Electrochemical Behavior of Magnesium and its Alloys in non-Aqueous Solutions
DOI:
https://doi.org/10.18321/ectj381Abstract
Magnesium and its alloys are widely used in creation of chemical sources of current, because possesses a number of characteristics: highly negative standart potential, low equivalent weight, high melting point, low cost, relative abundance, ease of handling, machining, and disposal, and low toxicity of most its compounds. Therefore study of magnesium behavior and isolation is actually and perspective. However results of researches in this area are separated and have no a general direction. In this connection, the given article supposes by the purpose to generalize last achievements, available in the modern literature in electrochemistry of magnesium and its alloys in non-aqueous media.
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(41). Shiryaev V.G., Leonov V.I., Ivanov V.G., Bairachny E.G., Cherepanov V.B., On some features of anode dissolution of Mg-Hg alloys system, 3 All union conference on electrochemical power. Thesis of reports. M., October 19-21,
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(3). Mamyrbekova A.K., Electrodeposition of copper from dymethylsulphide electrolytes: the abstract of the dissertation c.c.s., Almaty, 1998.
(4). Mann Ch., Barkas K., Electrochemical reactions in non-aqueous systems, M: Chemistry, 1974, p. 22.
(5). Krestov G.A., Specifics and prospects of development of chemistry of non-aqueous solutions, 4 All union conference on synthesis and research of inorganic connections in non-aqueous solutions. Thesis of reports. Ivanovo, January 15-17, 1980, Ivanovo: Ministry of energy, USSR, 1980, p. 3.
(6). Damaskin B.B., Petry O.A., Electrochemistry, M: Higher school, 1987, p. 266.
(7). Gabano J.P., Editor, “Lithium Batteries”, Academic Press, New York, 1983.
(8). Gregory Thomas D., Hoffman Ronald J., Winterton Richard C., J. Electrochem. Soc., 1990, 137, N3, p.775.
(9). Brown O.K., Mc. Intyre R., J. Electrochim. Acta, 1985, 30, N5, p. 427.
(10). Suhova G.I., Study of electrochemical magnesium behavior in the electrolyte on the basis of ADS, H.S.Tech., 1984, N4, p. 5.
(11). Kedrynsky I.A., Suhova G.I., Electrode potentials of lithium and of magnesium in electrolytes on the basis of ADS, Siberian Tech. Inst. Krasnodar, 1984, p. 19.
(12). Suhova G.I., Chumakov V.G., On the properties of the passivation layer on magnesium in aprotonic electrolytes, 2 All union Scientific conference. Thesis of reports. M., 19-23 September, 1984, M.:1984, p. 32.
(13). Kedrynsky I.A., Grudyanov I.I., Suhova G.I., Abolin O.A., Kuznetsova T.V., Influence of surface formations on chemical and electrochemical behavior of active metals, 2 All union Scientific conference on electrochemical power. Thesis of reports. M., October 7-8, 1984, M: 1984, p. 25.
(14). Suhova G.I, Kuznetsova T.V., Kedrynsky I.A., Electrochemical behavior of magnesium in electrolytes on the basis of ADS, 4 Ukraine Republic conference on electrochemistry. Thesis of reports. Kharkov, December 5-9, 1984, Kiev: 1994, p.136.
(15). Suhova G.I, Kuznetsova T.V., Kedrynsky I.A., Electrode potentials of magnesium in electrolytes on the basis of ADS, Siberian Technological Institute. Krasnoyarsk, 1981, 10 p. Dep. in ONIINTACheì, Cherkassy dated 7.01.82. N58
HP- D82.
(16). Suhova G.I, Kedrynsky I.A., Corrosion and electrochemical behavior of magnesium in electrolytes on the basis of ADS, 2 All union symposium on electrochemistry and corrosion of metals in water-organic and organic media. Thesis
of reports. Rostov-on the-Don, September 25-27, 1984, Rostov-on the-Don: South Geology, 1984, p. 147.
(17). Suhova G.I, Kuznetsova T.V., Corrosion behavior of magnesium on the basis of ADS, 6 All union conference on electrochemistry. Thesis of reports. M., June 21-25, 1982, M: 1982, T. 1, p. 143.
(18). Meitav A., Peled E., Solid electrolyte interphase (SEI) electrode. The formation and properties of the SEI on Mg in SOCl-Mg(AlCL4)2 solutions, J. Electrochem. Soc., 1981, 128, N. 4, p.825.
(19). Peled E., Straze H., J. Electrochem. Soc., 1977, 124, N7, p. 1030.
(20). Battisti A., Trasatti S., J. Electroanal. Chem., 1977, 79, C. 251.
(21). Thomson J.K., Kleinberg J., J. Am. Cc., 73, 1243-1245, 1951.
(22). Kuvancheva A, Naurizbaev M., Ishkenov A., Electrochemical extraction of magnesium from non-aqueous electrolytic systems, Herald of KazGu, chemical series, Almaty, 2000, №1(18), p. 46.
(23). Fialkov Y.Ya., Gryshenko V.F., Electroisolation of metals from non-aqueous solutions, Kiev, 1985, p. 145.
(24). Mann Ch., Barkas K., Electrochemical reactions in non-aqueous systems, M:Chemistry, 1974, p. 22.
(25). Gendere J.P., Pletcher D., J. Electroanal. Chem., 1986, 199, N1, p. 93.
(26). Lossins L.P., Emmenegger F., J. Electrochim. Acta, 1996, 41, N3, p. 445.
(27). Brenner A., Adv. Electrochem. and electrochem. eng., 1967, 5, p. 205.
(28). Yakubson S.I., Electrolytic non-aqueous solutions, Kiev: 1967, p. 616.
(29). Quiun R.K., Lagowski J.J., Inorg.Chem., 1979, T.9, N2, p. 414.
(30). Bittrich H.J., Landsberg R., Gaube W., Chem. Abst., 1961, p.141.
(31). Popova S.S., Tseluikina G.V., Kabanov B.N., Electrochemistry, 1985, v. 21, t. 2, p. 161.
(32). Kuvancheva A.M., Kurbatov A.P., Ishkenov A.R., Nauryzbayev M.K., Study of electrochemical extraction of magnesium from dymethylsulfoxide solution of magnesium perchlorate, Almaty, Herald of Engineers Academy of Sciences, 2001.
(33). Smaglin G.S., Electrolytic production of magnesium, M: Metallurgy, 1965, p. 5.
(34). Toyr A., Loodmaa V., Anode materials of CSC on the basis of aluminium and of magnesium, St. West Tart.of University, 1986, N757, p. 175.
(35). Loodmaa V., Toir A., Research of the anode of a Mg-Hg alloy in LiClO4 solution in ADS, 7 All union conference on electrochemistry. Thesis of reports. Chernovtcy, October 10-14, 1988. Chernovtcy: 1988, t. 1, p. 109.
(36). Connor J.H., Reid Jr.W.E., Wood G.B., J. Electrochem.Soc., 1957, T. 104, p.38.
(37). Gillet I., Bloyaert F., Chem.Abst., 1951, T. 60, p. 609.
(38). Turyn Y.M., Flerov V.N., Pomicheva G.A., Kovaleva O.N., Samsonova A.D., Merkulov A.A., Elecrtrooxidation of metals from Grignard reagents, 5 All union conference on metalloorganic chemistry, Urmala, 1-4 April, 1991.
Thesis of reports, Riga, 1991, p. 357.
(39). Mayes Anton, Electrodeposition of aluminium, alminium/magnesium alloys and magnesium from organometallic electrolytes, J. Electrochem. Soc. 1990- 137, N9, p. 2806-2809.
(40). Nefedkyn S.I., Korovin N.V., Filippov A.L., Anode oxidation of magnesium in thyonylchloride solutions, Electrochemistry, M., 1982, p. 6.
(41). Shiryaev V.G., Leonov V.I., Ivanov V.G., Bairachny E.G., Cherepanov V.B., On some features of anode dissolution of Mg-Hg alloys system, 3 All union conference on electrochemical power. Thesis of reports. M., October 19-21,
1989. M: MEI, 1989, p. 33.
(42). Korolenko S.D., Marchenko S.V., Polypikes B.E., Rams B.M., Shadnyh A.A., Study of products of corrosion at discharge of magnesium-air current sources, 3 All union conference on electrochemical power. Thesis of reports. M., October 19-21, 1989. M: MEI, 1989, p. 38.
(43). Sheblovinsky V.M., Ahachinsky S.V., Alashkin V.M., Zastavsky A.R., Electrochemical behavior of binary alloys of lithium in g - BL, 3 All union conference on electrochemical power. Thesis of reports. M., October 19-21, 1989. M: MEI,
1989, p. 40.
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Published
2001-03-20
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Kuvancheva, A. M., Nauryzbayev, M. K., Ishkenov, A. R., & Kurbatov, A. P. (2001). Electrochemical Behavior of Magnesium and its Alloys in non-Aqueous Solutions. Eurasian Chemico-Technological Journal, 3(1), 17–27. https://doi.org/10.18321/ectj381
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