Structure and swelling of polymer-clay composites

Authors

  • R. S. Iminova Chair of Organic Сhemistry and Chemistry of Natural Compounds, Karassai batyr str.,95A, Almaty, Kazakhstan
  • Sh. N. Zhumagalieva Chair of Organic Сhemistry and Chemistry of Natural Compounds, Karassai batyr str.,95A, Almaty, Kazakhstan
  • M. K. Beisebekov Chair of Organic Сhemistry and Chemistry of Natural Compounds, Karassai batyr str.,95A, Almaty, Kazakhstan
  • Zh. A. Abilov Chair of Organic Сhemistry and Chemistry of Natural Compounds, Karassai batyr str.,95A, Almaty, Kazakhstan
  • G. A. Mun Chair of Organic Сhemistry and Chemistry of Natural Compounds, Karassai batyr str.,95A, Almaty, Kazakhstan

DOI:

https://doi.org/10.18321/ectj283

Abstract

Composition gels on the basis of bentonite clay of Manrak deposit (East-Kazakhstan region) and nonionogenic polymers - poly-2-hydroxyethyl-acrylate and polyacrylamide were synthesized by radical intercalative polymerization in situ with various content o f cross-linking agent N,N-methylene-bisacrylamide and with time of intercalation about 8 hours. The morphological structure, the nature of interaction of components and the swelling ability of composition gels were studied by scanner electron microscopy, equilibrium swelling and IR- spectroscopy methods. By studying of morphological structure it was determined, that the polymer-clay composition gels, synthesized by intercalative polymerization, are most homogenous and interconsistency in case of "acrylamide-clay" composition in contrast with "2-hydroxyethylacrylate-clay" composition. For "acrylamide-clay" gels the swelling degree of gels was stated to decrease with the increase in the content of cross-linking agent and ionic strength, but "2-hydroxyethylacrylate -clay" compositions have the extremely character of swelling, where maximum degree of swelling account for gel with content of cross-linking agent 1*10-2 M. Interaction of composition components was realized on account of hydrogen bonds with formation of chemically cross-linked complex polymer-clay. Decrease of swelling degree of compositions in physiological solution points to acquisition of polyelectrolyte nature of composition gels on account of combination of nonionogenic macromolecules of polymers with negatively charged particles of bentonite clay. For intercalated samples of polymer-clay compositions, the degree of swelling at all degrees of cross-linking is between those for pure polymers and pure clay, that in turn, agrees with the conclusion on the great composition homogeneity of samples with preliminary intercalation. As of results of holding investigation fit is safe to say, that obtained polymer-clay composition gels are potential sorbents and prolongated carriers of medicine

References

1. Lomakin S.М., Zaikov G.Е. Polymer nanocomposites of decreased combustibility on the basis of layer silicates. Vysokomol. soed., Series B, (2005), Volume 47, №1, pp. 104-120.

2. Pomogailo А. D. Synthesis and intercalation chemistry of hybrid organic-inorganic anocomposites.Vysokomol. soed., Series С, (2006), Volume 48, №7, pp. 1318-1351.

3. Goettler L.A., Lee K.Y., and Thakkar H. Layered Silicate Reinforced Polymer Nanocomposites: Development and Applications. J. of Polymer Reviews, (2007), Volume 47, pp. 291-317.

4. Iminova R.S., Kudaibergenova B. M., Zhumagalieva Sh.N., Beisebekov M.K., and Abilov Zh.A. Polymer composition materials. Vestnik KazNU, Chemical series, (2006), №1(41), pp. 61-71.

5. Kun Xu, Jihua Wang, Sheng Xiang, Qiang Chen, Wende Zhang and Pixin Wang Study on the synthesis and performance of hydrogels with ionic monomers and montmorillonite. Applied Clay Science, (2007), Volume 38, Issues 1-2, pp. 139-145.

6. Se-Hoon Kim1, Sang-Hyun Park1, SungChul Kim Novel clay treatment and preparation of Poly(ethylene terephthalate)/ clay nanocomposite by In-situ polymerization. Polymer Bulletin 53, (2005), рр. 285–292.

7. Lisa M. Stadtmueller, Kyle R. Ratinac and Simon P. Ringer The effects of intragallery polymerization on the structure of PMMA–clay nanocomposites. Polymer, (2005), Volume 46, Issue 23, рр. 9574-9584.

8. Wei'an Zhang, Yu Li, Luo Wei and Yue'e Fang In situ intercalative polymerization of poly(methyl
methacrylate)/clay nanocomposites by γ-ray irradiation. Materials Letters, (2003), Volume 57, Issues 22-23, , рр. 3366-3370.

9. Ivanchev S.S., Dmitrienko А. V. Polymerization filling by the method of radical polymerization as a method of obtaining composition materials. Uspehi Himii, (1982), Volume 51, Issue 6, pp. 1178-1200.

10. Akimbaeva А.М. Successes and problems in the field of polymerization of monomers on the surface of disperse layer silicates. Izvestia of NAS of RK, Chemical series, (2003), №3, pp. 84-96.

11. Zhumagalieva Sh.N., Beisebekov M.K., Abilov Zh.A., Akhmedova Sh. S. On bentonites and their usage in medicine. Vestnik KazNU, Chemical series, (2001), №3 (23), pp. 41-50 .

12. Essikova O.V., Starodubtsev S.G., Khokhlov A.R. Synthesis, swelling and absorption properties of composites on the basis of polyacrylamide gel and sodium bentonite. Vysokomol. soed., Series А, (2002), Volume 44, №5, pp. 802-808.

13. Beisebekov M.K. Beisebekov M.K. Polymer derivates of medicinal and biologically active substances. Kandidatskaya dissertaciya, 2004, Almaty, P. 52.

14. Kuznetsov E.V., Divgun S.M., Budarina A.A., Avakumova N.I., Kurenkov V.F. Practical work on physics and chemistry of polymers. –M.: Chemistry, 1977, 256 p.

15. Giannelis E.P., Polymer-layered silicate nanocomposites: synthesis, properties and applications. Appl Organomet Chem, (1998), Volume 12, pр. 675-680.

16. Mikitaev A. K., Kalajan A.A., Lednev O.B., Mikitaev М.А. Nanocomposite materials on the basis of organoclays. Electron journal «Issledovano v Rossii», 2004, pp. 912-921.

17. Iminova R.S., Zhumagalieva Sh.N., Beisebekov M.K., Mun G.A., Abilov Zh.A. Synthesis and investigation of composition gels on the basis of 2-hydroxy-ethyl-acrylate and bentonite clay. Proceedings of the II Inter. Sci. Conf. “Chemistry, technology and medical aspects of natural compounds”, 2007, Almaty, Kazakhstan, P.301.

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Published

2009-09-20

How to Cite

Iminova, R. S., Zhumagalieva, S. N., Beisebekov, M. K., Abilov, Z. A., & Mun, G. A. (2009). Structure and swelling of polymer-clay composites. Eurasian Chemico-Technological Journal, 11(3), 213–220. https://doi.org/10.18321/ectj283

Issue

Vol. 11 No. 3 (2009)

Section

Articles

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