Electrical Properties of Poly-N-Epoxypropylcarbazole/Vanadium Pentoxide Composite

Authors

  • M.H. Sayyad GIK Institute of Engineering Sciences and Technology, Topi, NWFP, 23460, Pakistan
  • K. ul Hasan GIK Institute of Engineering Sciences and Technology, Topi, NWFP, 23460, Pakistan
  • M. Saleem GIK Institute of Engineering Sciences and Technology, Topi, NWFP, 23460, Pakistan
  • Kh.S. Karimov Physical Technical Institute of Academy of Sciences, Rudaki Ave, 33, Dushanbe, 734025, Tajikistan
  • F.A. Khalid GIK Institute of Engineering Sciences and Technology, Topi, NWFP, 23460, Pakistan
  • M. Karieva Tajik Technical University, Dushanbe 734000, Tajikistan
  • Kh. Zakaullah GIK Institute of Engineering Sciences and Technology, Topi, NWFP, 23460, Pakistan
  • Z. Ahmad GIK Institute of Engineering Sciences and Technology, Topi, NWFP, 23460, Pakistan

DOI:

https://doi.org/10.18321/ectj255

Abstract

In the present work the electrical properties of poly-N-epoxypropylcarbazole (PEPC) and vanadium pentoxide (V2O5) composite have been studied. The composite was formed by mixing of PEPC solution in benzene with V2O5 powder and stirring at room temperature. The composite solution was deposited on a dielectric substrate with copper electrodes and the Cu/PEPC-V2O5/Cu surface type film samples were fabricated. The Cu/V2O5/Cu samples were used as a reference where the films were deposited from the mixture of V2O5 powder in distilled water. Resistance-temperature relationship and voltage-current characteristics of the composite and V2O5 samples were studied by using conventional digital voltmeter and ammeter in the temperature range of 27-110 °C with an error of ±0.5%. It was observed that the DC electrical conductivity, activation energy and non-linearity of voltage-current characteristics of the samples are temperature dependent. It was found that the temperature dependence of electrical conductivity of the V2O5 samples on the whole obeys T-1/4 law whereas the PEPC-V2O5 ones show visible deviations from that. The PEPC-V2O5 samples may be used as thermistors as the temperature coefficient of their resistance is large and at 27 °C is equal to -4.7%/°C.

References

(1). D. Patidar, N. Jain, N.S. Saxena, K. Sharma and T.P. Sharma, Brazilian Journal of Physics, (2006), Vol. 36,
No. 4A, pp. 1210-1212.

(2). C.H. Chen and I. Shih, J. Mater. Sci.: Mater. Electron (2006), 17, pp. 1047-1053.

(3). M.M. El-Nahass, K.F. Abd-El-Rahman, A.A.M. Farag and A.A.A. Darwish, J. Organic Electronics, (2005), 6,
pp. 129-136.

(4). Sh. Smith and S.R. Forrest, Applied Physics Letters, (2004), Vol. 84, No. 24, pp. 5019-5021.

(5). J.M. Shaw and P.F. Seidler. IBM, J. Res. & Dev., (2001), Vol. 45, No. 1, pp. 3-9.

(6). Y.J. Liu, J.L. Schindler, D.C. DeGroot, C.R. Kannewurf, W. Hirpo and M.G. Kanatzidis, Chem. Mater., (1996), 8, pp. 525-534.

(7). F. Gutman, L.E. Lyons, "Organic semiconductors", Part A, Krieger Robert E. Publishing Company, Malabar, Florida, U.S.A, (1981), p. 125.

(8). F. Gutman, H. Keyzer, L.E. Lyons and R.B. Somoano "Organic semiconductors", Part B, Krieger Robert E. Publishing Company, Malabar, Florida, U.S.A, (1983), p. 125.

(9). Kh.M. Akhmedov, Kh.S. Karimov and M.I. Fiodorov, Geliotekhnika1-3: (1995), p.178.

(10). M.I. Fiodorov, Kh.M. Akhmedov and Kh.S. Karimov, Organic Solar Cells, TajikNIINTI, Dushanbe, Tajikistan, (1989), p. 14.

(11). Kh.S. Karimov, Kh.M. Akhmedov and A.M. Achourov, in L.L. Regel and W.R. Wilcox (ed.), Centrifugal materials processing, Plenum Press, New York, U.S.A, (1997), p. 257.

(12). Kh. Karimov, Kh. Akhmedov, M. Mahroof-Tahir, R.M. Gul and A. Ashurov, in L.L. Regel and Wilcox (ed.), Processing by centrifugation, Kluwer Academic, Plenum Publishers, New York, U.S.A, (2001), p. 93.

(13). Kh. Karimov, S. Bellingeri and Y. Abe, in L.L. Regel and W.R. Wilcox (ed.), Processing by centrifugation, Kluwer Academic, Plenum Publishers, New York, U.S.A, (2001), p. 99.

(14). Kh.S. Karimov, Kh.M. Akhmedov, R. Marupov, J. Valiev, I. Homidov, M.A Turaeva, M. Mahroof- Tahir and R. Gul, Journal of Tajikistan Academy of Sciences, (2001), 73, pp. 9-10.

(15). Kh.M. Akhmedov, Synthesis, properties and utilization of carbazolile contained polymers. D.Sc. Thesis, Institute of Chemistry of Academy of Sciences, Dushanbe, Tajikistan, (1998), p. 76.

(16). Kh.M. Akhmedov and Kh.S. Karimov, Carbazole compounds, "Donish" Dushanbe, Tajikistan, (2006), p. 63.

(17). K.V. Madhuri, K.S. Rao, S. Uthanna, B.S. Naidu, O.M. Hussain and J. Indian Inst. Sci., (2001), 81, pp. 653-658.

(18). G.W. Audevson and W.D. Compton, J. Chem. Physics, (1970), Vol. 52, No. 12, pp. 6166-6174.

(19). A.F. Gorodetsky and A.F. Kravchenko, Semiconductor Devices, V. Shkola, Moscow, (1986), p. 121.

Downloads

Published

2007-01-10

How to Cite

Sayyad, M., Hasan, K. ul, Saleem, M., Karimov, K., Khalid, F., Karieva, M., … Ahmad, Z. (2007). Electrical Properties of Poly-N-Epoxypropylcarbazole/Vanadium Pentoxide Composite. Eurasian Chemico-Technological Journal, 9(1), 57–61. https://doi.org/10.18321/ectj255

Issue

Section

Articles