Highly Dispersed Palladium on Carbon Nanofibers for Hydrogenation of Nitrocompounds to Amines
DOI:
https://doi.org/10.18321/ectj200Keywords:
palladium dispersion, catalysis, hydrogenation of nitrobenzene.Abstract
The effect of palladium dispersion and nature of the support on catalytic performance in hydrogenation of nitrobenzene to aniline was studied. It was shown that the type of the support and modification of palladium with phosphorus make it possible to stabilize highly dispersed (1.5-2 nm) palladium particles in the metallic state, thus increasing the efficiency of new catalysts.
References
[2]. W. Chuntiag, V.G. Dorokhov, G.A. Boiko, B.S. Bal’zhinimaev, and V.V. Barelko, Dokl. Chem. 402 (2005) 111–113.
[3]. I.I. Obraztsova, and O.A. Efimov, Russ. J. Appl. Chem. 77 (2004) 511–512.
[4]. A.I. Kozlov, and V.L. Zbarsky, Russ. Chem. J. 50 (2006) 131–139.
[5]. I.I. Obraztsova, N.K. Eremenko, G.Yu. Simenyuk, and A.N. Eremenko, Russ. J. Natural and Technical Sciences 6 (2010) 91–94.
[6]. A.E. Shalagina, Z.R. Ismagilov, O.Yu. Podyacheva, et al. Carbon 45 (2007) 1808–1820.
[7]. Z.R. Ismagilov, A.E. Shalagina, O.Yu. Podyacheva et al. Kinetics and Catalysis 48 (2007) 581–588.
[8]. Z.R. Ismagilov, A.E. Shalagina, O.Yu. Podyacheva et al. Carbon 47 (2009) 1922–1926.
[9]. O.Yu. Podyacheva, A.N. Shmakov, Z.R. Ismagilov, Carbon 52 (2013) 486–492.
[10]. L. Jia, D.A. Bulushev, O.Yu. Podyacheva, A.I. Boronin, L.S. Kibis, E.Yu. Gerasimov, S.Beloshapkin, I.A. Seryak, Z.R. Ismagilov, and J.R.H. Ross, J. Catal. 307 (2013) 94–102.
[11]. A. Ayusheev, O. Taran, I. Seryak, O. Podyacheva, C. Descorme, M. Besson, L. Kibis, A. Boronin, A. Romanenko, Z. Ismagilov, and V. Parmon, Appl. Catal., B 146 (2014) 177–185.
[12]. O.Yu. Podyacheva, A.N. Stadnichenko, S.A. Yashnik, O.A. Stonkus, E.M. Slavinskaya, A.I.Boronin, A.V. Puzynin, and Z.R. Ismagilov, Chin. J. Catal. 35 (2014) 960–969.
[13]. O.A. Stonkus, L.S. Kibis, O.Yu. Podyacheva, E.M. Slavinskaya, V.I. Zaikovskii, Z.R. Ismagilov, A.S. Noskov, and A.I. Boronin, Chem. Cat. Chem. 6 (2014) 2115–2128.
[14]. O.Yu. Podyacheva, Z.R. Ismagilov, Catal. Today 249 (2015) 12–22.
[15]. I.I. Obraztsova, N.K. Eremenko, and Yu.N. Velyakina, Kinetics and Catalysis 49 (2008) 422–427.
[16]. A.A. Nasibulin, and M.V. Klyuev, Russ. J. Petrochemistry 38 (4) (1998) 277–281.
[17]. Y. Nakao, and S. Fujishige, J. Catal. 68 (1981) 406–410.
[18]. M.V. Klyuev, Russ. J. Organic Chemistry 23 (3) (1987) 581–585.
[19]. T. Pillo, R. Zimmermann, P. Steiner, and S. Hüfner, J. Phys. Condens. Matter. 9 (1997) 3987– 3999.
[20]. M.G. Mason, Electronic structure of supported small metal clusters, Phys. Rev. B. 27 (1983) 748–762.
[21]. D. Briggs, M.P. Seah, Eds. Practical Surface Analysis by Auger and X-ray Photoelectron Spectroscopy, John Wiley & Sons: New York (1983).
[22]. O.Yu. Podyacheva, Z.R. Ismagilov, A.I. Boronin, L.S. Kibis, E.M. Slavinskaya, A.S. Noskov, N.V. Shikina, V.A. Ushakov, and A.V. Ischenko, Catal. Today 186 (2012) 42–47.