Application of POSS Nanotechnology for Preparation of Efficient Ni Catalysts for Hydrogen Production

Authors

  • I. Z. Ismagilov Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
  • E. V. Matus Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
  • V. V. Kuznetsov Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
  • S. A. Yashnik Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
  • M. A. Kerzhentsev Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia
  • G. Gerritsen Hybrid Catalysis B.V., Den Dolech 2, Eindhoven 5612, AZ, the Netherlands
  • H. C.L. Abbenhuis Hybrid Catalysis B.V., Den Dolech 2, Eindhoven 5612, AZ, the Netherlands
  • Z. R. Ismagilov Boreskov Institute of Catalysis SB RAS, pr. Akademika Lavrentieva, 5, 630090, Novosibirsk, Russia; Institute of Coal Chemistry and Material Science SB RAS, pr. Sovetskiy, 18, 650000, Kemerovo, Russia

DOI:

https://doi.org/10.18321/ectj497

Keywords:

POSS nanotechnology, nanomaterials, Ni nanoparticles, autothermal reforming of methane, hydrogen production

Abstract

POSS (polyhedral oligomeric silsesquioxanes) nanotechnology was applied for preparation of efficient Ni catalysts for hydrogen production through autothermal reforming of methane (ATR of CH4). The novel metal-POSS precursor [Nickel (II) ‒ Heptaisobutyl POSS (C4H9)7Si7O9(OH)O2Ni] of Ni nanoparticles was introduced into Ce0.5Zr0.5O2 support with following calcination and reduction stages of activation. The peculiarity of the genesis of Ni/SiO2/Ce0.5Zr0.5O2 nanomaterials and their characteristics versus deposition mode were studied by X-ray fluorescence spectroscopy, thermal analysis, N2 adsorption, X-ray diffraction, high-resolution transmission electron microscopy and H2 temperature-programmed reduction. The two kinds of supported Ni-containing particles were observed: highly dispersed Ni forms (1‒2 nm) and large Ni-containing particles (up to 50‒100 nm in size). It was demonstrated that the textural, structural, red-ox and, consequently, catalytic properties of ex-Ni-POSS catalysts depend on the deposition mode. The increase of a portion of difficultly reduced Ni2+ species is found upon application of intermediate calcination during Ni-POSS deposition that has detrimental effect on the activity of catalyst in ATR of CH4. The Ni/SiO2/Ce0.5Zr0.5O2 catalyst prepared by one-step Ni-POSS deposition exhibits the highest H2 yield ‒ 80% at T = 800 °C.

 

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25-01-2017

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Ismagilov, I. Z., Matus, E. V., Kuznetsov, V. V., Yashnik, S. A., Kerzhentsev, M. A., Gerritsen, G., … Ismagilov, Z. R. (2017). Application of POSS Nanotechnology for Preparation of Efficient Ni Catalysts for Hydrogen Production. Eurasian Chemico-Technological Journal, 19(1), 3–16. https://doi.org/10.18321/ectj497

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