Effect of Preparation Mode on the Properties of Mn-Na-W/SiO2 Catalysts for Oxidative Coupling of Methane: Conventional Methods vs. POSS Nanotechnology

Authors

  • I. Z. Ismagilov Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
  • E. V. Matus Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
  • V. V. Kuznetsov Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
  • M. A. Kerzhentsev Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
  • S. A. Yasnik Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
  • T. V. Larina Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
  • I. P. Prosvirin Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
  • R. M. Navarro Instituto de Catálisis y Petroleoquímica, CSIC, Marie Curie 2, 28049, Madrid, Spain
  • J. L.G. Fierro Instituto de Catálisis y Petroleoquímica, CSIC, Marie Curie 2, 28049, Madrid, Spain
  • G. Gerritsen Hybrid Catalysis B.V., Den Dolech 2, Eindhoven 5612, AZ, the Netherlands
  • H. C.L. Abbenhuis Hybrid Catalysis B.V., Den Dolech 2, Eindhoven 5612, AZ, the Netherlands
  • Z. R. Ismagilov Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia; Institute of Coal Chemistry and Material Science SB RAS, pr. Sovetskiy, 18, 650000, Kemerovo, Russia

DOI:

https://doi.org/10.18321/ectj430

Keywords:

oxidative coupling of methane Mn-Na-W/SiO2 catalysts preparation methods

Abstract

Using XPS, BET, XRD, TG-DTA, HRTEM-EDX, TPR and UV-Vis Diffuse Reflectance spectroscopic methods the electronic, redox and structural properties of Mn-Na-W/SiO2 catalysts prepared by the incipient wetness impregnation method and mixture slurry method were studied in detail. Since POSS nanotechnology (POSS = polyhedral oligomeric silsesquioxanes) has attracted attention as tooling for synthesis of catalysts with novel properties and functionalities, we expanded this method for the preparation of Mn-Na-W/SiO2 catalyst. The physicochemical and catalytic properties of Mn-Na-W/SiO2 catalysts prepared by conventional methods
and POSS nanotechnology were examined comparatively. In all studied Mn-Na-W/ SiO2 catalysts both individual oxides (MnOx, WO3) and bimetal oxide phases (Na2WO4, MnWO4) are found in addition to oxide particles of high dispersion. The UV-Vis Diffuse Reflectance indicates that Na+ cations facilitates stabilization of octahedrally coordinated Mn3+Oh cations in the isolated state, while Mn3+Oh promote the disordering of W6+ cations in the supported system. The Mn-Na-W/ SiO2 prepared using metal-POSS precursors marks out presence of unglobular SiO2 particles, higher dispersion of MnOx and MnWO4 particles and more easily
reducible metal-oxide species. The catalysts prepared by incipient impregnation method and mixture slurry method have practically similar catalytic performance while the catalyst prepared by POSS nanotechnology method shows lower activity and selectivity. At 800‒850 °C the increase of C2 hydrocarbons yield from 4 to 15% and the rise of molar ratio С2Н4/C2H6 from 0.2 to 1 are observed when impregnation or mixture slurry method are used for catalyst preparation instead of POSS nanotechnology method.

Author Biography

R. M. Navarro, Instituto de Catálisis y Petroleoquímica, CSIC, Marie Curie 2, 28049, Madrid, Spain



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Published

2016-05-25

How to Cite

Ismagilov, I. Z., Matus, E. V., Kuznetsov, V. V., Kerzhentsev, M. A., Yasnik, S. A., Larina, T. V., … Ismagilov, Z. R. (2016). Effect of Preparation Mode on the Properties of Mn-Na-W/SiO2 Catalysts for Oxidative Coupling of Methane: Conventional Methods vs. POSS Nanotechnology. Eurasian Chemico-Technological Journal, 18(2), 93–110. https://doi.org/10.18321/ectj430

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Vol. 18 No. 2 (2016)

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