Effect of Current Density on Electrodeposition of Nickel-Organic Microcapsules Composite Coatings

O. S. Kholkin; A. P. Kurbatov; Gary W. Beall; T. Djenizian; A. K. Galeyeva; M. S. Lepikhin; S. T. Kokhmetova

doi:10.18321/ectj1

Authors

O. S. Kholkin Al-Farabi Kazakh National University, 050000, al-Farabi av. 71, Almaty, Kazakhstan
A. P. Kurbatov Al-Farabi Kazakh National University, 050000, al-Farabi av. 71, Almaty, Kazakhstan
Gary W. Beall Texas State University San Marcos, 805 Valley View West Road, San Marcos, TX 78666, USA
T. Djenizian Aix-Marseille Université, LP3 Laboratory, Avenue Escadrille Normandie-Niemen, F-13397 Marseille Cedex 20
A. K. Galeyeva Al-Farabi Kazakh National University, 050000, al-Farabi av. 71, Almaty, Kazakhstan
M. S. Lepikhin Al-Farabi Kazakh National University, 050000, al-Farabi av. 71, Almaty, Kazakhstan
S. T. Kokhmetova Al-Farabi Kazakh National University, 050000, al-Farabi av. 71, Almaty, Kazakhstan

DOI:

https://doi.org/10.18321/ectj1

Abstract

A formation of protective composite coatings based on nickel and organic substance of inert nature, containing a corrosion inhibitor, encapsulated in a polymer shell, was studied. The microcapsules were
synthesized in an aqueous-organic emulsion using the method of formation of shell of the modified gelatine
on the surface of microdroplets. Composite coatings were obtained by electrochemical codeposition of nickel
matrix and microcapsules, suspended in the electrolyte. Changes of surface morphology, microhardness
and corrosive properties of coatings with respect to changes of deposition parameters of coatings were
investigated. The distribution of particle sizes in coatings depending on the current density was studied. It was shown that an increase in the mass fraction of the microcapsules in the coating leads to an increase in its corrosion resistance.

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