Carbon Fabric Reinforced Addition-Cure Phenolic Resins Based on Propargyl and Allyl Ether Functional Novolac Produced by Vacuum Infusion

Authors

  • S. Nechausov M.V. Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119992, Russia
  • B. Bulgakov M.V. Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119992, Russia
  • D. Kalugin M.V. Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119992, Russia
  • A. Babkin M.V. Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119992, Russia
  • A. Kepman M.V. Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119992, Russia
  • A. Malakho M.V. Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119992, Russia
  • V. Avdeev M.V. Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119992, Russia

DOI:

https://doi.org/10.18321/ectj956

Keywords:

Vacuum infusion, Thermosetting resin, Mechanical properties, Polymer-matrix composites (PMCs)

Abstract

 Composites consisting of propargyl- and allyl/propargyl- modified novolac resins and carbon fabric were obtained by the vacuum infusion molding process. It was established that the presence of potassium cations remaining after the synthesis increase the resin melt viscosity, and acid washing is needed to obtain resins suitable for cost-effective injection techniques of composite fabrication. The mechanical properties of all composites such as compressive strength, tensile strength, in plane shear strength, and interlaminar shear strength were determined at 25, 200 and 230 °С. The carbon fiber reinforced plastics (CFRPs) retained their mechanical properties at temperatures up to 200 °C. It was shown that the use of the obtained allyl-containing polymer matrices improved mechanical properties and increased the thermal stability of the CFRPs in comparison with the propargylated novolac matrices. The composite material with novolac matrices modified by 18% propargyl and 23% allyl groups retains only up to 70% of the initial interlaminar shear strength values at 230 °C which corresponds to the data of the dynamic mechanical analysis of neat cured resins.

References

(1). J. Summerscales, T.J. Searle, Proc. Inst. Mech. Eng. L J. Mater. Des. Appl. 219 (2005) 45-48. Crossref

(2). J.C. Fish, S.W. Lee, Eng. Fract. Mech. 34 (1989) 43‒54. Crossref

(3). A.V. Babkin, E.B. Zodbinov, B.A. Bulgakov, A.V. Kepman, V.V. Avdeev, Eur. Polym. J. 66 (2015) 452‒457. Crossref

(4). B.A. Bulgakov, A.V. Sulimov, A.V. Babkin, I.A. Timoshkin, A.V. Solopchenko, A.V. Kepman, V.V. Avdeev. J. Compos. Mater. 51 (2017) 4157‒4164. Crossref

(5). J. Ahmad, Machining of Polymer Composites. Springer, New York, 2009. Crossref

(6). C.P. Reghunadhan Nair, Prog. Polym. Sci. 29 (2004) 401‒408. Crossref

(7). W.E. Douglas, A.S. Overend, Eur. Polym. J. 27 (1991) 1279‒1287. Crossref

(8). M. Wang, L. Wei, T. Zhao, Eur. Polym. J. 41 (2005) 903‒912. Crossref

(9). B. Bulgakov, D. Kalugin, A. Babkin, I. Makarenko, A. Malakho, A. Kepman, V. Avdeev, N. Garadja, A. Rogozin, Can. J. Chem. Eng. 94 (2016) 46. Crossref

(10). B. Bulgakov, A. Babkin, I. Makarenko, N. Tikhonov, D. Kalugin, A. Kepman, A. Malakho, V. Avdeev, Eur. Polym. J. 73 (2015) 247‒258. Crossref

(11). M. Wang, L. Wei, T. Zhao, J. Appl. Polym. Sci. 99 (2006) 1010. Crossref

(12). B.A. Bulgakov, A.V. Sulimov, A.V. Babkin, A.V. Kepman, A.P. Malakho, V.V. Avdeev, J. Appl. Polym. Sci. 133 (2017) 44786. Crossref

(13). D. Augustine, D. Mathew, C.P. Reghunadhan Nair, Polymer 60 (2015) 308‒317. Crossref

(14). D. Augustine, D. Mathew, C.P. Reghunadhan Nair, Eur. Polym. J. 71 (2015) 389‒400. Crossref

(15). D. Kalugin, D. Luchinkin, S. Nechausov, A. Malakho, A. Rogozin, N. Garadja, Polym. Advan. Technol. 27 (2016) 718. Crossref

(16). C.H. Lin, C.M. Huang, T.I. Wong, H.C. Chang, T.Y. Juang, W.C. Su, J. Polym. Sci. Part A: Polym. Chem. 52 (2014) 1359. Crossref

(17). T. Agag, T. Takeichi, Macromolecules 34 (2001) 7257–7263. Crossref

(18). C.P. Reghunadhan Nair, D. Vijayan, C. Gouri Polym. Polym. Compos. 12 (2004) 43–53.

(19). S.S. Nechausov, B.A. Bulgakov, A.V. Solopchenko, A.A. Serdan, D.I. Kalugin, A. Lyalin, A.V. Kepman, A.P. Malakho, J. Polym. Res. 23 (2016) 114. Crossref

(20). S.B. Gibbs, A. Versluis, D. Tantbirojn, S. Ahuja, The Journal of Prosthetic Dentistry 112 (2014) 293‒298. Crossref

(21). J.L. Valentin, J. Carretero-Conzales, I. Mora- Barrantes, W. Chasse, K. Saalwachter, Macromolecules 41 (2008) 4717‒4729. Crossref

(22). R.L. Bindu, C.P. Reghunadhan Nair, K.N. Ninan, Polym. Int. 50 (2011) 651‒658. Crossref

(23). L.W. Flanagin, C.L. McAdams, W.D. Hinsberg, I.C. Sanchez, C.G. Willson, Macromolecules 32 (1999) 5337‒5343. Crossref

(24). S.I. Kargov, L.A. Shelkovnikova, V.A. Ivanov, Russ. J. Phys. Chem. A 86 (2012) 860‒866. Crossref

(25). A.Y. Malkin, I.Y. Gorbunova, M.L. Kerber, Polym. Eng. Sci. 45 (2005) 95‒102. Crossref

(26). F.C. Campbell. Manufacturing processes for advanced composites, 2003, 532 p. Crossref

(27). M. F. Grenier-Loustalot, C. Sanglar, Eur. Polym. J. 33 (1997) 1125‒1134. Crossref

(28). M.F. Grenier-Loustalot, C. Sanglar, High Perform. Polym. 8 (1996) 315‒339. Crossref

(29). J.A. Nairn, Comprehensive Composite Materials 2 (2000) 403‒432. Crossref

Downloads

Published

2020-06-30

How to Cite

Nechausov, S., Bulgakov, B., Kalugin, D., Babkin, A., Kepman, A., Malakho, A., & Avdeev, V. (2020). Carbon Fabric Reinforced Addition-Cure Phenolic Resins Based on Propargyl and Allyl Ether Functional Novolac Produced by Vacuum Infusion. Eurasian Chemico-Technological Journal, 22(2), 99‒106. https://doi.org/10.18321/ectj956

Issue

Vol. 22 No. 2 (2020)

Section

Articles

License

You are free to: Share — copy and redistribute the material in any medium or format. Adapt — remix, transform, and build upon the material for any purpose, even commercially.

Eurasian Chemico-Technological Journal applies a Creative Commons Attribution 4.0 International License to articles and other works we publish.

Subject to the acceptance of the Article for publication in the Eurasian Chemico-Technological Journal, the Author(s) agrees to grant Eurasian Chemico-Technological Journal permission to publish the unpublished and original Article and all associated supplemental material under the Creative Commons Attribution 4.0 International license (CC BY 4.0).

Further distribution of this work must maintain attribution to the author(s) and the published article’s title, journal citation, and DOI.

Most read articles by the same author(s)