar Cells, Vol.87 (2005)
pp. 61-75.
14. Haibo Wang, De Song, Junliang Yang, Bo Yu, Yanhou Geng and Donghang Yan , Applied Physics Letters, 90, 253510 (2007), pp. 1-3.
15. Lijuan Wang and Guojun Liu , Applied Physics Letters 91, 153508 (2007), pp. 1-3.
16. H.Tada, T.Kawaguchi, A.Koma, Appl.Phys. Lett. 61 (17),26 Oct., (1992), pp. 2021-2023.
17. Yong-le Pan, Xiao-dong Liao, Yingjuan Wu, Ling-bing Chen, You-yuan Zhao, Yuan- hua Shen, Fu-ming Li,
Shu-yin Shen, De-yin Huang, Thin Solid Films, 324 (1998), pp. 209-213.
18. D.E.Barlow and K.W.Hipps. J. Phys.Chem., B. 104 (2000), pp. 5993-6000.
19. M.M.El-Nahass, K.F.Abd-El-Rahman, Journaal of Alloys and Compounds, Vol.430 (2007), pp. 194-199.
20. Kh.S.Karimov, M.M.Ahmed, S.A. Moiz, M.I.Fedorov, Solar Energy Materials & Solar Cells, Vol. 87 (2005)
pp. 61-75.
21. R.C.Loutfy, J.H.Sharp, C.K.Hsiao, and R.Ho, J.Appl. Phys. Vol.52 (8), (1981), pp. 5218-5230.
22. D. A. Neamen, Semiconductor Physics and Devices, Richard D. Irwin, Inc., USA,1999.
23. A.F.Gorodetsky, A.F.Kravchenko, Semiconductor Devices, Visshaya Shkola, Moscow, 1986.
24. S.A.Moiz, M.M.Ahmed, Kh.S.Karimov, ETRI Journal, Vol.27, No.3 (2005), pp. 319-325.
25. M.A.Lampert, Current Injection in Solids, Acad demic Press, New York, 1970, p. 21.
26. M.Gratzel, Nature, Vol.414, 15 Novemver,(2001), pp. 338-344.