The Composition and properties of Straight-Run and Mechanoactivated 360-400 °C Distillate from Yakut Petroleum

Authors

  • P. A. Pikula Institute of Petroleum Chemistry, Russian Academy of Sciences, Siberian Branch 3, Academichesky Av., 634021, Tomsk, Russia
  • A. K. Golovko Institute of Petroleum Chemistry, Russian Academy of Sciences, Siberian Branch 3, Academichesky Av., 634021, Tomsk, Russia
  • V. F. Kamyanov Institute of Petroleum Chemistry, Russian Academy of Sciences, Siberian Branch 3, Academichesky Av., 634021, Tomsk, Russia

DOI:

https://doi.org/10.18321/ectj570

Abstract

The group hydrocarbon composition of 360-400 °C straight-run distillate of the petroleum from Talakanskoye oil-field (Yakutia − Republic of Saha) has been studied in detail using clathrate formation, liquid adsorption chromatography, thermodiffusion methods and mass spectrometric analysis of obtained thermodiffusion fractions. The fundamental physical constants of all isolated narrow hydrocarbon fractions were measured. The regularities of thermodiffusion separation of saturated hydrocarbons having different amounts of rings in molecules as well as the relations between properties and composition of the concentrates obtained were traced. It is established that a mechanoactivation of petroleum distillate leads to a change of its hydrocarbon composition, first of all to a decrease of its paraffin content, as well as to respective changes of its physicalchemical characteristics (to a decrease in pour point and an increase in density and viscosity values).

References

1. Petrov Al.A. The chemistry of naphthenes. Nauka, Moscow, Pussia, 1971, 388 pp.

2. Sergiyenko S.R., Aidogdyev A., Korotky A.G., et al. Petroleums from oil-fields of Caspian East coast. «Ylym», Ashkhabad, Turkmenistan, 1972, 247 pp.

3. Bogomolov A.I., Temyanko M.B., Khotyntseva L.I. (eds.) Modern methods of petroleum analysis. Nedra, Leningrad, Russia, 1984, 432 pp.

4. Washall T.A., and Melpolder F.W. Ind. Eng. Chem., Process Design & Development 1:26 (1962)

5. Polyakova A.A. (ed.) Mass-spectral analysis in petroleum refining and petrochemistry. VNII NP, Moscow, Russia, 1988, 115 pp.

6. Rybak B.M. The analysis of oil and oil products. Gostoptekhizdat, Moscow, Russia, 1962, 888 pp.

7. Hagan M. Clathrate inclusion compounds. Mir, Moscow, Russia, 1966, 165 pp.

8. Petrov Al.A. Petroleum hydrocarbons. Nauka, Moscow, 1984, 264 pp.

Downloads

Published

2001-12-10

How to Cite

Pikula, P. A., Golovko, A. K., & Kamyanov, V. F. (2001). The Composition and properties of Straight-Run and Mechanoactivated 360-400 °C Distillate from Yakut Petroleum. Eurasian Chemico-Technological Journal, 3(3), 205–210. https://doi.org/10.18321/ectj570

Issue

Section

Articles