Investigation of Electrohydraulic Effect on Physicochemical Characteristics of High-Resinous Oil “Karazhanbas”
DOI:
https://doi.org/10.18321/ectj999Keywords:
Electrohydraulic action, NMR spectroscopy, Petroleum products, Fragment compositionAbstract
In order to change the viscosity of high-resinous oil of the “Karazhanbas” field (Kazakhstan), the effect of electrohydraulic action on it was studied. The effect of adding an organic solvent xylene on the rheological properties of oil is investigated. A comparative study of the hydrocarbon composition of oil before and after electrohydraulic impact was carried out by the method of gas chromatographymass spectrometry. Fragment composition of oil hydrocarbons before and after electrohydraulic treatment was determined by 1H and 13C NMR spectroscopy. It is shown that the conversion of heavy oil fractions to light ones begins with a five-time electrohydraulic impact. It is determined that 20‒25 electric discharge pulses are sufficient for the quantitative process of splitting hydrocarbons. It was found that the addition of xylene to high-viscosity oil leads to an increase in the conversion of hydrocarbons under electrohydraulic action. The content of paraffins and naphthalenes in high-viscosity oil is slightly reduced during electrohydraulic processing. In oil, after electrohydraulic action, a decrease in the proportion of protons of long alkyl terminal СН3-groups of hydrocarbons is observed, which indicates the process of decomposition of heavy oil fractions into light fractions.
References
(1). E.K. Ongarbaev, E.O. Doszhanov, Z.A. Mansurov. Refining of Heavy Oils and Residual Oils and Recycling of Waste. Kazakh University, Almaty, 2011, p. 256 (in Russian).
(2). A.A. Kalybai, N.K. Nadirov, D.U. Bodykov, A.K. Abzhali, Petroleum and Gas 2 (2019) 100–119.
(3). A.I. Nesterenko, Yu.S. Berlisov, Chem. Technol. Fuels Oils 43 (2007) 515–518. Crossref
(4). M.A. Promtov, Chem. Petrol. Eng. 44 (2008) 63–66. Crossref
(5). D.J. Flannigan, K.S. Suslick, Nature 434 (2005) 52–55. Crossref
(6). W. Chen, W. Huang, Y. Liang, X. Gao, W. Cui, Phys. Rev. E 78 (2008) 035301(R). Crossref
(7). A.N. Sawarkar, A.B. Pandit, S.D. Samant, J.B. Joshi, Can. J. Chem. Eng. 87 (2009) 329–342. Crossref
(8). D.U. Bodykov, M.S. Abdikarimov, M.A. Seitzhanova, M. Nazhipkyzy, Z.A. Mansurov, A.O. Kabdoldina, Zh.R. Ualiyev, J. Eng. Phys. Thermophys. 90 (2017) 1096–1101. Crossref
(9). M.M. Sergazina, M.B. Alimzhanova, Рroceedings of 15th International Multidisciplinary Scientific Conference “SGEM”, Albena, Bulgaria, 2015, р. 157–163.
(10). G.F. Pauli, B.U. Jaki, D.C. Lankin, J. Nat. Prod. 68 (2005) 133–149. Crossref
(11). C.O. Rossi, P. Caputo, G. De Luca, L. Maiuolo, S. Eskandarsefat, C. Sangiorgi, Appl. Sci. 8 (2018) 229. Crossref
(12). C.O. Rossi, P. Caputo, V. Loise, S. Ashimova, B. Teltayev, C. Sangiorgi. A New Green Rejuvenator: Evaluation of Structural Changes of Aged and Recycled Bitumens by Means of Rheology and NMR. RILEM 252-CMB Symposium. RILEM Bookseries, vol 20 (2019). Crossref
(13). I.Z. Rakhmatullin, S.V. Efimov, B.Ya. Margulis, V.V. Klochkov, J. Petrol. Sci. Eng. 156 (2017) 12–18. Crossref
Downloads
Published
How to Cite
Issue
Section
License
You are free to: Share — copy and redistribute the material in any medium or format. Adapt — remix, transform, and build upon the material for any purpose, even commercially.
Eurasian Chemico-Technological Journal applies a Creative Commons Attribution 4.0 International License to articles and other works we publish.
Subject to the acceptance of the Article for publication in the Eurasian Chemico-Technological Journal, the Author(s) agrees to grant Eurasian Chemico-Technological Journal permission to publish the unpublished and original Article and all associated supplemental material under the Creative Commons Attribution 4.0 International license (CC BY 4.0).
Further distribution of this work must maintain attribution to the author(s) and the published article’s title, journal citation, and DOI.