Support and Catalyst for the Alkylation of Benzene by Ethylene Process

Authors

  • R. A. Shkrabina Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of SciencesNovosibirsk-90, Pr.Ak.Lavrentieva, 5, Russia
  • Z. R. Ismagilov Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of SciencesNovosibirsk-90, Pr.Ak.Lavrentieva, 5, Russia
  • N. A. Koryabkina Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of SciencesNovosibirsk-90, Pr.Ak.Lavrentieva, 5, Russia
  • Yu. K. Vorobiev Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of SciencesNovosibirsk-90, Pr.Ak.Lavrentieva, 5, Russia

DOI:

https://doi.org/10.18321/ectj347

Abstract

A method for preparation of a spherical alumina support with preset porous structure for a catalyst of benzene alkylation with ethylene has been developed. The process of the support manufacture has been adjusted in a pilot installation, and an industrial installation for production of alumina support for the alkylation catalyst has been designed and built at the Shevchenko Plastics Plant (Aktau, Kazakhstan).

References

(1). Report 4.26.01.02-77. Development of Domestic Catalyst «Supported Boron Trifluoride» for the Purchased Process of Benzene Alkylation with Ethylene. Krasnodar, Polytechnical Institute, 45 p., (1981).

(2). Kozorezov Yu. I., Rusakov A. P., Kuleshov A. N., Khim. Prom. , 11: 815 (1970), (in Russian).

(3). E. A. Paukshtis, In Infrared Spectroscopy in Heterogeneous Acid-base Catalysis., ( Edited by I.V.Kozhevnikov), Novosibirsk, Nauka, p. 254, (1992), (in Russian).

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(5). Ismagilov Z. R., Shkrabina R. A., Koryabkina N. A., Catal. Tod., 1-4:47-51 (1999). <a href="https://doi.org/10.1016/s0920-5861(98)00283-1">Crossref</a>

(6). Ismagilov Z. R., Shkrabina R. A., Barannik G. B., Kerzhenzev M. A., React. Kinet. Catal. Lett.,V.55, 2:489-499 (1995). <a href="https://doi.org/10.1007/bf02073086">Crossref</a>

(7). Ismagilov Z. R., Shkrabina R. A., Shepeleva M.N., Koryabkina N. A., Vorobiev, Yu. K. et.al., Intern.Pat. (Intern. Appl.) WO94/10088 (NPCT RU 93/00248) - Method of the granulated alumina preparation, (1994).

(8). Shkrabina R. A., Koryabkina N. A., Ismagilov Z. R., Vorobiev Yu. K., et al., Pat. RF. No 1511904. -Method of the support preparation for the catalyst of benzene alkylation by ethylene, (1987).

(9). Vorobiev Yu. K., Ismagilov Z. R., Shkrabina R. A., et al., Pat USSR No 1718616 – Fluidized bed apparatus for production of amorphous aluminum hydroxide, (1990).

(10). Gerasimov M. G., Samoilovich A. L., Ismagilov Z. R., Shkrabina R. A., Pat. RF. No 1829189. - Method of the catalyst preparation for the alkylation of benzene by ethylene process, (1992).

(11). Shkrabina R.A., Shepeleva M.N., Koryabkina N.À., Ismagilov Z.R., Vorobiev Yu.K., et al., Pat USSR No1445109. - Method of the spherical alumina preparation, (1987).

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Published

1999-11-10

How to Cite

Shkrabina, R. A., Ismagilov, Z. R., Koryabkina, N. A., & Vorobiev, Y. K. (1999). Support and Catalyst for the Alkylation of Benzene by Ethylene Process. Eurasian Chemico-Technological Journal, 1(1), 57–64. https://doi.org/10.18321/ectj347

Issue

Vol. 1 No. 1 (1999)

Section

Articles

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