Interpolymer Complex Formation Between Linear and Crosslinked Poly(acrylic acid) and Poly(vinyl ether of ethyleneglycol)

Authors

  • Z. S. Nurkeeva Department of Macromolecular Chemistry, Al-Farabi Kazakh State National University, 95 Karasai Batyr Str., 480012 Almaty, Kazakhstan
  • G. A. Mun Department of Macromolecular Chemistry, Al-Farabi Kazakh State National University, 95 Karasai Batyr Str., 480012 Almaty, Kazakhstan
  • V. V. , Khutoryanskiy Department of Macromolecular Chemistry, Al-Farabi Kazakh State National University, 95 Karasai Batyr Str., 480012 Almaty, Kazakhstan
  • V. A. Kan Kazakh National Technical University, 23 Satpayev str., 480013 Almaty, Kazakhstan
  • E. M. Shaikhutdinov Kazakh National Technical University, 23 Satpayev str., 480013 Almaty, Kazakhstan

DOI:

https://doi.org/10.18321/ectj369

Abstract

The formation of H-bonded interpolymer complexes between linear and cross-linked poly(acrylic acid) and  poly(vinyl ether of ethyleneglycol) is considered. The effects of pH and concentrations of polymers solution as well as the nature of the solvent on the complexation processes are discussed. It was found that the complexes are formed in aqueous solutions only below some critical pH value, which depends on the concentration of polymers and ionic strength of the solution. The interaction between gel of poly(acrylic acid) swollen in alcohol with solution of linear poly(vinyl ether of ethyleneglycol) is accompanied by formation of turbid layer of polycomplex and contraction of gel.

References

(1). V.A. Kabanov, Macromol. Chem. L. 8: 121 (1972).

(2). E.A. Bekturov, L.A. Bimendina, Adv. Polym. Sci. 41: 99 (1981).

(3). E. Tsuchida, K.Abe, Adv. Polym. Sci. 45: 7 (1982).

(4). M. Jiang, M. Li, M. Xiang, H. Zhou, Adv. Polym. Sci. 146: 121 (1999).

(5). C. Forder, C.S. Patrickios, S.P. Armes, N.C. Billingham, Macromolecules, 30: 5758 (1997).

(6). J. Horinaka, Y. Matsumura, M. Yamamoto, S. Aoshima, E. Kobayashi, Polym. Bull., 42: 85 (1997).

(7). Z.S. Nurkeeva, V.A. Kasaikin, E.M. Ivleva, G.B. Daurenbekova, R.E. Legkunetz, V.B.Sigitov., E.E.Ergozhin, Vysokomolek. Soed. A. 21:243 (1979).

(8). Z.S. Nurkeeva, E.M. Shaikhutdinov, A. Seitov, S.Kh. Saikieva, Vysokomol. Soed. A. 29: 932 (1987).

(9). S.E. Kudaibergenov, Z.S. Nurkeeva, G.A. Mun, B.B. Ermukhambetova, A.T. Akbauova, Macromol. Chem. Phys. 196: 2203 (1995).

(10). G.A. Mun, Z.S. Nurkeeva, V.V. Khutoryanskiy, A.B. Bitekenova, Macromol. Rapid Commun. 21: 381 (2000).

(11). G.A. Mun, Z.S. Nurkeeva, V.V. Khutoryanskiy, Macromol. Chem. Phys. 200: 2136 (1999).

(12). Z.S. Nurkeeva, G.A. Mun, V.V. Khutoryanskiy, R.A. Mangazbaeva, Polym. Int. 49: 867 (2000).

(13). Z.S. Nurkeeva, G.A. Mun, V.V. Khutoryanskiy, A.A. Zotov, R.A. Mangazbaeva, Polymer 41: 7647 (2000).

(14). N.G. Bel’nikevich, T.V. Budtova, N.P. Ivanova, Ye.F. Panarin, Yu.N. Panov, S.Ya. Frenkel, Vysokomolek. Soed. A. 31: 1691 (1989).

(15). T.V. Budtova, N.G. Bel’nikevich, V.M. Belyaev, Yu.N. Panov, S.Ya. Frenekel, Vysokomolek. Soed. A. 33:520 (1991).

(16). I. Iliopoulos, R. Audebert, Eur. Polym. J. 24: 171 (1988).

(17). G. Staikos, P. Antonopoulou, E. Christou, Polym. Bull. (Berlin) 21: 209 (1989).

(18). E. Meaurio, L.C. Cesteros, I. Katime, Polymer 39: 379 (1998).

(19). Y. Osada, Adv. Polym. Sci., 82: 1 (1987).

(20). O.E. Philippova, N.S. Karibyants, S.G. Starodubtzev, Macromolecules, 27: 2398(1994).

(21). O.E. Philippova, S.G. Starodubtzev, J.M.S. – Pure Appl. Chem. A32 (11): 1893 (1995).

(22). T.V. Budtova, I.E. Suleimenov, S.Y. Frenkel, Vysokomolek. Soed., 35: 93 (1993).

(23). X. Yu, A. Tanaka, K. Tanaka, T. Tanaka, J. Chem. Phys., 97(10): 7805 (1992).

(24). G.A. Mun, V.V. Khutoryanskiy, I.K. Nam, Z.S. Nurkeeva, S.E. Kudaibergenov, Polymer Science, 40B: 290 (1998).

(25). A.R. Khokhlov, E.Y. Kramarenko, Makromol. Chem. Theory Simul., 2: 169 (1993).

(26). Z.S. Nurkeeva, G.A. Mun, V.V. Khutoryanskiy, V.A. Kan, A.A. Zotov, Shaikhutdinov E.M., Polym. Bull. 44: 563 (2000).

Downloads

Published

2000-06-12

How to Cite

Nurkeeva, Z. S., Mun, G. A., Khutoryanskiy, V. V. , Kan, V. A., & Shaikhutdinov, E. M. (2000). Interpolymer Complex Formation Between Linear and Crosslinked Poly(acrylic acid) and Poly(vinyl ether of ethyleneglycol). Eurasian Chemico-Technological Journal, 2(2), 125–129. https://doi.org/10.18321/ectj369

Issue

Section

Articles

Most read articles by the same author(s)