Investigation of the Sorption Properties of Ore Materials for the Removal of Sulfur Dioxide from Exhaust Flue Gases of Power Plants

  • N. V. Shikina Boreskov Institute of Catalysis, pr. Akad. Lavrentieva, 5, Novosibirsk, 630090, Russia
  • S. R. Khairulin Boreskov Institute of Catalysis, pr. Akad. Lavrentieva, 5, Novosibirsk, 630090, Russia
  • N. A. Rudina Boreskov Institute of Catalysis, pr. Akad. Lavrentieva, 5, Novosibirsk, 630090, Russia
  • T. N. Teryaeva F.T. Gorbachev Kuzbass State Technical University, Kemerovo, 650000, Russia
  • E. S. Mikhaylova Institute of Coal Chemistry and Materials Science, Pr. Sovetskiy, 18, Kemerovo, 650000, Russia
  • Z. R. Ismagilov Boreskov Institute of Catalysis, pr. Akad. Lavrentieva, 5, Novosibirsk, 630090, Russia

Abstract

The prospects of using a natural material – ferromanganese nodules (FMN) from the Gulf of Finland – as the SO2 adsorbent are discussed. The starting material was studied as pellets and powder using X-ray fluorescence spectroscopy, XRD, BET, and mechanical strength analysis; dependences of physicochemical parameters of the material on heat treatment at 100-1000 ºC were found. FMN samples were tested in the process of SO2 sorption. The sorptive capacity of FMN samples for SO2 was found to increase with humidity of adsorbents; FMN samples with a humidity above 40% were shown to be promising for the removal of sulfur dioxide from gases

References

[1]. G.K. Boreskov, E.A. Levitsky, Z.R. Ismagilov, Journal of the All-Union Mendeleev Chemical Society, Vol. XXIX, 4 (1984) 379–385.

[2]. Z.R. Ismagilov, M.A. Kerzhentsev, Journal of the All-Union Mendeleev Chemical Society, Vol. XXXV, 1 (1990) 43–53.

[3]. Z.R. Ismagilov, M.A. Kerzhentsev, Catal. Rev. Sci.& Eng. 32 (1-2) (1990) 51–103.

[4]. Z.R. Ismagilov, M.L. Schipko, S.V. Bogomolov, M.A. Kerzhentsev, Chemistry For Sustainable Development 4 (6) (1996) 473–480.

[5]. L.A.C. Tarelho, M.A.A. Matos, F.J.M.A. Pereira, Fuel Process. Technol. 86 (12–13) (2005) 1385–1401.

[6]. F.N. Ridha, V. Manovic, A. Macchi, E.J. Anthony, Appl. Energy. 92 (2012) 415–420.

[7]. L. Yan, X. Lu, Q. Wang, Y. Kang, J. Xu, Ye. Chen, Appl. Therm. Eng. 65 (2014) 487–494.

[8]. A. Ansari, A. Bagreev, T.J. Bandosz, Carbon 43 (5) (2005) 1039–1048.

[9]. T.J. Bandosz, K. Block, Ind. Chem. Eng. Res. 45 (10) (2006) 3666–3672.

[10]. A. Bagreev, T.J. Bandosz, J. Colloid Interface Sci. 252 (2002) 188–194.

[11]. A. Bagreev, S. Bashkova, D.C. Locke, T.J. Bandosz, Sewage Sludge Derived Materials as Adsorbents for H2S and SO2. // Fundamentals of Adsorption -7, K. Kaneko, H. Kanoh, Y. Hanzawa Eds., IK International, Chiba, Japan. 2002. P. 239.

[12]. S. Bashkova, A. Bagreev, D.C. Locke, T.J. Bandosz, Environ. Sci. Technol. 35 (2001) 3263-3269.

[13]. F.L. Malikov, I.P. Mukhlenov, M.S.Mirzarakhimov, Journal of Applied Chemistry, 1981. Vol.64. P.2296.

[14]. RF patent 2164445, 2001.

[15]. H.T. Jang, S.B. Kim, D.S. Doh, Korean J. Chem. Eng. 20 (1) (2003) 116–120.

[16]. Y.I. Yoon, M.W. Kim, Y.S. Yoon, S.H. Kim, Chem. Eng. Sci. 58 (10) (2003) 2079–2087.

[17]. S.K. Jeong, T.S. Park, S.C. Hong, J. Chem. Techn.& Biotechn. 76 (10) (2001) 1080–1084.

[18]. M. Nitta, Appl. Catal. 9 (1984) 151–176.

[19]. US Patent 3330096, 1967.

[20]. A.I. Romanchuk, V.P. Ivanovskaya, T.N. Matevich, A.B. Korolev, Ores and Metals. 1995. No.4. P.100.

[21]. A.M. Ivanova, A.N. Smirnov, V.S. Rogov, A.P. Motov, N.S. Nikolskaya, K.V. Palshin, Mineral Resources of Russia 6 (2006) 14–19.

[22]. Z.R. Ismagilov, S.R. Khairulin, S.A. Yashnik, I.V. Ilyukhin, V.N. Parmon, Catalysis in Industry, 2008, special issue. P. 73–79.
Published
2015-04-10
How to Cite
[1]
N. Shikina, S. Khairulin, N. Rudina, T. Teryaeva, E. Mikhaylova, and Z. Ismagilov, “Investigation of the Sorption Properties of Ore Materials for the Removal of Sulfur Dioxide from Exhaust Flue Gases of Power Plants”, Eurasian Chem.-Technol. J., vol. 17, no. 2, pp. 137-137, Apr. 2015.
Section
Articles

Most read articles by the same author(s)