New Thermo-Sensitive Hydrogel Based on Copolymer of 2-hydroxyethyl Acrylate and Ethyl Acrylate

Authors

  • R. K. Rakhmetulayeva al-Farabi Kazakh National University, al-Farabi ave. 71, 050040 Almaty, Kazakhstan
  • A. N. Azhkeyeva Satpayev Kazakh National Research Technical University, 050013, 22a Satpayev Str., Almaty, Kazakhstan
  • G. Zh. Yeligbayeva Satpayev Kazakh National Research Technical University, 050013, 22a Satpayev Str., Almaty, Kazakhstan
  • Ye. M. Shaikhutdynov al-Farabi Kazakh National University, al-Farabi ave. 71, 050040 Almaty, Kazakhstan; Satpayev Kazakh National Research Technical University, 050013, 22a Satpayev Str., Almaty, Kazakhstan
  • G. A. Mun al-Farabi Kazakh National University, al-Farabi ave. 71, 050040 Almaty, Kazakhstan
  • M. Abutalip al-Farabi Kazakh National University, al-Farabi ave. 71, 050040 Almaty, Kazakhstan

DOI:

https://doi.org/10.18321/ectj502

Keywords:

polymer hydrogel, swelling behavior, 2-hydroxyethyl acrylate (HEA), ethyl acrylate, lower critical solution temperature, differential scanning calorimetry, thermal gravimetric analysis

Abstract

In this work firstly the thermo-sensitive polymer hydrogels were obtained by three-dimensional radical copolymerization of water-soluble HEA and hydrophobic monomer ethyl acrylate (EA) in the presence of crosslinking agent N,N’-methylenebisacrylamide (BAA). The hydrogels with certain copolymer compositions showed thermo-sensitive behavior in aqueous solutions. The regularity of complex formation of cross-linked copolymer HEA-EA with anionic and cationic surface-active substances have been studied. The swelling behavior of the hydrogels in cetylpyridinium bromide aqueous solutions was studied. Increased swelling of the hydrogels was observed in the surfactant solutions. The increased swelling was more prominent for the hydrogels with a higher content of the hydrophobic moiety in the copolymer composition and with the higher surfactant concentration. The reason for the observed phenomenon is discussed.

 

References

[1]. A. Chilkoti, M.R. Dreher, D.E. Meyer, D. Raucher, Adv. Drug Delivery Rev. 54 (2002) 613– 630. <a href=" http://doi.org/10.1016/S0169-409X(02)00041-8">Crossref</a>

[2]. I.Yu. Galaev, B. Mattiasson, Enzyme and Microb. Technol. 15 (1993) 354–366. <a href=" http://doi.org/10.1016/0141-0229(93)90122-I">Crossref</a>

[3]. V.V. Khutoryanskiy, Z.S. Nurkeeva, G.A. Mun, A.D. Sergaziyev, S. Kadlubovski, N. A. Fefelova, T. Baizhumanova, J. Polym. Sci. Part B: Polym. Phys. 42 (2004) 515–522. <a href=" http://doi.org/10.1002
/polb.10693">Crossref</a>

[4]. G.A. Mun, V.V. Khutoryanskiy, Z.S. Nurkeeva, P.I. Urkimbaeva, D. Zhunuspaev, J. Polym. Sci.: Part B: Polym. Phys. 42 (2004) 2625–2632. <a href=" http://doi.org/10.1002/polb.20138">Crossref</a>

[5]. M. Shibayama, T. Norisuye, S. Nomura, Macromolecules 29 (1996) 8746–8750. <a href=" http://doi.org/10.1021/ma9609994">Crossref</a>

[6]. M.K. Yoo, Y.K. Sung, Y.M. Lee, C.S. Cho, Polymer 41 (2000) 5713–5719. <a href=" http://doi.org/10.1016/S0032-3861(99)00779-X">Crossref</a>

[7]. W.-F. Lee, C.-H. Hsu, J. Appl. Polym. Sci. 74 (1999) 3242–3253. <a href=" http://doi.org/10.1002/(SICI)1097-4628(19991220)74:13<3242::AID-APP27>3.0.CO;2-Y">Crossref</a>

[8]. I.C. Barker, J.M.G. Cowie, T.N. Huckerby, D.A. Shaw, I. Soutar, L. Swanson, Macromolecules 36 (2003) 7765–7770. <a href=" http://doi.org/10.1021/ma034250m">Crossref</a>

[9]. K. Van Durme, S. Verbrugghe, F.E. Du Prez, B. Van Mele, Macromolecules 37 (2004) 1054– 1061. <a href=" http://doi.org/10.1021/ma035319t">Crossref</a>

[10]. O.V. Khutoryanskaya, Z.A. Mayeva, G.A. Mun, V.V. Khutoryanskiy, Biomacromolecules 9 (2008) 3353–3361. <a href=" http://doi.org/10.1021/bm8006242">Crossref</a>

[11]. S. Nayak, L.A. Lyon, Angew. Chem., Int. Ed. 44 (2005) 7686–7708. <a href=" http://doi.org/10.1002/ anie.200501321">Crossref</a>

[12]. E.R. Gillies, T.B. Jonsson, J.M.J. Fréchet, J. Am. Chem. Soc. 126 (2004) 11936–11943. <a href=" http://doi.org/10.1021/ja0463738">Crossref</a>

[13]. G. Y. Li, L. Q. Shi, R. J. Ma, Y. L. An, N. Huang, Angew. Chem., Int. Ed. 45 (2006) 4959–4962. <a href=" http://doi.org/10.1002/anie.200600172">Crossref</a>

[14]. I. Dimitrov, B. Trzebicka, A.H.E. Müller, A. Dworak, C.B. Tsvetanov, Prog. Polym. Sci. 32 (2007) 1275–1343. <a href=" http://doi.org/10.1016/j. progpolymsci.2007.07.001">Crossref</a>

[15]. A. Klaikherd, C. Nagamani, S. Thayumanavan, J. Am. Chem. Soc. 131 (2009) 4830–4838. <a href=" http://doi.org/10.1021/ja809475a">Crossref</a>

[16]. R.K. Rakhmetullayeva, G.A. Mun, G.Zh. Yeligbayeva, A.N. Azhkeyeva, M. Abutalip, A. Yedgeyeva. Research physico-chemical properties new materials based on 2– hydroxyethylacrylate and ethylacrylate. Chemical Bulletin of Kazakh National University, chemical series. 1 (77) (2015) 73–79 (in Kazakh).

[17]. R.K. Rakhmetullayeva, U. Nakan, A. Kurmanbekova, A.A. Mamutova, A.K. Toktabayeva, E.S.M. Negim, M.E. Nursultanov, The new hybrid copolymers based on N-isopropyl acrylamide. 2nd International Conference on: «Multidisciplinary Innovation for Sustainability and Growth», Malaysia, 38, 2005.

[18]. A. Yedgeyeva, K.A. Almenova, A. Azhkeyeva, R. Rakhmetullayeva, The obtain of new film materials based on acrylic monomers // Collection of articles on the materials of the XXXVIII International Scientific and Practical Conference, Moskow, Internauk, 2016, p. 71-75.

[19]. C.E. Mora-Huertas, H. Fessi, and A. Elaissari. Polymer-based Nanocapsules for Drug Delivery. Int. J. Pharm. 385 (2010) 113–142. <a href=" http://doi.org/10.1016/j.ijpharm.2009.10.018">Crossref</a>

[20]. M.A. Yakiyayeva, R.K. Rakhmetullayeva, A.K. Toktabayeva, G.A. Mun. Research by modern methods of new stimuli-sensitive properties of copolymer based on butyl acrylate. Chemical Bulletin of Kazakh National University, chemical series. 1 (69) (2013) 77–83 (in Kazakh).

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Published

2017-01-25

How to Cite

Rakhmetulayeva, R. K., Azhkeyeva, A. N., Yeligbayeva, G. Z., Shaikhutdynov, Y. M., Mun, G. A., & Abutalip, M. (2017). New Thermo-Sensitive Hydrogel Based on Copolymer of 2-hydroxyethyl Acrylate and Ethyl Acrylate. Eurasian Chemico-Technological Journal, 19(1), 47–55. https://doi.org/10.18321/ectj502

Issue

Vol. 19 No. 1 (2017)

Section

Articles

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