Effect of Modification on Electrochemical Chelation of Polyimide Films

Saule Kudaikulova; Assima Syzdykova; Rinat Iskakov; Bulat Zhubanov; Juldyz Akhmetova; Olga Moisseyevich; Andrey Kurbatov; Tleuken Akhmetov; Marc J.M. Abadie

doi:10.18321/ectj329

Authors

Saule Kudaikulova Institute of Chemical Sciences, 106 Walikhanov Street, 480100, Almaty, Kazakhstan
Assima Syzdykova Institute of Chemical Sciences, 106 Walikhanov Street, 480100, Almaty, Kazakhstan
Rinat Iskakov Institute of Chemical Sciences, 106 Walikhanov Street, 480100, Almaty, Kazakhstan
Bulat Zhubanov Institute of Chemical Sciences, 106 Walikhanov Street, 480100, Almaty, Kazakhstan
Juldyz Akhmetova Center of Physico-Chemical Analysis, al-Farabi National University 95a Karasay Batyr st., 480012, Almaty, Kazakhstan
Olga Moisseyevich Center of Physico-Chemical Analysis, al-Farabi National University 95a Karasay Batyr st., 480012, Almaty, Kazakhstan
Andrey Kurbatov Center of Physico-Chemical Analysis, al-Farabi National University 95a Karasay Batyr st., 480012, Almaty, Kazakhstan
Tleuken Akhmetov Center of Physico-Chemical Analysis, al-Farabi National University 95a Karasay Batyr st., 480012, Almaty, Kazakhstan
Marc J.M. Abadie Laboratory of Polymer Science & Advance Organic Materials, Montpellier University 2, S.T.L., Place Eugène Bataillon, 34095 Montpellier Cedex 5, France

DOI:

https://doi.org/10.18321/ectj329

Abstract

Novel procedure of electrochemical chelation of polyimide films was developed. The kinetics of silver cation sorptions into the films during the chelation was found out. The effect of modification treatment of film surfaces on kinetics of electrochemical process was studied. The stabilization of ion-sorbed layer of films occurs in water-isopropanol solvents. Sorption of silver during electrochemical deposition is 0.75-1.5 mg per 100 µm of polyimide depending on modification solution. Thus, the most appropriate morphological modification with about 1.5 mg/100 µm take places in heterocyclic solvents. The resulting metallized polyimide films show good non-washing out adhesion of metal into gel-like structured surfacial layers of the film.

References

1. Sroog C.E. J.Polym.Sci. Macromol.Rev. 11:161 (1976).

2. Polyimides: Fundamentals and Applications. Ghosh M.K. and Mittal K.L.(eds.) Marcel Dekker, New York, 1996, p.531.

3. Matienzo L.Y., Unertl W.N. in Polyimides: Fundamentals and Applications. Ghosh M.K. and Mittal K.L.(eds.) Marcel Dekker, New York, 1996, p.629.

4. Lee K.W., Viehbeck A. in Polyimides. Fundamentals and Applications. Ghosh M.K. and Mittal K.L.(eds.) Marcel Dekker, New York, 1996, p.505.

5. Syzdykova, S. Kudaikulova, G. Boiko, B. Zhubanov. Mater. Int. confer. Chemistry, education & industry. Pavlodar Nov. 15-16 2001, p. 260.

6. M. Koton, T. Redrova, A. Krasovski. Doklady AN USSR. 265:660 (1982).

7. N. Mikhailov, V. Artemiev, N. Kuparkin, et al. J. Prikladnoy chimia. 5:1156 (1986).

8. N. Melnikova, A. Kuzmin, V. Kartashev. Plastamassy. 2:23 (1988).

9. V. Mirkin, M. Ilushenko. Potentiometric indicators as electrodes. Almaty. 1983, p. 255.

10. N. Melnikova, E. Kochneva, A. Kuzmin, V. Kartashev. J. Prikladnoy chimia. 7:1512 (1991).

11. N. Melnikova, E. Grudzinskaya, O. Kondrashina, S. Zhukova. Izvestia VUZov. Chim. & Chim. technol. 40(3): 44 (1997).

12. Syzdykova, S. Kudaikulova, G. Boiko, B. Zhubanov. Mater. Int. confer. Chemistry, education & industry. Pavlodar Nov. 15-16 2001, p. 266.

13. S. Kudaikulova, A. Syzdykova, G. Boiko, B. Zhubanov. Mater. III Int. Beremjanov’s summit Chem.& Chem.technol. Oskemen, Sept. 10-12, 2001, p. 160.