Initiated Low-Temperature Cracking of Ozonizated Petroleum and Heavy Petroleum Ends

Authors

  • A. K. Golovko Russian Academy of Sciences, Siberian Branch, Institute of Petroleum Chemistry, 3, Academichesky Ave., 634021, Tomsk, Russia
  • V. F. Kamyanov Russian Academy of Sciences, Siberian Branch, Institute of Petroleum Chemistry, 3, Academichesky Ave., 634021, Tomsk, Russia
  • I. G. Shabotkin Russian Academy of Sciences, Siberian Branch, Institute of Petroleum Chemistry, 3, Academichesky Ave., 634021, Tomsk, Russia

DOI:

https://doi.org/10.18321/ectj597

Abstract

New way to produce greater amounts of distillate motor fuels from crude petroleums, petroleum residues and natural bitumens by an ozonization of raw material followed with thermal treatment of the product formed under the conditions similar to ones characteristic of common petroleum atmospheric rectification process is proposed. About half of heavy petroleum components boiling above 350 °C can be converted into light hydrocarbons constituting the gasoline and diesel fractions and total yield of the lasts can be accordingly increased by means of described new method of oil processing. Ultimate products contain up to 16 wt.% olefins and lesser amounts of sulfur compounds and have noticeably improved principal operational properties in comparison with analogues straight-run motor petroleum distillates.

References

(1). Handbook of an oil-processor (Spravochnik neftepererabotchika), G.A. Lastovkin, E.D. Radchenko, M.G.Rudin, eds. Leningrad (Russia): Khimiya, 1986. 648 pp.

(2). Russian patent No 2117028. Bull. Invent. 1998. No 22.

(3). Bailey P.S. The reactions of ozone with organic compounds. Chem. Revs. 1958. Vol. 58, No 7. pp. 925-1010.

(4). Razumovsky S.L., Zaikov G.E. Ozone and its reactions with organic compounds. (Ozon i yego reaktsii s organicheskimi soyedineniyami), Moscow (Russia): Nauka, 1974. 304 pp.

(5). Russian patent No 1754762. Bull. Invent. 1992. No 30.

(6). Kam'yanov V.F., Lebedev A.K., Sivirilov P.P. Ozonolysis of petroleum stocks. (Ozonoliz neftyanogo syr'ya). Tomsk (Russia):Rasko, 1997. 258 pp.

(7). Musaev A.G., Nadirov N.K. Processing of kazakhstanian bituminous rocks. (Pererabotka bituminoznykh porod Kazakhstana). Alma-Ata: Kaz-INTI, 1991. 48 pp.

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Published

2004-06-28

How to Cite

Golovko, A. K., Kamyanov, V. F., & Shabotkin, I. G. (2004). Initiated Low-Temperature Cracking of Ozonizated Petroleum and Heavy Petroleum Ends. Eurasian Chemico-Technological Journal, 6(2), 99–105. https://doi.org/10.18321/ectj597

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Articles