Comparative Analysis of Physicochemical Properties of Rutile TiO2 with Hierarchical 3D Architecture Prepared by Liquid Hydrolysis of TiCl4 and Hydrothermal Method

N. V. Shikina; S. A. Yashnik; A. V. Toktarev; A. V. Ishchenko; V. A. Ushakov; M. S. Mel’gunov; Z. A. Mansurov; Z. R. Ismagilov

doi:10.18321/ectj976

Authors

N. V. Shikina Federal Research Center Boreskov Institute of Catalysis SB RAS, 5 pr. Akad. Lavrentieva, Novosibirsk, Russia
S. A. Yashnik Federal Research Center Boreskov Institute of Catalysis SB RAS, 5 pr. Akad. Lavrentieva, Novosibirsk, Russia
A. V. Toktarev Federal Research Center Boreskov Institute of Catalysis SB RAS, 5 pr. Akad. Lavrentieva, Novosibirsk, Russia
A. V. Ishchenko Federal Research Center Boreskov Institute of Catalysis SB RAS, 5 pr. Akad. Lavrentieva, Novosibirsk, Russia
V. A. Ushakov Federal Research Center Boreskov Institute of Catalysis SB RAS, 5 pr. Akad. Lavrentieva, Novosibirsk, Russia
M. S. Mel’gunov Federal Research Center Boreskov Institute of Catalysis SB RAS, 5 pr. Akad. Lavrentieva, Novosibirsk, Russia
Z. A. Mansurov Institute of Combustion Problems, 172 Bogenbay Batyr str., Almaty, Kazakhstan
Z. R. Ismagilov Federal Research Center Boreskov Institute of Catalysis SB RAS, 5 pr. Akad. Lavrentieva, Novosibirsk, Russia; Federal Research Center of Coal and Coal Chemistry Institute of Coal Chemistry and Materials Science SB RAS, 18 Sovetskiy pr., Kemerovo, Russia

DOI:

https://doi.org/10.18321/ectj976

Keywords:

titanium dioxide, nanostructured rutile, porous structure, thermal treatment

Abstract

TiO₂ (rutile) samples with a hierarchical 3D nanostructure of the particles were synthesized by two methods: liquid hydrolysis of TiCl₄ at 90 °С and atmospheric pressure; hydrothermal synthesis from TiCl₄ at 160 °С and different [H₂O]/[Ti] ratios. The effect exerted by conditions of the synthesis and post-treatments on the crystallite size, morphology, electronic properties and pore structure of the rutile samples was investigated. It was shown that severe hydrothermal conditions with the ratio [H₂O]/[Ti] = 20 provide the formation of a more perfect crystal structure of rutile with a smaller band gap energy (3.00 eV against 3.06 eV for the rutile obtained by liquid hydrolysis at atmospheric pressure). The study revealed the stabilizing effect of cerium cations on the pore structure of rutile, which changes upon thermal treatment.

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